Metamorphic fluid flow in the northeastern part of the 3.8-3.7 Ga Isua Greenstone Belt (SW Greenland): A re-evalution of fluid inclusion evidence for early Archean seafloor-hydrothermal systems

Fluid inclusions in quartz globules and quartz veins of a 3.8-3.7 Ga old, well-preserved pillow lava breccia in the northeastern Isua Greenstone Belt (IGB) were studied using microthermometry, Raman spectrometry and SEM Cathodoluminescence Imaging. Petrographic study of the different quartz segregations showed that they were affected by variable recrystallization which controlled their fluid inclusion content. The oldest unaltered fluid inclusions found are present in vein crystals that survived dynamic and static recrystallization. These crystals contain a cogenetic, immiscible assemblage of CO₂-rich (+H₂O, +graphite) and brine-rich (+CO₂, +halite, +carbonate) inclusions. The gas-rich inclusions have molar volumes between 44.8 and 47.5 cm³/mol, while the brine inclusions have a salinity of ∼33 eq. wt% NaCl. Modeling equilibrium immiscibility using volumetric and compositional properties of the endmember fluids indicates that fluid unmixing occurred at or near peak-metamorphic conditions of ∼460 °C and ∼4 kbar. Carbonate and graphite were precipitated cogenetically from the physically separated endmember fluids and were trapped in fluid inclusions.In most quartz crystals, however, recrystallization obliterated such early fluid inclusion assemblages and left graphite and carbonate as solid inclusions in recrystallized grains. Intragranular fluid inclusion trails in the recrystallized grains of breccia cementing and crosscutting quartz veins have CO₂-rich assemblages, with distinctly different molar volumes (either between 43.7 and 47.5 cm³/mol or between 53.5 and 74.1 cm³/mol), and immiscible, halite-saturated H₂O-CO₂-NaCl(-other salt) inclusions. Later intergranular trails have CH₄-H₂ (X_H2 up to ∼0.3) inclusions of variable density (ranging from 48.0 to >105.3 cm³/mol) and metastable H₂O-NaCl(-other salt?) brines (∼28 eq. wt% NaCl). Finally, the youngest fluid inclusion assemblages are found in non-luminescent secondary quartz and contain low-density CH₄ (molar volume > 105.33 cm³/mol) and low-salinity H₂O-NaCl (0.2-3.7 eq. wt% NaCl). These successive fluid inclusion assemblages record a retrograde P-T evolution close to a geothermal gradient of ∼30 °C/km, but also indicate fluid pressure variations and the introduction of highly reducing fluids at ∼200-300 °C and 0.5-2 kbar. The quartz globules in the pillow fragments only contain sporadic CH₄(+H₂) and brine inclusions, corresponding with the late generations present in the cementing and crosscutting veins. We argue that due to the large extent of static recrystallization in quartz globules in the pillow breccia fragments, only these relatively late fluid inclusions have been preserved, and that they do not represent remnants of an early, seafloor-hydrothermal system as was previously proposed.Modeling the oxidation state of the fluids indicates a rock buffered system at peak-metamorphic conditions, but suggests a change towards fluid-graphite disequilibrium and a logf_H2/f_H2O above the Quartz-Fayalite-Magnetite buffer during retrograde evolution. Most likely, this indicates a control on redox conditions and on fluid speciation by ultramafic rocks in the IGB.Finally, this study shows that microscopic solid graphite in recrystallized metamorphic rocks from Isua can be deposited inorganically from a fluid phase, adding to the complexity of processes that formed reduced carbon in the oldest, well-preserved supracrustal rocks on Earth.     

What conditions supply chain strategies of ports? The case of Dubai

Recent academic debates about port competition have centered on the strategic responses of port authorities, operators, managers and owners to the emergence of global supply chains. The competitive performance of a port authority or operator, given the rise of the integrated logistics sector, depends increasingly on its strategic relationship to these supply chains and rather less on traditional port competition factors such as hinterland size and physical infrastructure. However, there are few empirical studies investigating the degree to which particular port actors are capable of inserting themselves into global supply chains. In this article we ask what factors condition the supply chain strategies of port actors. We hypothesize that the strategic supply chain choices of a port authority or operator are conditioned by the territorialized institutional framework in which the dominant actors in a port operate. We apply these insights through a case study of the transformation of Dubai Port Authority, and the rise of Dubai Ports World (DPW).

Soil stabilization with microbially induced desaturation and precipitation (MIDP) by denitrification: a field study

Acta Geotechnica - A field trial was performed to test the feasibility of microbially induced desaturation and precipitation (MIDP) by denitrification for the stabilization of a silty soil....     

Amplification and deformation of tidal wave in the Upper Scheldt Estuary

Ocean Dynamics - The records of HW and LW in the most upper part of the Scheldt Estuary since 1971 have been analysed together with the daily river discharge. The tidal range, the hydraulic head...     

Consistent past half-century trends in the atmosphere, the sea ice and the ocean at high southern latitudes

Simulations performed with the climate model LOVECLIM, aided with a simple data assimilation technique that forces a close matching of simulated and observed surface temperature variations, are able to reasonably reproduce the observed changes in the lower atmosphere, sea ice and ocean during the second half of the twentieth century. Although the simulated ice area slightly increases over the period 1980–2000, in agreement with observations, it decreases by 0.5 × 10⁶ km² between early 1960s and early 1980s. No direct and reliable sea ice observations are available to firmly confirm this simulated decrease, but it is consistent with the data used to constrain model evolution as well as with additional independent data in both the atmosphere and the ocean. The simulated reduction of the ice area between the early 1960s and early 1980s is similar to the one simulated over that period as a response to the increase in greenhouse gas concentrations in the atmosphere while the increase in ice area over the last decades of the twentieth century is likely due to changes in atmospheric circulation. However, the exact contribution of external forcing and internal variability in the recent changes cannot be precisely estimated from our results. Our simulations also reproduce the observed oceanic subsurface warming north of the continental shelf of the Ross Sea and the salinity decrease on the Ross Sea continental shelf. Parts of those changes are likely related to the response of the system to the external forcing. Modifications in the wind pattern, influencing the ice production/melting rates, also play a role in the simulated surface salinity decrease.     

Sedimentary geology of the Palaeoarchaean Buck Ridge (South Africa) and Kittys Gap (Western Australia) volcano-sedimentary complexes

The two Palaeoarchaean volcano-sedimentary complexes of the Buck Ridge (Barberton Greenstone Belt, South Africa) and Kittys Gap (Coppin Gap Greenstone Belt, East Pilbara, Australia) have a similar geological setting and age (∼3.45 Ga). The predominantly volcaniclastic sediments are concentrated at the top of these complexes, and experienced thorough, (very) early diagenetic silicification. In many places the silicification process has led to excellent preservation of the primary sedimentary structures. Elsewhere it has resulted in their obliteration or replacement by diagenetic structures. The Buck Ridge chert forms a regressive-transgressive succession, deposited around base level, with lacustrine and littoral marine facies. Deposition of the Kittys Gap Chert was also close to base level, almost exclusively subaqueous, with tidal influence and a regressive sequential trend.     

Repeated glacial-lake outburst floods in Patagonia: an increasing hazard?

Five similar glacial-lake outburst floods (GLOFs) occurred in April, October, December 2008, March and September 2009 in the Northern Patagonia Icefield. On each occasion, Cachet 2 Lake, dammed by the Colonia Glacier, released circa 200-million m³ water into the Colonia River. Refilling has occurred rapidly, such that further outbreak floods can be expected. Pipeflow calculations of the subglacial tunnel drainage and 1D hydraulic models of the river flood give consistent results, with an estimated peak discharge surpassing 3,000 m³ s^?1. These floods were larger in magnitude than any flood on record, according to gauged data since 1963. However, geomorphological analysis of the Colonia valley shows physical evidence of former catastrophic outburst floods from a larger glacial-lake, with flood discharges possibly as high as 16,000 m³ s^?1. Due to potential impacts of climate change on glacier dynamics in the area, jökulhlaups may increase future flood risks for infrastructure and population. This is particularly relevant in view of the current development of hydropower projects in Chilean Patagonia.     

Uncertain climate: An investigation into public scepticism about anthropogenic climate change

This study presents a detailed investigation of public scepticism about climate change in Britain using the trend, attribution, and impact scepticism framework of Rahmstorf (2004). The study found that climate scepticism is currently not widespread in Britain. Although uncertainty and scepticism about the potential impacts of climate change were fairly common, both trend and attribution scepticism were far less prevalent. It further showed that the different types of scepticism are strongly interrelated. Although this may suggest that the general public does not clearly distinguish between the different aspects of the climate debate, there is a clear gradation in prevalence along the Rahmstorf typology. Climate scepticism appeared particularly common among older individuals from lower socio-economic backgrounds who are politically conservative and hold traditional values; while it is less common among younger individuals from higher socio-economic backgrounds who hold self-transcendence and environmental values. The finding that climate scepticism is rooted in people's core values and worldviews may imply a coherent and encompassing sceptical outlook on climate change. However, attitudinal certainty appeared mainly concentrated in non-sceptical groups, suggesting that climate sceptical views are not held very firmly. Implications of the findings for climate change communication and engagement are discussed.     

An experimental study of discharge partitioning and flow structure at symmetrical bifurcations

Recent research has examined the factors controlling the geometrical configuration of bifurcations, determined the range of stability conditions for a number of bifurcation types and assessed the impact of perturbations on bifurcation evolution. However, the flow division process and the parameters that influence flow and sediment partitioning are still poorly characterized. To identify and isolate these parameters, three‐dimensional velocities were measured at 11 cross‐sections in a fixed‐walled experimental bifurcation. Water surface gradients were controlled, and systematically varied, using a weir in each distributary. As may be expected, the steepest distributary conveyed the most discharge (was dominant) while the mildest distributary conveyed the least discharge (was subordinate). A zone of water surface super‐elevation was co‐located with the bifurcation in symmetric cases or displaced into the subordinate branch in asymmetric cases. Downstream of a relatively acute‐angled bifurcation, primary velocity cores were near to the water surface and against the inner banks, with near‐bed zones of lower primary velocity at the outer banks. Downstream of an obtuse‐angled bifurcation, velocity cores were initially at the outer banks, with near‐bed zones of lower velocities at the inner banks, but patterns soon reverted to match the acute‐angled case. A single secondary flow cell was generated in each distributary, with water flowing inwards at the water surface and outwards at the bed. Circulation was relatively enhanced within the subordinate branch, which may help explain why subordinate distributaries remain open, may play a role in determining the size of commonly‐observed topographic features, and may thus exert some control on the stability of asymmetric bifurcations. Further, because larger values of circulation result from larger gradient disadvantages, the length of confluence–diffluence units in braided rivers or between diffluences within delta distributary networks may vary depending upon flow structures inherited from upstream and whether, and how, they are fed by dominant or subordinate distributaries. Copyright © 2011 John Wiley & Sons, Ltd.