Leaching of silica bands and concentration of magnetite in Archean BIF by hypogene fluids: Beebyn Fe ore deposit, Yilgarn Craton, Western Australia

The ~2,752-Ma Weld Range greenstone belt in the Yilgarn Craton of Western Australia hosts several Fe ore deposits that provide insights into the role of early hypogene fluids in the formation of high-grade (>55 wt% Fe) magnetite-rich ore in banded iron formation (BIF). The 1.5-km-long Beebyn orebody comprises a series of steeply dipping, discontinuous, <50-m-thick lenses of magnetite–(martite)-rich ore zones in BIF that extend from surface to vertical depths of at least 250 m. The ore zones are enveloped by a 3-km-long, 150-m-wide outer halo of hypogene siderite and ferroan dolomite in BIF and mafic igneous country rocks. Ferroan chlorite characterises 20-m-wide proximal alteration zones in mafic country rocks. The magnetite-rich Beebyn orebody is primarily the product of hypogene fluids that circulated through reverse shear zones during the formation of an Archean isoclinal fold-and-thrust belt. Two discrete stages of hypogene fluid flow caused the pseudomorphic replacement of silica-rich bands in BIF by Stage 1 siderite and magnetite and later by Stage 2 ferroan dolomite. The resulting carbonate-altered BIF is markedly depleted in SiO₂ and enriched in CaO, MgO, LOI, P₂O₅ and Fe₂O_3(total) compared with the least-altered BIF. Subsequent reactivation of these shear zones and circulation of hypogene fluids resulted in the leaching of existing hypogene carbonate minerals and the concentration of residual magnetite-rich bands. These Stage 3 magnetite-rich ore zones are depleted in SiO₂ and enriched in K₂O, CaO, MgO, P₂O₅ and Fe₂O_3(total) relative to the least-altered BIF. Proximal wall rock hypogene alteration zones in mafic igneous country rocks (up to 20 m from the BIF contact) are depleted in SiO₂, CaO, Na₂O, and K₂O and are enriched in Fe₂O_3(total), MgO and P₂O₅ compared with distal zones. Recent supergene alteration affects all rocks within about 100 m below the present surface, disturbing hypogene mineral and the geochemical zonation patterns associated with magnetite-rich ore zones. The key vectors for identifying hypogene magnetite-rich Fe ore in weathered outcrop include textural changes in BIF (from thickly to thinly banded), crenulated bands and collapse breccias that indicate volume reduction. Useful indicators of hypogene ore in less weathered rocks include an outer carbonate–magnetite alteration halo in BIF and ferroan chlorite in mafic country rocks.     

River Seepage Conductance in Large‐Scale Regional Studies

Flow exchange between surface and groundwater is of great importance be it for beneficial allocation and use of water resources or for the proper exercise of water rights. In large‐scale regional studies, most numerical models use coarse grid sizes, which make it difficult to provide an accurate depiction of the phenomenon. In particular, a somewhat arbitrary leakance coefficient in a third type (i.e., Cauchy, General Head) boundary condition is used to calculate the seepage discharge as a function of the difference of head in the river and in the aquifer, whose value is often found by calibration. A different approach is presented to analytically estimate that leakance coefficient. It is shown that a simple equivalence can be deduced from the analytical solution for the empirical coefficient, so that it provides the accuracy of the analytical solution while the model maintains a very coarse grid, treating the water‐table aquifer as a single calculation layer. Relating the empirical leakance coefficient to the exact conductance, derived from physical principles, provides a physical basis for the leakance coefficient. Factors such as normalized wetted perimeter, degree of penetration of the river, presence of a clogging layer, and anisotropy can be included with little computational demand. In addition the river coefficient in models such as MODFLOW, for example, can be easily modified when grid size is changed without need for recalibration.     

中德联合冬给措纳湖地区寒区环境变迁研究进展

青藏高原腹地的内陆湖及其湖相沉积物能够较真实地反映气候变化特征,在高原环境变迁研究中备受中外科学家的关注.2006年8月15日~9月10日,中德联合考察小组对青藏高原东北部的冬给措纳湖一带进行了第四纪冻土、地貌和地质学考察,并对湖岸阶地做了初步的数字高程分析.调查了冬给措纳湖底地形、地貌,采集了湖相沉积物样本.在湖的东岸和西岸发现多年冻土,湖泊西北山谷观察到古冰川活动遗迹.初步推测该湖是由断陷沉降形成.为进一步分析湖区气候和环境变迁,联合小组拟定2007年3月份钻取湖芯.     

How Effective Is Thermal Remediation of DNAPL Source Zones in Reducing Groundwater Concentrations?

Dense nonaqueous phase liquid (DNAPL) source areas containing chlorinated volatile organic compounds (cVOCs) such as trichloroethene (TCE) and perchloroethene (PCE) often give rise to significant dissolved plumes in groundwater, leading to the closure of downgradient water supply wells and creating vapor intrusion issues in buildings located above the plume. Hydraulic containment via pump‐and‐treat has often been implemented to limit migration but must continue indefinitely. Removal of the DNAPL source area by means such as in situ thermal remediation (ISTR) offers the potential to diminish or end the need for hydraulic containment if the associated dissolved plume attenuates sufficiently following source removal. A question often raised is whether this occurs or whether the back diffusion of contaminants from secondary sources such as low‐permeability lenses in the dissolved plume precludes it. The authors conducted DNAPL source removal using ISTR at dozens of sites. This paper presents a compilation of cases—10 separate DNAPL source areas at five project sites—where data indicate that the implementation of a thorough ISTR in a DNAPL source area can result in the attenuation of the associated dissolved plume, such that in several cases, long‐standing pump‐and‐treat systems could be turned off. Our findings contrast with recent assertions that aggressive source remediation may not be justifiable because dissolved plume concentrations will not decline sufficiently. We show that the application of ISTR can result in the thorough removal of the DNAPL source, effective diminution of dissolved plume groundwater concentrations, and achievement of drinking water standards.     

Climate sensitivity studies of the Greenland ice sheet using satellite AVHRR,SMMR, SSM/I and in situ data

Summary The feasibility of using satellite data for climate research over the Greenland ice sheet is discussed. In particular, we demonstrate the usefulness of Advanced Very High Resolution Radiometer (AVHRR) Local Area Coverage (LAC) and Global Area Coverage (GAC) data for narrow-band albedo retrieval. Our study supports the use of lower resolution AVHRR (GAC) data for process studies over most of the Greenland ice sheet. Based on LAC data time series analysis, we can resolve relative albedo changes on the order of 2–5%. In addition, we examine Scanning Multichannel Microwave Radiometer (SMMR) and Special Sensor Microwave Imager (SSM/I) passive microwave data for snow typing and other signals of climatological significance. Based on relationships between in situ measurements and horizontally polarized 19 and 37 GHz observations, wet snow regions are identified. The wet snow regions increase in aerial percentage from 9% of the total ice surface in June to a maximum of 26% in August 1990. Furthermore, the relationship between brightness temperatures and accumulation rates in the northeastern part of Greenland is described. We found a consistent increase in accumulation rate for the northeastern part of the ice sheet from 1981 to 1986.With 16 Figures     

Deriving incline values for street networks from voluntarily collected GPS traces

ABSTRACT

When producing optimal routes through an environment, considering the incline of surfaces can be of great benefit in a number of use cases. For instance, steep segments need to be avoided for energy-efficient routes and for routes that are suitable for mobility-restricted people. Such incline information may be derived from digital elevation models (DEMs). However, the corresponding data capturing methods (e.g. airborne LiDAR, photogrammetry, and terrestrial surveying) are expensive. Current low-cost and open-licensed DEM (e.g. Shuttle Radar Topography Mission [SRTM] and Advanced Spaceborne Thermal Emission and Reflection Radiometer [ASTER]) generally do not have sufficient horizontal resolution or vertical accuracy, and lack a global coverage. Therefore, we have investigated an alternative low-cost approach which derives street incline values from GPS traces that have been voluntarily collected by the OpenStreetMap contributors. Despite the poor absolute accuracy of this data, the relative accuracy of traces seems to be sufficient enough to compute incline values with reasonable accuracy. A validation shows that the accuracy of incline values calculated from GPS traces slightly outperforms incline values derived from SRTM-1 DEM, though results depend on how many traces per street segment are used for computation.     

Holocene environmental history in high‐Arctic North Greenland revealed by a combined biomarker and macrofossil approach

In this study, we use a combined biomarker and macrofossil approach to reconstruct the Holocene climate history recorded in Trifna Sø, Skallingen area, eastern North Greenland. Chronological information is derived from comparison of lithological, biogeochemical and macrofossil characteristics with a well‐dated record from nearby Lille Sneha Sø. Following local deglaciation around c. 8 cal. ka BP, the local peak warmth occurred between c. 7.4 and 6.2 cal. ka BP as indicated by maximum macrofossil abundances of warmth‐demanding plants (Salix arctica and Dryas integrifolia) and invertebrates (Daphnia pulex and Chironomidae). Warm conditions were dominated by terrestrial organic matter (OM) sedimentation as implied by the alkane‐based P_aq ratio, but increased aquatic productivity is indicated when temperature was highest around 6.5 cal. ka BP. The n‐C₂₉/n‐C₃₁ alkane ratio shows that vegetation in the catchment was dominated by shrubs after deglaciation, but shifted towards relatively more grassy/herbaceous vegetation during peak warmth. After 5.4 cal. ka BP, the disappearance of warmth‐demanding plant and invertebrate macrofossils indicates cooling in the Skallingen area. This cooling was characterized by a significant shift towards dominance of aquatic OM sedimentation in Trifna Sø as implied by high P_aq ratios. Cooling was also associated with a shift in vegetation type from dwarf‐shrub heaths towards relatively more herbaceous vegetation in the catchment, stronger erosion and more oligotrophic conditions in the lake. Our data show that mean air temperatures inferred using branched glycerol dialkyl glycerol tetraethers (brGDGTs) do not seem to accurately reflect the local climatic history. Irrespective of calibration, methylation of branched tetraethers (MBT) palaeothermometry cannot be reconciled with the macrofossil evidence and seems to be biased by either changing brGDGT sources (in situ vs. soil‐derived) or changing species assemblages and/or an unknown physiological response to changing environmental conditions at high latitude.     

A priori fully populated covariance matrices in least-squares adjustment—case study: GPS relative positioning

In this contribution, using the example of the Mátern covariance matrices, we study systematically the effect of apriori fully populated variance covariance matrices (VCM) in the Gauss–Markov model, by varying both the smoothness and the correlation length of the covariance function. Based on simulations where we consider a GPS relative positioning scenario with double differences, the true VCM is exactly known. Thus, an accurate study of parameters deviations with respect to the correlation structure is possible. By means of the mean-square error difference of the estimates obtained with the correct and the assumed VCM, the loss of efficiency when the correlation structure is missspecified is considered. The bias of the variance of unit weight is moreover analysed. By acting independently on the correlation length, the smoothness, the batch length, the noise level, or the design matrix, simulations allow to draw conclusions on the influence of these different factors on the least-squares results. Thanks to an adapted version of the Kermarrec–Schön model, fully populated VCM for GPS phase observations are computed where different correlation factors are resumed in a global covariance model with an elevation dependent weighting. Based on the data of the EPN network, two studies for different baseline lengths validate the conclusions of the simulations on the influence of the Mátern covariance parameters. A precise insight into the impact of apriori correlation structures when the VCM is entirely unknown highlights that both the correlation length and the smoothness defined in the Mátern model are important to get a lower loss of efficiency as well as a better estimation of the variance of unit weight. Consecutively, correlations, if present, should not be neglected for accurate test statistics. Therefore, a proposal is made to determine a mean value of the correlation structure based on a rough estimation of the Mátern parameters via maximum likelihood estimation for some chosen time series of observations. Variations around these mean values show to have little impact on the least-squares results. At the estimates level, the effect of varying the parameters of the fully populated VCM around these approximated values was confirmed to be nearly negligible (i.e. a mm level for strong correlations and a submm level otherwise).     

青藏高原东北缘冬给错纳湖全新世湖面波动

青藏高原处于东亚季风、印度季风和西风环流交互作用区.末次冰消期以来,太阳辐射对该地区的古气候环境产生了重要影响,湖泊随着季风系统的变化发生了明显的水位升降,对湖岸阶地的形成起到了直接作用.本项研究重建了青藏高原东北缘冬给错纳湖湖岸阶地记录的湖面波动历史,试图了解青藏高原季风系统演变过程.通过湖泊北岸265 cm厚湖岸阶地沉积物粒度、碳酸盐、矿物、元素和介形虫古环境指标,结合OSL年代模式,分析表明在约10. 2 ka B. P.之前水体较浅;约10. 2~9. 0 ka B. P.湖面开始上升,气候凉湿;9. 0~8. 5 ka B. P.为印度季风强盛期,湖面明显上升,降雨量增高、温度上升;8. 5~7. 9 ka B. P.湖面降低与气候变冷有关;7. 9~7. 0 ka B. P.印度季风开始减弱,气温、降雨下降,但有效湿度较大,湖面降低;7. 0~6. 1 ka B. P.湖面上升可能与低蒸发作用有关,印度季风仍然影响该地区;6. 1~5. 2 ka B. P.,印度季风衰退,气候逐渐变冷、降雨量减小、水体变浅;5. 2~4. 6 ka B. P.气候冷干,有效湿度减小,湖面进一步下降;4. 6 ka B. P.至今气候干冷,东亚季风衰退,湖面下降,期间也可能受西风环流影响而有短暂的降雨增加时期.