Pedogenic zones in postglacial sediment of lake manitoba,Canada

The postglacial sediment record of Lake Manitoba is composed dominantly of silty clay to clayey silt with little variation in most physical, chemical, and mineralogical properties. Distinct in the sedimentary sequence of this large lake, however, are four zones that have a low moisture content, blocky to pelletal structure, and gleyed colour. All of these zones formed during the warmest and driest postglacial period in the region, 9500 to 4500 years ago. Although several possible hypotheses can be formulated regarding the origin of these zones including changes in sedimentation rate, clay mineralogy, lake chemistry, and depth of winter freezing, the most likely explanation is that they represent pedogenic horizons. Formation by pedogenesis during dry or extremely low water conditions is not mutually exclusive of the other hypotheses, and several are favoured by low water conditions.     

The iron-nickel-phosphorus system: Effects on the distribution of trace elements during the evolution of iron meteorites

To better understand the partitioning behavior of elements during the formation and evolution of iron meteorites, two sets of experiments were conducted at 1 atm in the Fe-Ni-P system. The first set examined the effect of P on solid metal/liquid metal partitioning behavior of 22 elements, while the other set explored the effect of the crystal structures of body-centered cubic (α)- and face-centered cubic (γ)-solid Fe alloys on partitioning behavior. Overall, the effect of P on the partition coefficients for the majority of the elements was minimal. As, Au, Ga, Ge, Ir, Os, Pt, Re, and Sb showed slightly increasing partition coefficients with increasing P-content of the metallic liquid. Co, Cu, Pd, and Sn showed constant partition coefficients. Rh, Ru, W, and Mo showed phosphorophile (P-loving) tendencies. Parameterization models were applied to solid metal/liquid metal results for 12 elements. As, Au, Pt, and Re failed to match previous parameterization models, requiring the determination of separate parameters for the Fe-Ni-S and Fe-Ni-P systems.Experiments with coexisting α and γ Fe alloy solids produced partitioning ratios close to unity, indicating that an α versus γ Fe alloy crystal structure has only a minor influence on the partitioning behaviors of the trace element studied. A simple relationship between an element’s natural crystal structure and its α/γ partitioning ratio was not observed. If an iron meteorite crystallizes from a single metallic liquid that contains both S and P, the effect of P on the distribution of elements between the crystallizing solids and the residual liquid will be minor in comparison to the effect of S. This indicates that to a first order, fractional crystallization models of the Fe-Ni-S-P system that do not take into account P are appropriate for interpreting the evolution of iron meteorites if the effects of S are appropriately included in the effort.     

Examination of climate risk using a modified uncertainty matrix framework—Applications in the water sector

Previous climate risk assessments provide important methodological insights into how to derive tractable research questions and the appropriate use of data under uncertainty, as well as identifying steps that benefit from stakeholder involvement. Here we propose the use of a framework for the systematic and objective exploration of climate risk assessments. The matrix facilitates a breakdown of information about aim and context, main results, methodological choices, stakeholder involvement, sources and characteristics of uncertainties and overall weaknesses. We then apply the matrix to three risk assessments in the water sector to explore some methodological strengths and weaknesses of approaches strongly linked to climate model outputs (top-down) versus those that originate from local knowledge of climate exposures (bottom-up), and demonstrate that closer integration with social and physical sciences is more likely to yield robust climate risk assessments.     

Trace element distribution during the reproductive cycle of female and male spiny and Pacific scallops, with implications for biomonitoring

Trace element concentrations and contents in gills, gonad, kidneys, mantle, muscle and remainder during the reproductive cycle of female and male spiny and Pacific scallops, from the Strait of Georgia, BC, Canada, were quantified by using ICPMS. The elements investigated were chromium, manganese, iron, cobalt, nickel, selenium, molybdenum, cadmium, tin and mercury. For all ten elements, the tissue distribution was to some extent influenced by species, sex and reproductive status. The implications of the present study in relation to the design of biomonitoring programmes are: (1) care should be taken to ensure an equal/constant sex composition when making interannual comparisons of pooled samples. Preferably the sexes should be monitored separately. (2) the practice of obtaining pooled samples in the interspawn phase is applicable only to monitoring long-term trends in contaminant levels, while the reproductive status should be heeded when studying short-term changes. (3) the present study confirms that direct temporal or spatial comparisons of absolute accumulated element concentrations are only valid intraspecifically.