Experiments in long-range climate control

Extrapolation of the palaeoclimate chronology of the past million years or so seems to leave little doubt that another glacial stage can be expected in the near geologic future. On a shorter time scale it appears that the increasing greenhouse effect from the use of fossil fuel will raise atmospheric temperature by 2 to 3 °K within a hundred years. The possibility of man's reversing or at least weakening these portentous climate changes is investigated here with the use of a thermodynamic climate model. Preliminary results indicate that the climate effects referred to may be reversible if caught early and certainly suggest that further and more sophisticated attention be given the subject.     

Nonlinear principal component analysis by neural networks

Nonlinear principal component analysis (NLPCA) can be performed by a neural network model which nonlinearly generalizes the classical principal component analysis (PCA) method. The presence of local minima in the cost function renders the NLPCA somewhat unstable, as optimizations started from different initial parameters often converge to different minima. Regularization by adding weight penalty terms to the cost function is shown to improve the stability of the NLPCA. With the linear approach, there is a dichotomy between PCA and rotated PCA methods, as it is generally impossible to have a solution simultaneously (a) explaining maximum global variance of the data, and (b) approaching local data clusters. With the NLPCA, both objectives (a) and (b) can be attained together, thus the nonlinearity in NLPCA unifies the PCA and rotated PCA approaches. With a circular node at the network bottleneck, the NLPCA is able to extract periodic or wave modes. The Lorenz (1963) 3‐component chaotic system and the monthly tropical Pacific sea surface temperatures (1950–1999) are used to illustrated the NLPCA approach.     

Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

The Laurentian Fan: Sohm Abyssal Plain

The 0.5- to 2-km thick Quaternary Laurentian Fan is built over Tertiary and Mesozoic sediments that rest on oceanic crust. Two 400-km long fan valleys, with asymmetric levees up to 700-m high, lead to an equally long, sandy, lobate basin plain (northern Sohm Abyssal Plain). The muddy distal Sohm Abyssal Plain is a further 400-km long. The sediment supplied to the fan is glacial in origin, and in part results from seismically triggered slumping on the upper continental slope. Sandy turbidity currents, such as the 1929 Grand Banks earthquake event, probably erode the fan-valley floors; but thick muddy turbidity currents build up the high levees. Margin setting represents fan and/or source area