Experimental studies of oxygen isotope fractionation in the carbonic acid system at 15°, 25°, and 40°C

In light of recent studies that show oxygen isotope fractionation in carbonate minerals to be a function of HCO₃⁻ and CO₃²⁻ concentrations, the oxygen isotope fractionation and exchange between water and components of the carbonic acid system (HCO₃⁻, CO₃²⁻, and CO_2(aq)) were investigated at 15°, 25°, and 40°C. To investigate oxygen isotope exchange between HCO₃⁻, CO₃²⁻, and H₂O, NaHCO₃ solutions were prepared and the pH was adjusted over a range of 2 to 12 by the addition of small amounts of HCl or NaOH. After thermal, chemical, and isotopic equilibrium was attained, BaCl₂ was added to the NaHCO₃ solutions. This resulted in immediate BaCO₃ precipitation; thus, recording the isotopic composition of the dissolved inorganic carbon (DIC). Data from experiments at 15°, 25°, and 40°C (1 atm) show that the oxygen isotope fractionation between HCO₃⁻ and H₂O as a function of temperature is governed by the equation:

     

UX Ret and CN Hyi: hipparcos photometry analysis

We present an analysis of the Hipparcos photometry of the contact binary systems UX Ret and CN Hyi. The Wilson-Devinney code is employed to model the V band light curve for several fixed values of the mass ratio. From the quality-of-fit of the different solutions a final solution is derived for each system. Absolute values of the system are derived using the parallax data from the Hipparcos catalog. Analysis of the V band photometry of two stars (EL Aqr and FN Cam) with spectroscopically known mass ratios is also provided as a validation for the methods adopted for this study.     

Monitoring of Irgarol 1051 concentrations with concurrent phytoplankton evaluations in East Coast areas of the United States

The objectives of this study were to measure: (1) Irgarol and GS26575 (major metabolite) during the peak 2004 boating season at selected marinas and reference areas in the Carolinian Zoogeographic Province of the Eastern United States; (2) Irgarol and GS26575 at selected stations during the summer months in the Back Creek/Severn River area in Maryland in 2003 and 2004; and (3) structural and functional characteristics of resident phytoplankton communities concurrently with Irgarol and GS26575 monitoring in Back Creek/Severn River area. Irgarol concentrations from 14 marinas in the Carolinian Province ranged from non-detectable (<1 ng/L) to 85 ng/L; concentrations were less than 16 ng/L at all reference sites. The probability of exceeding the plant 10th centile for Irgarol (251 ng/L) was less than 0.6% for all marinas and 0.01% for all reference areas. These data suggest low ecological risk from Irgarol exposure for both marina and reference areas in the Carolinian Province. Irgarol concentrations ranged from 5 ng/L at the Severn River reference site to 1,816 ng/L in Port Annapolis marina during the two year study. Ecological risk from Irgarol exposure was high for the Port Annapolis marina sites based on a probability of exceeding the plant 10th centile. However, risk was low for Severn River and Severn River reference sites. Functional and structural measures of resident phytoplankton communities in the Back Creek and Severn River did not suggest that these target species are impaired in the Port Annapolis marina area where probabilistic analysis predicted adverse effects from Irgarol exposure.     

Blooms of the cyanobacterium Lyngbya majuscula in coastal Queensland, Australia: disparate sites, common factors

During the last decade there has been a significant rise in observations of blooms of the toxic cyanobacterium Lyngbya majuscula along the east coast of Queensland, Australia. Whether the increase in cyanobacterial abundance is a biological indicator of widespread water quality degradation or also a function of other environmental change is unknown. A bioassay approach was used to assesses the potential for runoff from various land uses to stimulate productivity of L. majuscula. In Moreton Bay, L. majuscula productivity was significantly (p<0.05) stimulated by soil extracts, which were high in phosphorus, iron and organic carbon. Productivity of L. majuscula from the Great Barrier Reef was also significantly (p<0.05) elevated by iron and phosphorus rich extracts, in this case seabird guano adjacent to the bloom site. Hence, it is possible that other L. majuscula blooms are a result of similar stimulating factors (iron, phosphorus and organic carbon), delivered through different mechanisms.     

Trace element distribution during the reproductive cycle of female and male spiny and Pacific scallops, with implications for biomonitoring

Trace element concentrations and contents in gills, gonad, kidneys, mantle, muscle and remainder during the reproductive cycle of female and male spiny and Pacific scallops, from the Strait of Georgia, BC, Canada, were quantified by using ICPMS. The elements investigated were chromium, manganese, iron, cobalt, nickel, selenium, molybdenum, cadmium, tin and mercury. For all ten elements, the tissue distribution was to some extent influenced by species, sex and reproductive status. The implications of the present study in relation to the design of biomonitoring programmes are: (1) care should be taken to ensure an equal/constant sex composition when making interannual comparisons of pooled samples. Preferably the sexes should be monitored separately. (2) the practice of obtaining pooled samples in the interspawn phase is applicable only to monitoring long-term trends in contaminant levels, while the reproductive status should be heeded when studying short-term changes. (3) the present study confirms that direct temporal or spatial comparisons of absolute accumulated element concentrations are only valid intraspecifically.     

Temporal variability of ultraviolet cloud features in the Venus stratosphere

Statistics on the temporal variability of uv cloud features on Venus during 66 days of nominal mission imaging by the Pioneer Venus Orbiter Cloud Photopolarimeter reveal at least five types of systematic variability on large scales: (1) a low-latitude global-scale wave of period 3.94 ± 0.1 days corresponding to longitudinal motion of the dark equatorial band and propagating westward relative to the mean flow; (2) a midlatitude wave of period 5.20 ± 0.2 days corresponding to wavenumber 1 oscillations of the latitude of the bright polar bands and propagating eastward relative to the mean flow; (3) ～2- to 3-week fluctuations in the slope of longitudinal cloud brightness power spectra at intermediate wavenumbers manifested by variations in the intensity of large bow-shaped features; (4) ～2-month variations in polar region brightness consistent with polar brightening episodes observed from Earth; and (5) a monotonic decrease in the disk-integrated brightness of Venus during the nominal mission which may be either a true time variation or a solar-locked longitudinal dependence of brightness. Small-scale features appear to correlate with large-scale albedo patterns. Specifically, cellular features exist primarily where large-scale dark material is present, while the orientation of streak features with respect to latitude circles oscillates with the same ～4-day period as the large-scale features at low latitudes. The wide range of time scales present in the data suggests the complexity of Venus stratospheric dynamics. Extended observations over many years may be becessary to define the general circulation.