Geothermal prospecting by ground radon measurements

Radon-222 was measured using Kodak LR-115 film in the soils of 2500 locations near the Ngawha hot springs region, New Zealand, which is being exploited for geothermal power; the object was to determine its usefulness for predicting good drill sites. Unlike other surveys, which have shown large areas with consistent high radon values, anomalies here were scattered, and corresponded mainly with fault lineaments. The results suggested a major previously unnoticed fault. The sampling distance was 50 m.There was a strong seasonal effect on ground radon levels, with summer levels about ten times higher than winter levels.Swamps usually had measured radon levels of near zero because of the slow diffusion of radon in stagnant water, and even thermal areas (mainly in the swamps) usually had low measured values. However, where a fault crossed swamp it was sometimes detected, and with high signal/noise ratio, so swamps should be surveyed.Arguments from the radon levels found on different geologies show that at Ngawha radon has a maximum half value diffusion thickness of 7 m for lacustrine sediment and 25 m for basalt unless a permeable area is present (e.g., a fault).There was a weak correlation of radon levels with the temperatures found on drilling deep bores.Comparisons with the ROAC system and Alphacard system for measuring radon showed no statistical inter-correlations, but some qualitative correspondence of radon contours.The main strength of the method in regions with impermeable soils (such as at Ngawha), seems to be in detecting or confirming the presence of faults, and possibly (through them) indicating geological structure as deep as 300 m.     

A New Zealand test of the track-etch® method of prospecting for geothermal steam

The Track Etch® system for radon detection was evaluated as a geothermal exploration technique in a known geothermal resource area in New Zealand called the Craters of the Moon (previously known as “Karapiti”). Very strong radon anomalies spaced along mapped fault traces were detected using 60-m sample spacings. Such radon anomalies may indicate good areas to drill for steam. The anomalies detected in these tests were located inside a larger area known to have above-back-ground concentrations of radon and thought to be a generally favourable area for finding shallow steam. Track Etch® radon cups with an improved type of detector were found to be usable in ground temperatures as high as 60°C. There was no direct correlation of radon concentrations with resistivity measurements, but a moderate correlation with near-surface temperature measurements. Varying vegetation cover had no significant effect on the results but there was an apparent correlation with superficial pumice deposits. It is concluded from the tests that the Track Etch method shows promise in vapour-dominated areas for improving drill-hole siting and thus reducing the economic loss of drilling non-productive holes.     

Effect of non-petroleum oil spills on wintering birds near Vancouver

Within the period of our records, spills of vegetable oils at Vancouver harbour have caused greater losses of birds than spills of petroleum oils. Vegetable oils affect birds by feather wetting but do not exhibit odour and slick characteristics of petroleum oils. Because most vegetable oils are edible their potential danger to aquatic birds may go unnoticed; sites of storage and transhipment of vegetable oils may be overlooked in oil spill contingency planning.     

Mineralogy and petrology of melt rocks from the Popigai impact structure,Siberia

Abstract— The late Eocene Popigai impact structure of Siberia comprises an approximately 0.5–1.5 km thick, ˜100 km diameter sequence of clast-rich and clast-poor andesitic to rhyolitic impact melt rocks and impact breccias, underlain by Archean to Proterozoic crystalline basement and Proterozoic to Phanerozoic sedimentary rocks. The fine-grained to cryptocrystalline texture of the more melt-rich rocks, despite their occurrence in bodies locally in excess of 800 m thick and 28 km long, suggests that the melt crystallized in response to (1) cooling by the clast load, and/or; (2) rapid nucleation on finely brecciated clasts, which have since been assimilated and/or; (3) crystallization enhanced by the relatively low water contents of the melts. Rapid crystallisation of the melt is indicated by the lack of zoning in minerals, the presence of glass, the lack of strain recovery features in clasts and the lack of evidence for fractionation in the major and trace elements, including the rare earth elements. Optical and analytical electron microscopy reveal that the previously reported division of the melt rocks into high- and low-temperature variants based on hand sample appearance, or glass content, is not warranted. Clasts within the melt-rich rocks exhibit a wide range of shock metamorphic features, though they are not distributed in the impact melts in a systematic manner. This indicates that the melt-rich rocks were well mixed during their formation, thus juxtaposing unshocked with shocked material. Injection of mesostasis melt into partially melted checkerboard plagioclase and orthopyroxene clasts also occurred during this mixing stage.     

Late Miocene paleoenvironment of the Lambert Graben embayment, East Antarctica, evident from: Mollusc paleontology, sedimentology and geochemistry

The Upper Miocene (10.7–9.0 Ma) Battye Glacier Formation was deposited 250 km inland from the modern Amery Ice Shelf edge in Prydz Bay, East Antarctica. The composition of clay minerals distinguishes a Lower Member, which reflects regional erosion of Precambrian metamorphic basement, from an Upper Member, which records increased erosion of local Permian–Triassic Amery Group strata. The Upper Member was deposited in an ice-proximal environment akin to the modern fjords of East Greenland, with substantial diamict deposition resulting from melting iceberg discharge. The Lower Member was deposited in an ice-distal environment and included the accumulation of the fossil-bearing McLeod Beds. The McLeod Beds contain much siliceous biogenic sediment (≤ 15% opal), which is rare to absent in the predominantly hemipelagic mud of modern East Greenland fjords. The McLeod Beds also contain largely monospecific in situ Hiatella sp. mollusc assemblages suggestive of environmental stress, potentially caused by low salinity melt-water and a high input of terrigenous sediment, which excluded most other benthic taxa. Geochemical results from primary aragonite in Hiatella shells imply large freshwater input into the marine environment during mollusc growth, causing low δ¹⁸O, Na, Mg and high Fe values. The present study indicates that iceberg melt-water influence entering the marine environment was greater during the Late Miocene than today around Antarctica, and documents the paleoenvironment associated with a discrete period of ice margin retreat and marine incursion into the Lambert embayment.     

Exploration rock geochemistry — detection of trace element halos at heath steele mines (N.B., Canada) by discriminant analysis

The Heath Steele massive sulphide deposit in northern New Brunswick lies conformably within a sedimentary-volcanic sequence of probable Ordovician age which has been metamorphosed to the greenschist stage. The dominant sulphide mineral is pyrite, and the main economic minerals are sphalerite, galena, and chalcopyrite; the general grade of the ore is 5% Zn, 2% Pb, and 1% Cu.The distribution of Pb and Zn in acid volcanic rocks stratigraphically above the massive sulphides is compared with the distribution in similar rocks stratigraphically below the sulphides. Whereas there are discernable differences in the populations, there is also considerable overlap between them. To enable individual samples to be classified, linear discriminant functions were calculated for the two groups; Pb and Zn were found to be the most useful variables to separate the two populations. The functions were then tested on hanging wall and footwall samples not used in computing the functions. A halo region, extending about 1,200 ft above the sulphides and 4,000 ft along the same stratigraphic horizon as the sulphides was outlined by samples classified as “hanging wall”. Beyond the halo zone there is no significant difference in the distribution of Pb and Zn between the hanging wall and footwall acid volcanic rocks.The results demonstrate that rocks at Heath Steele, which show no evidence of mineralogical alteration attributable to mineralization, have a trace element halo of considerable extent spatially associated with the sulphides. If similar halos can be shown to be a general feature of massive sulphide deposits, the technique described should have wide application for exploration for deeply buried deposits of this type.     

Tinted windows: The presence of the UV absorbing compounds called mycosporine-like amino acids embedded in the frustules of marine diatoms

Diatom frustule-bound organic compounds presumably play an important role in biomineralization and constitute an important pool of organic matter preserved in diatom frustule-rich sediments. In this study, detailed analysis of diatom frustule-bound organic matter in opal-rich Southern Ocean plankton and sediments revealed for the first time the presence of low molecular weight, UV light absorbing compounds called mycosporine-like amino acids (MAAs). Chemically cleaned diatom frustule-derived biosilica was dissolved in HF, releasing bound or entrapped organic compounds that were subsequently characterized using liquid chromatography with UV-Vis and electrospray ionization mass spectrometry (LC/PDA/ESI-MS). Palythine ([M+H]⁺ = 245), porphyra-334 ([M+H]⁺ = 347) and shinorine ([M+H]⁺ = 333) were the most abundant MAAs detected in HF digests of plankton and sediment. Traces of asterina ([M+H]⁺ = 289), palythinol ([M+H]⁺ = 303) and palythinic acid ([M+H]⁺ = 329) were also detected. MAAs in cleaned HF digested frustules were up to two orders of magnitude more abundant than methanol extractable MAAs. MAAs are substituted with acid hydrolysable amino acid residues. Our results suggest that MAAs, and not proteins, could be responsible for the high proportion of the amino acids glycine and threonine found in hydrolysates of HF digested diatom-rich environmental samples. Total MAAs accounted for 3-27% of the carbon and 2-18% of total nitrogen in the frustules undergoing various chemical cleaning treatments. This is the first report of MAAs in close association with a mineral phase and we hypothesize that the mineral matrix could stabilize these compounds, thereby enhancing photoprotection against the harmful effects of UV light. The presence of frustule-bound MAAs in sediment cores further suggests the possibility that they could be used in compound-specific isotope analysis of diatom-bound organic matter and as indicators of past solar irradiance.