Urban and rural observations of carboxylic acids in rainwater in Southwest of China: the impact of urbanization

Seven carboxylic acids in rainwater were simultaneously determined using ion chromatography for 13 months in two different sites, Guiyang and Shangzhong, southwest of China. Results showed formic, acetic and oxalic acids were the three predominant carboxylic acids. Their volume-weighted average concentrations were 14.24, 9.35, 2.79 μmol/L in Guiyang and 4.95, 1.35, 2.31 μmol/L in Shangzhong, respectively. A distinctive diurnal pattern in carboxylic acid concentrations (daytime>nighttime, t test, p < 0.05) was observed during the growing season in Guiyang. Shangzhong witnessed higher concentration of these acids during the growing season than that during the non-growing season. Direct emissions from growing vegetation or soils probably account for the main provenance of the acids in the rural area. However, the opposite trend were found in Guiyang and the anthropogenic sources during the non-growing season were the main reason. By comparison of our result with the previous data about 20 years ago, we calculated that at least 42% of acetic acids and 69% of formic acid originated from the anthropogenic sources in Guiyang. Furthermore, the ratio of formate/acetate in gas phase larger than 1 suggest the oxidation of unsaturated hydrocarbons from the human activity and/or natural sources were the main origin of carboxylic acids in Guiyang. While The F/A ratio in gas phase was less than 1 in Shangzhong which indicate the direct emissions from biogenic sources. Oxalic acid was in similar amounts in both sites, indicating the common source of the acid.     

一种改进的电法勘探技术在探测隐伏溶洞的应用

贵州岩溶地貌分布广泛,地质情况非常复杂,严重影响重大工程建设和地下水安全,文章提出一种改进的电法勘探技术,对不良地质体勘查取得了成功应用。以直流电法理论为基础,该方法是根据视电阻率微分统计原理,由电流密度分布规律与供电电极AB两极分布总存在着一定的对应关系,在野外同一供电测线(剖面)上,通过不断加密改变供电极距AB的位置,观测测量电极MN之间的电性参数变化,求取剖面相应纵向空间上,较大深度的(近地表的)近似连续视电阻率地电断面异常。此方法在深300 m以浅的岩溶区隐患排查中取得较好勘查效果,对煤矿钻孔及页岩气钻孔的选址探测误差能够控制在7%以内,值得进一步探索实践。     

Application of a New Qeneration of Geophonesto Improve Seismic Acquisitionin Onshore-offshore Transition Areas

In this paper, we review the differences between velocity geophones （VG） and acceleration geophones （AG） and their effect on seismic signals acquired in onshore-offshore transition areas. We present a new generation of Land Piezoelectric Geophone （LPG） and analyze its performance. Our field experiments demonstrate that our new LPG can be used to substitute for VGs in order to eliminate phase, frequency and energy differences between different geophone systems commonlv used in transition areas.     

兰州大尖山地震台阵勘址

介绍了兰州大尖山核试验监测地震台阵的勘址工作，包括本地区的地质背景、气象条件以及中心建筑（CRF）和各子台建筑的的工程地质情况。该台阵投入观测后表明：台阵所在地区的气象、地质条件等观测环境完全满足全面禁止核试验条约组织国际监测系统（CTBTO／MS）勘选台阵的要求。兰州大尖山地震台阵的建成，进一步提高了甘肃省兰州市及周边地区微震活动的监测能力。     

基于离散点绘制等高线算法的研究

等高线图在实际工作中应用非常广泛，在离散点数据的基础上自动生成等高线图有许多算法。本文着重讨论了如何在采集离散点时加入编码的基础上，尽量减少或不进行人工干预，基于有约束的TIN构建方法一次性生成等高线图。实践表明该方法能够明显加快成图速度与提高等高线成图的精度。     

蒙古国植被自然恢复潜力

植被自然恢复能力评估是生态恢复实践的重要内容。基于蒙古国的MODIS EVI植被指数产品、气象数据及土壤数据,依据相似生境原则,构建了植被恢复潜力计算模式,计算得到蒙古国植被恢复潜力值（VRP,可代表在自然条件下区域植被能够恢复到的最佳状况）及植被恢复潜力指数（VRPI,代表植被生长现状与最大潜力之间的差距）,并用蒙古国纵贯铁路沿线长期围封区的采样分析数据进行了验证。结果表明：（1）蒙古国整体上具有较高的植被恢复潜力,植被自然恢复潜力值0.6—0.9;（2）受降水、气温、土壤等自然要素组配的空间分异影响,蒙古国植被自然恢复潜力具有较大的空间差异性,其中北部及东部地区为VRP高值区和VRPI低值区,植被轻度退化,且较容易恢复;南部及西部地区为VRP中低值区和VRPI高值区,植被退化程度较重,恢复难度相对较大。     

科尔沁沙地沙漠化风险评价

基于气象、土地利用类型与植被覆盖指数等数据,采用层次分析法与加权综合评分法评价了科尔沁沙地沙漠化风险。结果表明：1995、2000、2010年科尔沁沙地沙漠化风险指数平均值分别为0.420、0.428、0.437,16年来科尔沁沙地沙漠化处于高度风险水平。科尔沁沙地沙漠化风险等级在空间分布上表现为北部与西部沙漠化风险等级低,南部与东部为沙漠化高风险区。1995-2010年科尔沁沙地各旗县沙漠化风险等级存在差异,开鲁县的沙漠化风险由高度风险转变为极高度风险等级,扎鲁特旗的沙漠化风险由中度风险转变为低度风险等级,敖汉旗、巴林右旗、科尔沁区与科尔沁左翼中旗的沙漠化风险等级波动变化,其余旗县的沙漠化风险等级未变化。1995-2010年科尔沁沙地沙漠化中度,高度风险等级的面积分别减少了16 544.76、4 223.25 km²,低度,极高度风险等级的面积分别增加了16 544.76、4 223.25 km²。区域沙漠化风险的主要影响因素为年降水量、年均风速、植被覆盖指数、沙漠化土地面积与载畜量,植被覆盖指数增加有助于区域沙漠化风险的降低。     

苔藓结皮复配凹凸棒基高吸水性固沙材料的生理特性

综合性固沙技术在荒漠治理方面有着良好的发展前景。通过研究荒漠苔藓与凹凸棒基高吸水性树脂固沙材料的复配质量比与接种量对苔藓结皮的生长状态与生理特性的影响,探索和优化生物固沙与化学固沙技术相结合的技术途径。结果表明：温度和光照一定时,荒漠苔藓与凹凸棒基高吸水性固沙材料以质量比1∶4复配,以接种量500g·m^-2洒于沙面,所形成的苔藓结皮发育状况最佳。     

基于鲸鱼优化算法的长短期记忆模型水库洪水预报

洪涝灾害是世界主要自然灾害之一,优化洪水预报方案对防洪决策至关重要,然而传统水文模型存在参数多、调参受人为因素影响,泛化能力弱等问题。针对上述问题,本文提出基于改进的鲸鱼优化算法和长短期记忆网络构建自动优化参数的WOA-LSTM模型,通过优化神经网络结构进一步增强该模型的稳定性和精确度,并且建立不同预见期下的洪水预报模型来分析讨论神经网络结构与预报期之间的关系。以横锦水库流域1986—1997年洪水资料为例,其中以流域7个雨量站点的降雨以及横锦站水文资料为输入,不同预见期下洪水过程作为输出,以1986—1993年作为模型的率定期,1994—1997年作为模型的检验期,研究结果表明:(1)以峰现时差、确定性系数、径流深误差和洪峰流量误差作为评价指标,相比较于LSTM模型和新安江模型对检验期的模拟结果表明WOA-LSTM模型拥有更高的精度、预报结果更稳定;(2)结合置换特征值和SHAP法分析模型特征值重要性,增强了神经网络模型的可解释性;(3)通过改变神经网络结构在一定程度避免由于预见期增加和数据关联性下降而导致的模型预报精度下降的问题,最终实验表明该模型在预见期1~6 h下都可以满足横锦水库的洪水预报要求,可以为当地的防洪决策提供依据。     

Metamorphic,deformation, fluids and geological significance of low-temperature retrograde mylonites of Diancangshan metamorphic massif along Ailaoshan-Red River strike-slip fault zone,Yunnan, China

Diancangshan metamorphic massif is one of the four metamorphic massifs developed along the Ailaoshan-Red River strike-slip fault zone, Yunnan, China. It has experienced multi-stage metamorphism and deformation, especially since the late Oligocene it widely suffered high-temperature ductile shear deformation and exhumation of the metamorphic rocks from the deep crust to the shallow surface. Based on the previous research and geological field work, this paper presents a detailed study on deformation and metamorphism, and exhumation of deep metamorphic rocks within the Diancangshan metamorphic massif, especially focusing on the low-temperature overprinted retrogression metamorphism and deformation of mylonitic rocks. With the combinated experimental techniques of optical microscope, electron backscatter diffraction attachmented on field-emission scanning electron microscopy and cathodoluminescence, our contribution reports the microstructure, lattice preferred orientations of the deformed minerals, and the changes of mineral composition phases of the superposition low-temperature retrograde mylonites. All these results indicate that: (1) Diancangshan deep metamorphic rock has experienced early high-temperature left-lateral shear deformation and late extension with rapid exhumation, the low-temperature retrogression metamorphism and deformation overprinted the high-temperature metamorphism, and the high-temperature microstructure and texture are in part or entirely altered by subsequent low-temperature shearing; (2) the superposition of low-temperature deformation-metamorphism occurs at the ductile-brittle transition; and (3) the fluid is quite active during the syn-tectonic shearing overprinted low-temperature deformation and metamorphism. The dynamic recrystallization and/or fractures to micro-fractures result in the strongly fine-grained of the main minerals, and present strain localization in micro-domians, such as micro-shear zones in the mylonites. It is often accompanied by the decrease of rock strength and finally influences the rheology of the whole rock during further deformation and exhumation of the Diancangshan massif.