硅灰加固宁波软土的试验研究

为探索硅灰对软土的力学性质的影响,以宁波鄞州地区一种淤泥质黏土为试样,掺入不同量的硅灰,对硅灰加固土的力学性质和结构特征进行了测试。采用三轴不固结不排水剪切试验,测试分析了不同掺入量的硅灰加固土的应力应变关系,通过扫描电镜SEM照片分析了不同硅灰掺入量的硅灰加固土的结构特征。结果表明:(1)硅灰可以提高软土的黏聚力,黏聚力随着硅灰掺入量的增加而增大;(2)随着硅灰掺入量的增加,硅灰加固土的抗变形能力呈先增加后减小的趋势;(3)同一围压条件下,随着硅灰掺入量的增加,硅灰加固土的破坏偏应力逐渐增加;(4)随着硅灰掺入量的增加,硅灰加固土中大孔隙逐渐减少,小孔隙逐渐数量增加,孔径<1μm的小孔隙组分逐渐占优。     

黄陵背斜的构造几何形态及其成因探讨

黄陵背斜位于扬子克拉通的东缘,其核部出露的崆岭群被认为是扬子克拉通的基底岩石,并成为华南地质学研究的热点地区。从区域上看,黄陵背斜紧邻江汉盆地,东西两侧分别是荆当盆地与秭归盆地,黄陵背斜和周缘盆地构成明显的隆起—坳陷相互对应的构造。详细的野外观察和构造几何学的剖析表明,黄陵背斜的两翼西陡东缓,构成不对称背形的穹隆构造。在穹隆形成过程中,相应的岩石变形以顺层滑脱及相关的褶皱和小规模的逆冲断层为主,在早三叠世薄层灰岩、志留纪龙马溪组页岩、奥陶纪灰岩、寒武纪炭质灰岩以及震旦纪陡山沱组薄层灰岩广泛发育,并具有垂向缩短的重力滑脱特点,构造叠加关系指示了其形成于晚侏罗—早白垩纪之间。在构造变形分析的基础上,并深入探讨了黄陵背斜成因的3种可能的动力学背景。     

Reconstruction of hydrometeorological time series and its uncertainties for the Kaidu River Basin using multiple data sources

This paper tried to reconstruct the time series (TS) of monthly average temperature (MAT), monthly accumulated precipitation (MAP), and monthly accumulated runoff (MAR) during 1901–1960 in the Kaidu River Basin using the Delta method and the three-layered feed forward neural network with backpropagation algorithm (TLBP-FFNN) model. Uncertainties in the reconstruction of hydrometeorological parameters were also discussed. Available monthly observed hydrometeorological data covering the period 1961–2000 from the Kaidu River Basin, the monthly observed meteorological data from three stations in Central Asia, monthly grid climatic data from the Climatic Research Unit (CRU), and Coupled Model Intercomparison Project Phase 3 (CMIP3) dataset covering the period 1901–2000 were used for the reconstruction. It was found that the Delta method performed very well for calibrated and verified MAT in the Kaidu River Basin based on the monthly observed meteorological data from Central Asia, the monthly grid climatic data from CRU, and the CMIP3 dataset from 1961 to 2000. Although calibration and verification of MAP did not perform as well as MAT, MAP at Bayinbuluke station, an alpine meteorological station, showed a satisfactory result based on the data from CRU and CMIP3, indicating that the Delta method can be applied to reconstruct MAT in the Kaidu River Basin on the basis of the selected three data sources and MAP in the mountain area based on CRU and CMIP3. MAR at Dashankou station, a hydrological gauge station on the verge of the Tianshan Mountains, from 1961 to 2000 was well calibrated and verified using the TLBP-FFNN model with structure (8,1,1) by taking MAT and MAP of four meteorological stations from observation; CRU and CMIP3 data, respectively, as inputs; and the model was expanded to reconstruct TS during 1901–1960. While the characteristics of annual periodicity were depicted well by the TS of MAT, MAP, and MAR reconstructed over the target stations during the period 1901–1960, different high frequency signals were captured also. The annual average temperature (AAT) show a significant increasing trend during the 20th century, but annual accumulated precipitation (AAP) and annual accumulated runoff (AAR) do not. Although some uncertainties exist in the hydrometeorological reconstruction, this work should provide a viable reference for studying long-term change of climate and water resources as well as risk assessment of flood and drought in the Kaidu River Basin, a region of fast economic development.     

黑钨矿类质同象系列的红外光谱研究

本文是对黑钨矿类质同象系列研究的一个组成部分。测试结果表明在中红外区及远红外区的某些吸收谱带,其频率和强度的变化与黑钨矿中两端员组份FeWO_4和MnWO_4的相对含量有良好的线性相关关系。文中给出了频率变化的相关方程和相关图,并讨论了频率位移和强度变化的内部机制。     

中国上市公司的时空变化及机制研究

针对在中国地区发展不均衡的态势下,上市公司分布格局时空演变问题,该文对2009-2017年中国大陆各省上市公司的数量和总资产采用Local Moran’s I指数与Getis-Ord Gi*统计量进行研究,分析了中国大陆上市公司的空间分布格局和时间演变趋势,总结出中国上市公司相关指标的高值聚集和高低聚集分布格局、热点区域及其经济辐射能力。并且以北京、上海和广东为热点区域典型代表,从上市公司产业结构和区域经济发展两方面对时空变化机制的成因进行深入探讨。     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.     

2.5-D DC Resistivity Modeling Considering Flexibility and Accuracy

We highlighted the flexibility of using unstructured mesh together with the local refinement by a resistivity model with complicated topography. The effect of topography is emphasized. Based on this, we calculated a specific class of layered models and found that the accuracy is not always satisfactory by utilizing the standard approach. As an improvement, we employed the layered earth as the reference model to calculate the wavenumbers. The comparison demonstrates that the accuracy is considerably improved...     

The Evolutionary History of Ore-forming Processes of Metallic Ore Deposits in Northern Guangxi1

Abstract The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late times; in the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.     

三门峡市冰雹出现规律与防雹工作探讨

利用1971-2005年三门峡市冰雹天气过程资料,分析了冰雹时空分布特征、主要影响系统、本站要素指标及雷达回波特征等,结果表明:渑池县降雹次数最多,灵宝次之,卢氏最少;降雹集中在4-8月,13-19时降雹几率最高.三门峡降雹的天气形势主要有蒙古-华北冷槽、冷涡型和西北气流型.受上述天气系统影响时,500 hPa有冷平流,若地面连续2～3天增温增湿,有可能出现冰雹天气.此外,雹云雷达回波强度＞50 dBz,云顶高度＞10 km,云顶温度＜-40℃,垂直积分液态含水量有明显的跃升.是降雹的前兆.     

东北冷涡南落型强对流天气的潜势预报分析

通过2005-2008年4-6月Micaps资料,查找500 hPa东北有冷涡,500 hPa和700 hPa江苏境内为大片的西北气流,当天午后到夜里出现强对流天气的若干典型个例,借助Micaps系统通过对一些个例的物理量资料分析,得出它们共同的发生强对流天气的机理;同时还分析得出诊断该类对流天气的不太适合使用的物理量和较适合使用的物理量;并分析个例的大气探空层结曲线,得出它们的对流层结与其它类型的区别,并剖析它们的一日转变情况;同时用Q矢量锋生函数方法分析,发现低层强锋生区域与强对流天气区域有较好的对应关系,锋生函数正值中心区域常出现个别站龙卷或大范围冰雹.