Electron microscopy study of domain structure due to phase transitions in natural perovskite

Transmission electron microscopy on natural calcium metatitanate perovskite (dysanalyte) reveals the following twin laws in the orthorhombic (space group Pbnm) phase: reflection twins on the {110} and {112} planes, and 90° rotation twins about the [001] axis (referred to as [001]_90° twin). Single crystals that were heattreated and quenched from above 1585 K exhibit a dramatic change in domain structure compared with the starting material and specimens quenched from T < 1470=" k.=" mutually=" perpendicular=" {110}=" and=">_90° twins are observed throughout the crystal, forming a cross-hatched domain texture. 1/2[001] antiphase domains, which are very rarely observed in the starting material, also become dominant in the crystal. This change in domain structure is interpreted as due to a structural phase transition in perovskite at a temperature below 1585 K. From the point symmetry elements that describe the twin laws and the translational elements that relate the antiphase domains, the most likely phase near 1585 K is tetragonal with space group P4/mbm. These results are consistent with high-temperature powder X-ray diffraction study. On the other hand, density of the {112} twins is increased significantly in the crystal quenched from 1673 K. Twin domains are either bound by mutually perpendicular {110} and (001) walls, or by {112} walls with {110} twin domains within the polygonal {112} domains. Both twin density variation and domain morphology suggest that the crystal may be cubic at this temperature. Microstructure of a single crystal deformed at 1273 K and 3.5 GPa (within the orthorhombic stability field) is morphologically quite distinct from that of the heat-treated specimens. Dislocations dominate the microstructure and often interact with twin domain boundaries.A National Science Foundation Science and Technology Center     

Determination of Negative Friction and Horizontal Displacement for Steel Pipe Piles

This paper presents a new instrument, Sliding-Micrometer-ISETH, and its application to determination of negative friction of piles. This instrument is now used to determine negative friction and horizontal displacement of steel pipe piles for a huge power station in East of China. Eight month’s measurements demonstrate that this instrument is specially suitable for long-term measurement of variety of geotechnical engineering. In the case of stack load with a high of 4.6m, the measured maximum axial load is about 800 KN with the rising rate of 30 KN per month, whose critical value will be lower than that calculated according to effective stresses and approximate to that, if additional pore pressure is considered. The bending stress is higher than allowable stress, and the horizontal displacement is over 600 mm in a pile located at boundary of stack area. A comparison analysis is made for measured results with the data of ground settlement, horizontal displacement and pore pressure.     

科学家的人文关怀--读80年前德日进第一次来华时的书信

文章通过读德日进1923～1924年第一次来华工作期间的书信，介绍了德日进思想中的几个重要侧面：其宗教思想中的“上帝”及“现世”；学术研究应跨学科综合进行；精神生活的首要地位以及如何看待东西方文化的异同。     

新变种矿物——铌铁锐钛矿及其共生矿物钕易解石

铌铁锐钛矿是含铌、铁的锐钛矿变种。呈土黄色、褐棕色,板状或土粒状。反射率589nm,15.9％,显微硬度H_v=275.9kg/mm~2。计算比重4.4g/cm~3。主要化学成分Nb_2O_534.92—44.3％,TiO_2 29.38—37.58％,Fe_2O_3 14.94—17.19％。化学式:(Ti_(0.44)Nb_(0.31)Fe_(0.25))_(1.00)O_2X射线分析表明该矿物属四方晶系,α=3.828±0.002,c=9.682±0.009,空间群I4_1/amd,Z=4。 共生矿物钕易解石,深红色者变生现象轻微;浅黄色钕易解石与铌铁锐钛矿可能形成于稍晚、较低温度条件下的矿化过程。     

二滩电站坝肩厂房三维有限元分析及围岩变形观测反分析

本文首先用应力函数法对二滩电站地下厂房区的着干地应力实测点进行拟合,给出了三维连续初始应力场。然后对三个大型洞室形成的厂房群进行三维有限元分析,得出了洞群围岩中破损区、应力弱化区及高应力区的分布,并就三维分析与二维分析的结果进行了对比。可以认为,二维分析不一定比三维分析更安全,因为三维分析得出的拉破裂范围更大些。文中还提出了一个用弹性有限元分析近似推求裂隙围岩破裂范围的方法。最后介绍在该现场的一个试验洞中进行围岩变形观测及反分析的结果,该反分析较好的验证了围岩力学参数及地应力测量的结果。     

Ree geochemistry characteristics of stratigraphic samples in the abalieke region,Western Kunlun北大核心

The Abalieke region locats in the central section of the western Kunlun polymetallic (Pb, Zn, Cu, etc) ore belt, an area with major potential for further base metal deposit discoveries. This paper reports REE data for 82 samples from 8 stratigraphic sections for Huoshilafu formation in the Abalieke region. To attempt to solve the origin of ore-forming materials using REE geochemistry. Although total REE contents are quite variable ( Σ REE = 7. 52 × 10-6-220. 70 × 10-6, ΣLREE = 5. 82 × 10-6-198. 46 × 10-6, ΣHREE = 1. 49 × 10-6- 32. 74 × 10-6 and Y = 4. 77 × 10-6-91. 30 × 10-6) , chondrite-normalized REE patterns of the majority of samples are uniformly LREE-enriched (averaging ΣLREE/ΣHREE = 6. 57), with remarkably fractionation of LREE and HREE [averaging (La/Yb)N = 8. 20], slightly negative Eu anomalies (averaging δEu = 0. 77) and insignificant Ce anomalies (averaging δCe = 0. 88). The results demonstrate that REE characteristics of stratigraphic samples from Abalieke region are similar to those of rock and ore samples from other representative deposits (Tiekelike, Tamu, Kalangu, Tuokuziate) in the western Kunlun polymetallic ore belt, which indicate a close genetic relationship between the ore-forming materials and the host strata for the majority of deposits in this belt.     

东海陆架盆地南部中生界沉积模式

在沉积相综合分析基础之上,通过地震相分析的手段明确了东海陆架盆地南部中生界的沉积特征;结合古地理背景分析,建立了该区侏罗纪和白垩纪的沉积模式。侏罗纪时雁荡低凸起和瓯江凹陷均未形成,闽江凹陷和基隆凹陷连为一体,物源来自浙闽隆起区,发育滨浅海沉积体系,火山作用较为强烈。白垩纪晚期-古新世,随着太平洋板块俯冲角度的加大,浙闽隆起区发生裂陷,雁荡低凸起形成。西部的瓯江凹陷沉积了一套陆相的冲积扇-河流-三角洲-湖泊沉积体系;由于此间台北低凸起尚未起到分割作用,东部的闽江凹陷与基隆凹陷仍然连为一体,物源来自浙闽隆起带和台北水下火山岩带,发育滨浅海沉积体系,火山作用影响强烈。     

新疆沙尔湖煤田煤层特征及对比

沙尔湖煤田含煤地层为中侏罗统西山窑组,根据岩性特征、含煤性以及其组合特征,将西山窑组分为上、中、下三段,可采煤层均分布在中段,煤层层数多,厚度变化较大,可采煤层6～27层,可采煤层总厚114.35～139.90m,根据各煤层之间的沉积间距及其与上、下岩层的旋回韵律,又将其划分为Ⅰ、Ⅱ、Ⅲ煤组。以大量地质资料为基础,总结了主要含煤层段的岩相组合特点,揭示了各煤层间的差异及组合特征,利用有效的对比方法,特别是数字测井在煤层对比中的应用,对可采煤层进行系统对比分析,对煤层对比的可靠性进行评价,保证了层位对比的正确可靠,并解决了勘查工作中终孔层位难以确定的问题,为正确划分煤系地层、准确估算煤炭资源量提供了可靠依据。     

山西省炼焦煤的粘结性和结焦性探讨

山西炼焦煤资源不仅分布广泛,煤类齐全,而且资源丰富,粘结性强、结焦性好。大量分析数据显示山西霍西煤田霍州矿区粘结性较好,特别是南部的霍州—乔家湾区,煤的粘结指数为80～100,胶质层厚度为24～33mm;沁水煤田东部潞安矿区煤的粘结性较差,为全省最低,一般在13～68,胶质层厚度在0～7.5mm。单独炼焦性能最好的是西山古交矿区、霍西汾西矿区和柳林三交矿区的主焦煤,其次是霍西的肥煤和乡宁的焦煤,比较差的是大同的气煤,潞安和西山的瘦煤。     

基于遥感技术的龙门山前山带烃类微渗漏信息提取

通过对龙门山前山带含油区与非含油区的岩石、土壤、植被等进行测试,认为烃类微渗漏会造成地表热异常、红层褪色、低价铁富集以及粘土矿化等现象,并对研究区的粘土矿物、Fe3+、Fe2+与烃类的波普曲线特征进行了分析对比。以ETM卫星图像为主要信息源,选择了TM2/TM3、TM3/TM4和TM5/TM7进行比值处理,从光谱数据中直接提取出碳酸盐化、粘土矿化、红层褪色等油气蚀变信息,并在对研究区遥感地质解译的基础上,指出烃渗漏信息异常晕主要沿断裂带分布,特别在不同走向断裂的交汇区域分布面积和强度较大,而在已知油气圈闭区域,信息晕主要呈碎片状或斑点状零散分布,且以低值异常为主。根据烃渗漏异常的分布特征,提取出石板滩、中坝、孝泉、聚源、鸭子河以及邛崃等遥感信息异常区块。