Postglacial relative sea-level history: sediment and diatom records of emerged coastal lakes, north-central Kola Peninsula, Russia

Sediment cores recovered from four emerged lakes (54, 41, 22, and 7 m a.s.l.) provide new data on the deglaciation and relative sea-level history of the Murman coast, Kola Peninsula. The transition from marine to lacustrine sediment is identified in the cores by analysis of sediment physical properties and diatom assemblages. Fourteen AMS-radiocarbon ages on organic macrofossils isolated from core sediment provide chronology for the records. Basal ages from two of the cores indicate deglaciation of the area prior to 11000 BP. Radiocarbon ages associated with the marine-lacustrine sediment transition in the cores further constrain the emergence history of the area. The prominent late-glacial shoreline on the Murman coast (48 m a.s.l.) is dated to c . 10500–10300 BP, the emergence ages of lake basins 54 and 41 m a.s.l. Glaciofluvial terraces graded to this shore level indicate remnant glaciers on the north-central Kola Peninsula during the Younger Dryas.     

Geometry and facies of Tertiary clinothems, Spitsbergen

Sandstone clinothems from the Battfjellet Formation (Palaeogene) on Spitsbergen are locally exceptionally well preserved along depositional dip-parallel mountainsides. The clinothems are more than 1 km wide and more than 100 m thick. Superposition of several sandstone clinothems separated by mudstones reflects repeated shoreline progradation and transgression. Deposition took place partly on‘post-transgressional’ depositional shelves, and partly by contributing seaward-sloping wedges, or clinothems, to a ramp progradation. Shorelines dominated both by mouth bar and shoreface environments have been identified. The clinothems are organized into an overall progradational architecture with a geometry having features in common with progradational seismic facies.     

Dolomitization of the Devonian Swan Hills Formation, Rosevear Field, Alberta, Canada

The Swan Hills Formation (Middle-Upper Devonian) of the Western Canada Basin is host to several NW-SE-trending gas fields developed in massive replacement dolostone. One of these, the Rosevear Field, contains two major dolostone trends along opposing margins of a marine channel that penetrates into a platform-reef complex. Dolostones consist predominantly of branching and bulbous strdmatoporoid floatstones and rudstones with well-developed moldic and vuggy porosity. Replacement dolomite is coarsely crystalline (100-600 μm), inclusion-rich, composed of euhedral through anhedral crystals and has a blotchy to homogeneous red cathodoluminescence. Geochemically, replacement dolomite is characterized by (i) nearly stoichiometric composition (50.1-51.1 mol% CaCO₃), (ii) negative δ¹⁸O values (mean=-7.5‰, PDB) and (iii) variable ⁸⁷Sr/⁸⁶Sr ratios ranging from values similar to Late Devonian-Early Mississippian seawater (～0.7082) to radiogenic compositions comparable to saddle dolomite cements (>0.7100). Dolomitization began after widespread precipitation of early, equant calcite spar and after the onset of pressure solution, implying that replacement dolomite formed in a burial environment. Oxygen isotope data suggest that dolomite formed at 35-75°C, temperatures reached during burial in Late Devonian through Jurassic time, at minimum depths of 450 m. The linear NW-SE orientation of most dolomite fields in the Swan Hills Formation is suggestive of fault control on fluid circulation. Two models are proposed for fault-controlled circulation of dolomitizing fluids at the Rosevear Field. In the first, compaction-driven, updip fluid migration occurred in response to basin tilting commencing in the Late Palaeozoic. Deep basinal fluids migrating updip were focused into channel-margin sediments along fault conduits. The second model calls upon fault-controlled convective circulation of (i) warm Devonian-Mississippian seawater or (ii) Middle Devonian residual evaporitic brines. The overlap in ⁸⁷Sr/⁸⁶Sr and δ¹⁸O compositions, and similar cathodoluminescence properties between replacement and saddle dolomites provide evidence for neomorphism of some replacement dolomite. Quantitative modelling of Sr and O isotopes and Sr abundances suggests partial equilibration of some replacement dolomite with hot radiogenic brines derived during deep burial of the Swan Hills Formation in the Late Cretaceous-Palaeocene. Interaction of replacement dolomite with deep brines led to enrichment in ⁸⁷Sr while leaving δ¹⁸O similar to pre-neomorphism values.     

Concentrations of B,Sm, Gd and H in 24 Reference Materials*

Analysis of 24 reference materials for B, Sm, Gd, H, has been carried out over several years, using prompt gamma neutron activation analysis. The results are compared with values obtained by other workers, in order to better calibrate these standards. In most cases our results of repeated analysis of RMs show agreement with results from other laboratories, using various methods. A djustments to working values are proposed in some cases.     

Basalt and Sediment Geochemistry and Magma Petrogenesis in a Transect from Oceanic Island Arc to Rifted Continental Margin Arc: the Kermadec--Hikurangi Margin, SW Pacific

Sediment mixing and recycling through a subduction zone canbe detected in lead isotopes and trace elements from basaltsand sediments from the Kermadec-Hikurangi Margin volcanic arcsystem and their coupled back-arc basins. Sr, Nd and Pb isotopesfrom the basalts delineate relatively simple, almost overlapping,arrays between back-arc basin basalts of the Havre Trough-NgatoroBasin (⁸⁷Sr/⁸⁶Sr = 0.70255; _Nd=+9.3; ²⁰⁶Pb/²⁰⁴Pb = 18.52; ²⁰⁸Pb/²⁰⁴Pb= 38.18), island arc basalts from the Kermadec Arc togetherwith basalts from Taupo Volcanic Zone (⁸⁷Sr/⁸⁶Sr 0.7042; _Nd= +5; ²⁰⁶Pb/²⁰⁴Pb= 18.81; ²⁰⁸Pb/²⁰⁴Pb = 38.61), and sedimentsderived from New Zealand's Mesozoic (Torlesse) basement (⁸⁷Sr/⁸⁶Sr 0.715; _Nd —4; ²⁰⁶Pb/²⁰⁴Pb 18.86; ²⁰⁸Pb/²⁰⁴Pb 38.8).Basalts from the arc front volcanoes have high Cs, Rb, Ba, Th,U and K, and generally high but variable Ba/La, Ba/Nb ratios,characteristic of subduction-related magmas, relative to typicaloceanic basalts. These signatures are diluted in the back-arcbasins, which are more like mid-ocean ridge basalts. Strongchemical correlations in plots of SiO₂ vs CaO and loss on ignitionfor the sediments (finegrained muds) are consistent with mixingbetween detrital and biogenic (carbonate-rich) components. Otherdata, such as Zr vs CaO, are consistent with the detrital componentcomprising a mixture of arc- and continent-derived fractions.In chondrite-normalized diagrams, most of the sediments havelight rare earth element enriched patterns, and all have negativeEu anomalies. The multielement diagrams have negative spikesat Nb, P and Ti and distinctive enrichments in the large ionlithophile elements and Pb relative to mantle. Isotopic measurementsof Pb, Sr and Nd reveal restricted fields of Pb isotopes butwide variation in Nd and Sr relative to other sediments fromthe Pacific Basin. Rare K-rich basalts from Clark Volcano towardthe southern end of the oceanic Kermadec Island Arc show unusualand primitive characteristics ( 2% K₂O at 50% SiO₂, Ba 600p.p.m., 9–10% MgO and Ni > 100 p.p.m.) but have highlyradiogenic Sr, Nd and Pb isotopes, similar to those of basaltsfrom the continental Taupo Volcanic Zone. These oceanic islandarc basalts cannot have inherited their isotope signatures throughcrustal contamination or assimilation—fractional crystallizationtype processes, and this leads us to conclude that source processesvia bulk sediment mixing, fluid and/or melt transfer or somecombination of these are responsible. Although our results showclear chemical gradients from oceanic island arc to continentalmargin arc settings (Kermadec Arc to Taupo Volcanic Zone), overlapbetween the data from the oceanic and continental sectors suggeststhat the lithospheric (crustal contamination) effect may beminimal relative to that of sediment subduction. Indeed, itis possible to account for the chemical changes by a decreasenorthward in the sediment flux into the zone of magma genesis.This model receives support from recent sediment dispersal studiesin the Southern Ocean which indicate that a strong bottom current(Deep Western Boundary Current) flows northward along the easterncontinental margin of New Zealand and sweeps continental derivedsediment into the sediment-starved oceanic trench system. Thetrace element and isotopic signatures of the continental derivedcomponent of this sediment are readily distinguished, but alsodiluted in a south to north direction along the plate boundary. KEY WORDS: subduction zone basalts; sediments; Sr-, Nd-, Pb-isotopes; trace elements ^*Present address: School of Earth Sciences, University of Melbourne, Parkville, Vic. 3052, Australia.     

Pyrometamorphism of Phyllites by a Dolerite Plug

The progressive thermal metamorphism of Dalradian phyllitesadjacent to a Tertiary basic plug is traced petrographicallyfrom the initial stages of breakdown of micaceous minerals tothe eventual development, in places near the contact, of rheomorphicmaterial of granitic composition and complementary highly desilicatedferromagnesian residues. Chemical analyses of unmetamorphosedand thermally metamorphosed country rock, granophyres, and desilicatedresidues, are used to illustrate the chemistry of these metamorphicprocesses and to suggest approximate temperature-pressure conditionsunder which they took place. The petrological significance ofthe emery-like residues is discussed briefly.     

IDENTIFICATION OF SEA-FLOOR SEDIMENTS USING UNDERWAY ACOUSTICS*

Laboratory measurements, and a few in situ observations, show that saturated marine sediments have interdependent mechanical and acoustical properties, Acoustically, of particular importance are the acoustic impedance, velocity of sound and the sound attenuation coefficient of the sediment. The first two properties can be measured relatively easily from a surface ship; the measurement of attenuation however, is more problematical. It is suggested that this can be achieved by a quantitative treatment of the acoustic data collected during routine sub-bottom profiling over a variable thickness of superficial sediments. In the assessment of four different sediment locations in the Irish Sea it was found that quantitative treatment of the acoustic signals yielded both a value of the attenuation coefficient as well as a measure of the frequency dependence of the attenuation. In addition a statistical analysis of the signal intensities seems to provide an indication of the relative roughness of the bottom and sub-bottom interfaces. From the wide range of information provided the mechanical properties of the sea-floor sediment may be estimated.     

Postglacial climate and vegetation history, north-central Kola Peninsula, Russia: pollen and diatom records from Lake Yarnyshnoe-3

A sediment core from Lake Yarnyshnoe-3 (69°04'N; 36°04'E), an emerged coastal lake from the tundra of the north-central Kola Peninsula, has been analyzed for fossil pollen and diatoms. The pollen record shows the Younger Dryas event marked by increasing Artemisia coupled with decreases in Poaceae, Cyperaceae and Salix at c. 10 700 to 10 000 BP. This core provides the first well-defined palynological record of the Younger Dryas event on the Kola Peninsula. Stomates from Pinus were recovered from the core interval between 8000 and 6000 BP. The stomates, coupled with elevated values of pine pollen, indicate that Pinus sylvestris grew near the arctic coastline of the central Kola Peninsula in the middle Holocene. However, the small number of stomates suggests that pines were not plentiful. The diatom record from the core reflects basin isolation from the sea and indicates additional limnological changes during the climate transition between c. 5000 and 4000 BP. The broadly similar climate and vegetation history on the north-central Kola Peninsula and in Fennoscandia demonstrates the propagation of late glacial and Holocene climate events from the North Atlantic region into the Eurasian Arctic.     

Late Devensian and Holocene depositional environments associated with the coversand around Caistor, north Lincolnshire, UK

Sand deposits described at three sites near Caistor, north Lincolnshire (UK), provide a record of Late Devensian (Late Weichselian) to Holocene palaeoenvironments at the western margin of the European sand belt. Thermoluminescence (TL) and radiocarbon analyses provide for the first time a chronological framework for the demise of proglacial Lake Humber and the onset of coversand deposition. The reconstructed palaeoenvironmental history suggests that proglacial Lake Humber had receded from its initial high-level stand before c. 18 ka, exposing the lake floor to periglacial conditions marked by the development of thermal contraction cracks. In the period between c. 18 and 14 ka, sand-depositional processes changed from dominantly fluvial to aeolian. The fluvial activity was possibly a consequence of ameliorating winter climates between c. 17 and 16 ka. The aeolian coversand deposition in this period has not been previously recognized in Britain and correlates with the Older Coversand II and Younger Coversand I deposits elsewhere in the European sand belt. Peat accumulation followed during the Windermere (Bølling/Allerød) Interstadial and early part of the Loch Lomond Stadial (Younger Dryas) before regionally extensive coversand deposition took place in the later part of the Loch Lomond Stadial. This coversand correlates with the widespread Younger Coversand II deposits found both within the UK and across the European sand belt. The Holocene has been characterized by widespread stability with the development of soils on the coversand punctuated with periods of localized reworking through to the present day.