Lymanα forests and the evolution of the universe

The Lyα forest absorption lines in the spectra of quasars are interpreted as caused by the crossings of the light beam with the walls of a bubble structure (expanding with the Hubble flow only). Then, the typical separation between the absorption lines is proportional to the mean size of the bubbles. The variable factor is the expansion rate H[z]. The Friedmann regression analysis of the observed line separations determines the density parameter ω₀ and the normalized cosmological term λ₀ = λc²/3H²₀ of the appropriate cosmological model: ω₀ = 0.014 ± 0.002, λ₀ = 1.080 ± 0.006. Depending on the Hubble parameter this method reveals the values of the present mean matter density pm,0 = 2.6 h² · 10⁻²⁸ kg m⁻³ and of the cosmological constant Λ = 3.77 h² · 10⁻⁵² m⁻² (with h = H₀/(100 km/s·Mpc)). According to our analysis all models with Λ = 0 must be excluded. The curvature of space is positive. The curvature radius R₀ is 3.3 times the Hubble radius (c/H₀). The age t₀ is 2.8 times the Hubble age (H₀⁻¹).     

High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

The effect of cracks on the thermal expansion of rocks

Thermal expansion during the first heating cycle at atmospheric pressure was measured in several directions in seven igneous rocks between 25° and 400°C at slow heating rates. The coefficient of thermal expansion measured under these conditions increases more rapidly as temperature is increased than the average thermal expansion coefficient of the constituent minerals. The “extra” expansion is attributed to the formation of cracks by differential expansion of mineral grains. The presence of such cracks in the rocks during the cooling part of the cycle and during any subsequent heating and cooling cycles will result in a substantial decrease in the coefficient of thermal expansion as compared to that measured during the first heating cycles. The effect of cracks initially present in a rock was studied by measuring the full tensor of the coefficient of thermal expansion on two rocks with anisotropic crack distributions. In these two rocks the coefficient of thermal expansion is least in the direction perpendicular to the plane of greatest crack concentration. The implication of our data is that thermal expansion depends greatly on the fracture state of the rock. Both the fractures in the rock and the boundary conditions on the rock are significant for the interpretation of thermal expansion measurements and for their application to other problems.     

The contribution of sulphur dioxide from ablating micrometeorites to the atmospheres of Earth and Mars

Atmospheric composition is a key control on climate and the habitability of planetary surfaces. Ablation of infalling micrometeorites has been recognised as one way in which atmospheric chemistry can be changed, especially at times in solar system history when the infall rates of exogenous material were high. Despite its potential to influence climate and habitability, extraterrestrial sulphur dioxide is currently an unquantified contribution to the atmospheres of the terrestrial planets. We have used flash pyrolysis to simulate the atmospheric entry of micrometeorites and Fourier-transform infrared spectroscopy to identify and quantify the sulphur dioxide produced from the carbonaceous meteorites Orgueil (CI1), ALH 88045 (CM1), Cold Bokkeveld (CM2), Murchison (CM2) and Mokoia (CV3). We have used this approach to understand the introduction of sulphur dioxide to the atmospheres of Earth and Mars from infalling micrometeorites. Sulphates, present in carbonaceous chondrites at a few wt.%, are resistant to thermal decomposition, limiting the yields of sulphur dioxide from unmelted micrometeorites. Infalling micrometeorites are a minor source of present-day sulphur dioxide on Earth and Mars, calculated to be up to around 2400 tonnes and about 350 tonnes, respectively. During the Late Heavy Bombardment (LHB), the much greater infall rates of micrometeoritic dust are calculated to be associated with average production rates of sulphur dioxide of around 20 Mt yr⁻¹ for the early Earth and 0.5 Mt yr⁻¹ for early Mars, for a LHB of 100 Myr. These rates of delivery of sulphur dioxide at high altitudes would have reduced the solar energy reaching the surfaces of these planets, via scattering of sunlight by stratospheric sulphate aerosols, and may have had detrimental effects on developing biospheres by promoting cooler climates and reducing the probability of liquid water on planetary surfaces.     

The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.     

Modeling preferential flow in reactive barriers: implications for performance and design

Reactive barriers are passive and in situ ground water treatment systems. Heterogeneities in hydraulic conductivity (K) within the aquifer-reactive barrier system will result in higher flux rates, and reduced residence times, through portions of the barrier. These spatial variations in residence time will affect the treatment capacity of the barrier. A numerical flow model was used to evaluate the effects of spatial variations in K on preferential flow through barriers. The simulations indicate that the impact of heterogeneities in K will be a function of their location and distribution; the more localized the high K zone, the greater the preferential flow. The geometry of the reactive barrier will also strongly influence flow distribution. Aquifer heterogeneities will produce greater preferential flow in thinner barriers compared to thicker barriers. If the barrier K is heterogeneous, greater preferential flow will occur in thicker barriers. The K of the barrier will affect the flow distribution; decreasing the K of the barrier can result in more even distribution of flow. Results indicate that less variable flow will be attained utilizing thicker, homogeneous barriers. The addition of homogeneous zones to thinner barriers will be effective at redistributing flow only if installed immediately adjacent to both the up- and downgradient faces of the barrier.     

A crustal suture and lineament in North Africa

A possible suture between an old craton in West Africa and the Arabian—Nubian shield is marked by a persistent zone of Phanerozoic weakness. This zone extends between the Nile and Niger deltas and passes through the Qattara embayment, along the Bahariya fault, through the Kufra basin, between the Tibesti and Jabal al Uwaynat massifs, through the Bahr el Ghazal and Lake Chad areas, and along the Benoue trough.