Paleomagnetism of the latest Precambrian/Cambrian Unicoi basalts from the Blue Ridge, northeast Tennessee and southwest Virginia: evidence for Taconic deformation

Three components of magnetization have been observed in ninety-six samples (twelve sites) of amygdaloidal basalts and “sedimentary greenstones” of the Unicoi Formation in the Blue Ridge Province of northeast Tennessee and southwest Virginia. These components could be isolated by alternating field as well as thermal demagnetization. One component, with a direction close to that of the present-day geomagnetic field is ascribed to recent viscous remanent magnetizations; another component, with intermediate blocking temperatures and coercivities, gives a mean direction of D = 132°, I = +43°,α₉₅ = 9° for N = 10 sites before correction for tilt of the strata. This direction and the corresponding pole position are close to Ordovician/Silurian data from the North American craton and we infer this magnetization to be due to a thermal(?) remagnetization during or after the Taconic orogeny. This magnetization is of post-folding origin, which indicates that the Blue Ridge in our area was structurally affected by the Taconic deformation. The third component, with the highest blocking temperatures and coercivities, appears to reside in hematite. Its mean direction, D = 276°, I = ?17°,α₉₅ = 13.8° for N = 6 sites (after tilt correction) corresponds to a pole close to Latest Precambrian and Cambrian poles for North America. The fold test is inconclusive for this magnetization at the 95% confidence level because of the near-coincidence of the strike and the declinations. We infer this direction to be due to early high-temperature oxidation of the basalts, and argue that its magnetization may have survived the later thermal events because of its intrinsic high blocking temperatures. A detailed examination of the paleomagnetic directions from this study reveals that the Blue Ridge in this area may have undergone a small counterclockwise rotation of about 15°.     

Longitudinal velocity patterns and bed morphology interaction in a rill

Present‐day understanding of rill dynamics is hampered by a lack of detailed data on velocity distributions in rills. The latter are dif?cult to collect with traditional techniques due to the very low water depths and the relatively high ?ow velocities in rills. The objectives of this paper were to investigate the feasibility of miniaturized acoustic Doppler velocimeter (mADV) measurements in rill ?ow and to explore longitudinal variations in ?ow velocities and their relationship with rill bed morphology. Detailed data on longitudinal ?ow velocity were required to achieve these objectives. A 1·8 m long rill was formed freely in a ?ume at 5° slope and 0·001 m³ s^?1 discharge. Rill topography was characterized by an alternation of steps and pools. The ?ume surface was then ?xed to preserve rill roughness. A topographical scanning of the entire ?ume surface was made. Velocity was measured with a mADV along the rill, and at different depths. Flow depth in a longitudinal direction was also measured using an elevation gauge. A strong relationship exists between rill topography and ?ow hydraulics. Over steps, ?ow was unidirectional and rapidly accelerating until a threshold Froude number (Fn) value between 1·3 and 1·7 was reached and a hydraulic jump occurred leading to the formation of a pool. In the pool, the ?ow pattern was multidirectional and complex. The ?ow was subcritical when leaving the pool and accelerated over the next step until the threshold Froude number value was again reached. Energy loss in the rill was concentrated in the pools, mainly due to the action of a hydraulic jump. This mechanism of energy dissipation appeared to be an essential factor in rill formation and bedform evolution. Copyright © 2004 John Wiley & Sons, Ltd.     

Soil detachment and transport on field‐ and laboratory‐scale interrill areas: erosion processes and the size‐selectivity of eroded sediment

Field‐ and laboratory‐scale rainfall simulation experiments were carried out in an investigation of the temporal variability of erosion processes on interrill areas, and the effects of such variation upon sediment size characteristics. Poorly aggregated sandy soils from the semi‐arid environment of Senegal, West Africa, were used on both a 40 m² field plot and a 0·25 m² laboratory plot; rainfall intensity for all experiments was 70 mm h^?1 with a duration of 1 to 2 hours. Time‐series measurements were made of the quantity and the size distribution of eroded material: these permitted an estimate of the changing temporal balance between the main erosion processes (splash and wash). Results from both spatial scales showed a similar temporal pattern of runoff generation and sediment concentration. For both spatial scales, the dominant erosional process was detachment by raindrops; this resulted in a dynamic evolution of the soil surface under raindrop impact, with the rapid formation of a sieving crust followed by an erosion crust. However, a clear difference was observed between the two scales regarding the size of particles detached by both splash and wash. While all measured values were lower than the mean weight diameter (MWD) value of the original soil (mean 0·32 mm), demonstrating the size‐selective nature of wash and splash processes, the MWD values of washed and splashed particles at the field scale ranged from 0·08 to 0·16 mm and from 0·12 to 0·30 mm respectively, whereas the MWD values of washed and splashed particles at the laboratory scale ranged from 0·13 to 0·29 mm and from 0·21 to 0·32 mm respectively. Thus only at the field scale were the soil particles detached by splash notably coarser than those transported by wash. This suggests a transport‐limited erosion process at the field scale. Differences were also observed between the dynamics of the soil loss by wash at the two scales, since results showed wider scatter in the field compared to the laboratory experiments. This scatter is probably related to the change in soil surface characteristics due to the size‐selectivity of the erosion processes at this spatial scale. Copyright © 2006 John Wiley & Sons, Ltd.     

Carbonyls and nonmethane hydrocarbons at rural European sites from the mediterranean to the arctic

Results of regular measurements during 1992–1995 of hydrocarbons and carbonyl compounds for a number of rural European monitoring sites are presented. The measurements are part of the EMEP programme for VOC measurements in Europe. In addition, several years of regular measurements are included from the Norwegian stations Birkenes at the south coast, and Zeppelin Mountain on Spitsbergen in the Arctic. The sampling frequency has been about twice per week throughout the years, implying that a substantial amount of measurement data are available. Almost all the chemical analyses have been performed by one laboratory, the EMEP Chemical Co-ordinating Centre located at NILU, which avoids problems of intercomparison and intercalibration among different laboratories. For the measured concentrations both seasonal and geographical variations are shown and discussed. The diurnal cycles of the hydrocarbon concentrations were studied in detail at one site, where the grab samples by EMEP where compared with a parallel continuous sampler, operated by EMPA, Switzerland. Hydrocarbons linked to natural gas and fuel evaporation become well mixed into the Arctic in the winter, whereas combustion products show a latitudinal gradient. The sum of oxygenated species constitutes about 5–15% of the sum of C₂–C₅ hydrocarbons in winter. In summer they are almost equal in magnitude, consistent with an increasing oxidation of hydrocarbons.     

Sr and Ar isotope studies of detrital smectites from the Atlantic Ocean (D.S.D.P., Legs 43, 48 and 50)

Mineralogical, morphological and isotopic (RbSr and KAr) determinations were made on some detrital smectites of Palaeocene and Cenomanian ages from D.S.D.P. drillings in the Atlantic Ocean. These minerals are not inert in their depositional environment; authigenic laths grow on detrital sheets with sharp borders. This authigenesis could occur slightly after deposition in a closed system, for some of these smectites. It has been tentatively quantified by the RbSr and KAr isotopic methods, which seem also well suited to evaluate the chemical extent of this authigenesis. At least, no preferential loss of ⁴⁰Ar vs. ⁸⁷Sr could be detected in the minerals, even in those which are smaller than 0.2 μm.     

Paleomagnetism of Middle Proterozoic mafic intrusions and Upper Proterozoic (Nankoweap) red beds from the Lower Grand Canyon Supergroup, Arizona

Paleomagnetic data from lavas and dikes of the Unkar igneous suite (16 sites) and sedimentary rocks of the Nankoweap Formation (7 sites), Grand Canyon Supergroup (GCSG), Arizona, provide two primary paleomagnetic poles for Laurentia for the latest Middle Proterozoic (ca. 1090 Ma) at 32°N, 185°E (dp=6.8°, DM=9.3°) and early Late Proterozoic (ca. 850–900 Ma) at 10°S, 163°E (dp=3.5°, DM=7.0°). A new ⁴⁰Ar/³⁹Ar age determination from an Unkar dike gives an interpreted intrusion age of about 1090 Ma, similar to previously reported geochronologic data for the Cardenas Basalts and associated intrusions. The paleomagnetic data show no evidence of any younger, middle Late Proterozoic tectonothermal event such as has been revealed in previous geochronologic studies of the Unkar igneous suite. The pole position for the Unkar Group Cardenas Basalts and related intrusions is in good agreement with other ca. 1100 Ma paleomagnetic poles from the Keweenawan midcontinent rift deposits and other SW Laurentia diabase intrusions. The close agreement in age and position of the Unkar intrusion (UI) pole with poles derived from rift related rocks from elsewhere in Laurentia indicates that mafic magmatism was essentially synchronous and widespread throughout Laurentia at ca. 1100 Ma, suggesting a large-scale continental magmatic event. The pole position for the Nankoweap Formation, which plots south of the Unkar mafic rocks, is consistent with a younger age of deposition, at about 900 to 850 Ma, than had previously been proposed. Consequently, the inferred 200 Ma difference in age between the Cardenas Basalts and overlying Nankoweap Formation provides evidence for a third major unconformity within the Grand Canyon sequence.     

Self-diffusion studies of pore fluids in unconsolidated sediments by PFG NMR

The self-diffusion of water and hexadecane in medium and coarse sands from glacial sand deposits in central Germany were investigated by pulsed field gradient nuclear magnetic resonance (PFG NMR). Due to the restriction of the diffusion path at the pore/grain interface, the measured apparent self-diffusion coefficients (D(Δ)) in the pore space depend on the observation time (Δ) in the PFG NMR experiment. Although the bulk self-diffusion coefficients of water and hexadecane differ by about one order of magnitude, the apparent self-diffusion coefficients in the pore space obey the same characteristic time-behaviour, which depends only on geometrical properties of the pore system. Using the “short-time diffusion” model, surface-to-volume (S/V) ratios and inherent self-diffusion coefficients (D₀) of the pore fluids were extracted from these diffusion measurements. The S/V ratios obtained are independent of the pore fluid used and agree with known geometrical properties of the sand grains. Moreover, the D₀ values are consistent with the corresponding bulk self-diffusion coefficients measured separately. In contrast to these results of PFG NMR, simultaneous investigations of longitudinal (T₁) nuclear magnetic relaxation reveal that the relaxation time of the pore fluid is a less suitable parameter for a quantitative estimation of geometrical properties of the pore/grain interface in these unconsolidated sediments since it depends on chemical properties of the fluid/grain interface.