Sediment colour reflectance spectroscopy as a proxy for wet/dry cycles at Lake El'gygytgyn,Far East Russia,during Marine Isotope Stages 8 to 12

Marine Isotope Stage 11 has been proposed as an analogue for the present interglacial interval; yet, terrestrial climate records from both this region and time interval are rare. The sediments deposited at Lake El'gygytgyn (67°30′N, 172°5′E) in Far East Russia contain a 3·56 Ma record of climate variability. This study presents a high‐resolution record of sediment colour change from Marine Isotope Stage 8 to 12 (ca 275 to 475 ka) and demonstrates the link between lake catchment processes and climate variability. The hue colour parameter, calculated from data collected via colour reflectance spectroscopy in the visible spectrum (380 to 720 nm), exhibits correspondence with global climate records. Determining the source of sediment colour changes was achieved through detailed mineralogical and sedimentological methods, and linked to colour changes through a series of colour sensitivity tests. Mineralogical data, measured by X‐ray diffraction, reveal fluctuations in concentrations of clay minerals corresponding to colour changes. Further analyses of the clay mineral assemblages show no change in relative clay mineral abundances, yet demonstrate a lake catchment dominated by physical weathering processes. Using measured mineral abundances, reconstructions of sediment colour based on colour reflectance mineral standards link mineral and clay mineral content to overall sediment colour. Colour sensitivity tests demonstrate the ability of iron oxide minerals to stain sediments red. Additionally, colour sensitivity to organic matter content was tested, suggesting that organic content drives variability in the red portion of the spectrum and darkens the overall colour signal. Sediment colour is then ultimately linked to physical weathering of bedrock minerals, with small amounts of chemical weathering producing iron oxides during wet intervals. Fluctuations in the sediment colour reveal a high‐resolution record of wet/dry cycles, and provide new information about wet periods for the Russian Arctic region not yet understood from other lake proxy records.     

Series Expansion-Based Genetic Inversion of Wireline Logging Data

An evolutionary approach is applied to solve the nonlinear well logging inverse problem. In the framework of the proposed interval inversion method, nuclear, sonic, and laterolog resistivity data measured at an arbitrary depth interval are jointly inverted, where the depth variation of porosity, water saturation, and shale volume is expanded into series using Legendre polynomials as basis functions. In the interval inversion procedure, the series expansion coefficients are estimated by using an adaptive float-encoded genetic algorithm. Since the solution of the inverse problem using traditional linear optimization tools highly depends on the selection of the initial model, a heuristic search is necessary to reduce the initial model dependence of the interval inversion procedure. The genetic inversion strategy used in interval inversion seeks the global extreme of the objective function and provides an estimate of the vertical distribution of petrophysical parameters, even starting the inversion procedure from extremely high distances from the optimum. For a faster computational process, after a couple of thousand generations, the genetic algorithm is replaced by some linear optimization steps. The added advantage of using the Marquardt algorithm is the possibility to characterize the accuracy of the series expansion coefficients and derived petrophysical properties. A Hungarian oil field example demonstrates the feasibility and stability of the improved interval inversion method. As a significance, the genetic inversion method does not require prior knowledge or strong restrictions on the values of petrophysical properties and gives highly reliable estimation results practically independent of the initial model and core information.

     

On the combination of global and local data in collocation theory

Due to the successful operation of dedicated satellite gravity missions, nowadays high-accuracy global gravity field models have become available. This triggers the challenge to optimally combine this long to medium wavelength gravity field information derived from space-borne data with high-resolution terrestrial gravity data. In this paper, the least squares collocation concept is revised with the attempt to consistently unify the combination procedure in such a way that the full information contained in both data sets is merged. For example, in local or regional geoid determination the remove-restore method is usually applied only partially taking into account the accuracy of the global model coefficients used for the long-wavelength reduction. The key advantage of the extended formulation is the fact that it automatically accounts for the error covariance of all data types involved. The applicability, feasibility and performance of the proposed method is investigated in the frame of numerical closed-loop simulations. The two main fields of application, i.e., the improvement of a global gravity field model by terrestrial gravity field data, and, vice versa, the support to a regional geoid solution by the incorporation of a global gravity field model, have been analyzed and assessed. Although applied under simplified conditions, it could be shown that the method works and is practically applicable.     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset II: Land use,hydrology and sediment production monitoring in Houay Pano,northern Lao PDR

Mountain regions of the humid tropics are characterized by steep slopes and heavy rains. These regions are thus prone to both high surface runoff and soil erosion. In Southeast Asia, uplands are also subject to rapid land-use change, predominantly as a result of increased population pressure and market forces. Since 1998, the Houay Pano site, located in northern Lao PDR (19.85°N 102.17°E) within the Mekong basin, aims at assessing the long-term impact of the conversion of traditional slash-and-burn cultivation systems to commercial perennial monocultures such as teak tree plantations, on the catchment hydrological response and sediment yield. The instrumented site monitors hydro-meteorological and soil loss parameters at both microplot (1 m²) and small catchment (0.6 km²) scales. The monitored catchment is part of the network of critical zone observatories named Multiscale TROPIcal CatchmentS (M-TROPICS). The data shared by M-TROPICS in Houay Pano are (1) rainfall, (2) air temperature, air relative humidity, wind speed, and global radiation, (3) catchment land use, (4) stream water level, suspended particulate matter, bed particulate matter and stones, (5) soil surface features, and (6) soil surface runoff and soil detachment. The dataset has already been used to interpret suspended particulate matter and bed particulate matter sources and dynamics, to assess the impact of land-use change on catchment hydrology, soil erosion, and sediment yields, to understand bacteria fate and weed seed transport across the catchment, and to build catchment-scale models focused on hydrology and water quality issues. The dataset may be further used to, for example, assess the role of headwater catchments in large tropical river basin hydrology, support the interpretation of new variables measured in the catchment (e.g., contaminants other than faecal bacteria), and assess the relative impacts of both climate and land-use change on the catchment.     

X-ray spectroscopy of galaxy clusters: studying astrophysical processes in the largest celestial laboratories

Galaxy clusters, the largest clearly defined objects in our Universe, are ideal laboratories to study in detail the cosmic evolution of the intergalactic intracluster medium (ICM) and the cluster galaxy population. For the ICM, which is heated to X-ray radiating temperatures, X-ray spectroscopy is the most important tool to obtain insight into the structure and astrophysics of galaxy clusters. The ICM is also the hottest plasma that can be well studied under thermal equilibrium conditions. In this review we recall the basic principles of the interpretation of X-ray spectra from a hot, tenuous plasma and we illustrate the wide range of scientific applications of X-ray spectroscopy. The determination of galaxy cluster masses, the most important prerequisite for using clusters in cosmological studies, rest crucially on a precise spectroscopic determination of the ICM temperature distribution. The study of the thermal structure of the ICM provides a very interesting fossil record of the energy release during galaxy formation and evolution, giving important constraints on galaxy formation models. The temperature and pressure distribution of the ICM gives us important insight into the process of galaxy cluster merging and the dissipation of the merger energy in form of turbulent motion. Cooling cores in the centers of about half of the cluster population are interesting laboratories to investigate the interplay between gas cooling, star- and black hole formation and energy feedback, which is diagnosed by means of X-ray spectroscopy. The element abundances deduced from X-ray spectra of the ICM provide a cosmic history record of the contribution of different supernovae to the nucleosynthesis of heavy elements and their spatial distribution partly reflects important transport processes in the ICM. Some discussion of plasma diagnostics for conditions out of thermal equilibrium and an outlook on the future prospects of X-ray spectroscopic cluster studies complete our review.     

Monitoring the Dynamics of the Ionosphere–Plasmasphere System by Ground-Based ULF Wave Observations

Cross-spectral analysis of ULF wave measurements recorded at ground magnetometer stations closely spaced in latitude allows accurate determinations of magnetospheric field line resonance (FLR) frequencies. This is a useful tool for remote sensing temporal and spatial variations of the magnetospheric plasma mass density. The spatial configuration of the South European GeoMagnetic Array (SEGMA, 1.56 <  L <  1.89) offers the possibility to perform such studies at low latitudes allowing to monitor the dynamical coupling between the ionosphere and the inner plasmasphere. As an example of this capability we present the results of a cross-correlation analysis between FLR frequencies and solar EUV irradiance (as monitored by the 10.7-cm solar radio flux F10.7) suggesting that changes in the inner plasmasphere density follow the short-term (27-day) variations of the solar irradiance with a time delay of 1–2 days. As an additional example we present the results of a comparative analysis of FLR measurements, ionospheric vertical soundings and vertical TEC measurements during the development of a geomagnetic storm.     

Pyrolytic and spectroscopic studies of Eocene resin from Vastan lignite Mine,Cambay basin,Western India

The molecular structure of an Eocene fossil resin (Vastan, Cambay basin, Western India) has been investigated with complimentary spectroscopic techniques. The FTIR spectrum shows strong aliphatic CH _x (3000–2800 and 1460–1450 cm⁻¹) and CH₃ (1377 cm⁻¹) absorptions and less intense aromatic C=C (1560–1610 cm⁻¹) absorptions. The major products from analytical pyrolysis are cadalene based bicyclic sesquiterpenoids including some bicadinenes and bicadinanes. The polycadinane products confirm the fossil material as an Angiosperm dammar resin, associated with inputs of tropical rain forests supported by past climates.     

Late orogenic, large-scale rotations in the Tien Shan and adjacent mobile belts in Kyrgyzstan and Kazakhstan

Most of Kazakhstan belongs to the central part of the Eurasian Paleozoic mobile belts for which previously proposed tectonic scenarios have been rather disparate. Of particular interest is the origin of strongly curved Middle and Late Paleozoic volcanic belts of island-arc and Andean-arc affinities that dominate the structure of Kazakhstan. We undertook a paleomagnetic study of Carboniferous to Upper Permian volcanics and sediments from several localities in the Ili River basin between the Tien Shan and the Junggar–Alatau ranges in southeast Kazakhstan. Our main goal was to investigate the Permian kinematic evolution of these belts, particularly in terms of rotations about vertical axes, in the hope of deciphering the dynamics that played a role during the latest Paleozoic deformation in this area. This deformation, in turn, can then be related to the amalgamation of this area with Baltica, Siberia, and Tarim in the expanding Eurasian supercontinent. Thermal demagnetization revealed that most Permian rocks retained a pretilting and likely primary component, which is of reversed polarity at three localities and normal at the fourth. In contrast, most Carboniferous rocks are dominated by postfolding reversed overprints of probably “mid-Permian” age, whereas presumably primary components are isolated from a few sites at two localities. Mean inclinations of primary components generally agree with coeval reference values extrapolated from Baltica, whereas declinations from primary as well as secondary components are deflected counterclockwise (ccw) by up to  90°. Such ccw rotated directions have previously also been observed in other Tien Shan sampling areas and in the adjacent Tarim Block to the south. However, two other areas in Kazakhstan show clockwise (cw) rotations of Permian magnetization directions. One area is located in the Kendyktas block about 300 km to the west of the Ili River valley, and the other is found in the Chingiz Range, to the north of Lake Balkhash and about 400 km to the north of the Ili River valley. The timing of the ccw as well as cw rotations is clearly later than the disappearance of any marine basins from northern Tarim, the Tien Shan and eastern Kazakhstan, so that the rotations cannot be attributed to island-arc or Andean-margin plate settings — instead we attribute the rotations to large-scale, east–west (present-day coordinates), sinistral wrenching in an intracontinental setting, related to convergence between Siberia and Baltica, as recently proposed by Natal'in and Şengör [Natal'in, B.A., and Şengör, A.M.C., 2005. Late Palaeozoic to Triassic evolution of the Turan and Scythian platforms: the pre-history of the palaeo-Tethyan closure, Tectonophysics, 404, 175–202.]. Our previous work in the Chingiz and North Tien Shan areas on Ordovician and Silurian rocks suggested relative rotations of  180°, whereas the Permian declination differences are of the order of 90° between the two areas. Thus, we assume that about 50% of the total post-Ordovician rotations are of pre-Late Permian age, with the other half of Late Permian–earliest Mesozoic age. The pre-Late Permian rotations are likely related to oroclinal bending during plate boundary evolution in a supra-subduction setting, given the calc-alkaline character of nearly all of the pre-Late Permian volcanics in the strongly curved belts.