Sicilian serpentinite xenoliths containing abiotic organics with nanodiamond clusters as key model for prebiotic processes

Rock fragments from the deepest parts of a buried hydrothermal system belonging to the Mesozoic Tethys Ocean entered as xenoliths in a Miocenic diatreme,hence brought to the surface,in the Hyblean Plateau(Sicily).Some xenoliths consist of strongly serpentinized ultramafic rocks bearing blebs of abiotic organic matter,where clusters of amorphous carbon nanoparticles,including nanodiamonds,are immersed.Such an occurrence conjures up established hypotheses that diamond surfaces are suitable catalytic platforms stimulating the assemblage of complex bio-organic molecules relevant to the emergence of life on Earth.The appearance of bio-organic molecules under primitive Earth conditions is one of the major unsolved questions on the origin of life.Here we report new micro-Raman spectra on blebs of abiotic organic matter from a selected xenolith.Diamond bands were related to hydrogenated nanocrystalline diamonds,with size of nearly 1-1.6 nm,formed from organics at low pressures and temperatures.In particular,diamond surfaces can give rise to crystalline interfacial water layers that may have played a fundamental role in the early biosphere evolution as a good medium for rapidly transporting positive charges in the form of hydrated protons.Nowadays,proton gradients in alkaline hydrothermal vents along oceanic ridges are generally viewed as key pre-biotic factors.In general,serpentinites span the entire geological record,including prebiotic times.These hydrous ultramafic rocks often display evidence of abiotic carbon species,both organic and inorganic,including nanodiamonds,being also capable to give rise to chemiosmotic processes and proton gradients necessary to the organisms,such as the"Last Universal Common Ancestor"(LUCA),in the prebiotic Earth.     

Quaternary faults and seismicity in the Umbro-Marchean Apennines (Central Italy): evidence from the 1997 Colfiorito earthquake

Analyses of structural and geomorphological data combined with remote sensing interpretation confirm previous knowledge on the existence of an extensional Quaternary tectonic regime in the Colfiorito area (Umbro-Marchean Central Apennines). This is characterized by a maximum principal axis of finite strain oriented approx. NE–SW, which is the result of a progressive deformation process due to pure and radial extension. Surface geological data, the crustal tectonic setting (reconstructed using a CROP 03 seismic reflection profile), and seismological data relative to the autumn 1997 Colfiorito earthquake sequence constrain the following seismotectonic model. We interpret the seismogenic SW-dipping low-angle normal fault pictured by seismic data as an inverted thrust ramp located in the basement at depth between 5 and 10 km. The surface projection of this seismogenic structure defines a crustal box within which high-angle normal faults are responsible for the deformation of the uppermost crust. The regional patterns of pre-existing basement thrusts therefore control the seismotectonic zoning of the area that cannot be directly related to the high-angle normal fault systems which cut through different crustal boxes; the latter system records, in fact, re-shear along pre-existing normal faults. Moreover, Quaternary slip-rates relative to high-angle normal faults in the Central Apennines are closely related to seismic hazard within each crustal box.     

Barnacle Larvae and their Settlement in Genoa Harbour (North Tyrrhenian Sea)

Abstract. Density of barnacle larvae in plankton and settlement on atoxic plane surfaces have been compared at one station of Genoa harbour over sixteen months.
There were two periods of larval emission, during summer and autumn, with a slight one during winter. Barnacle settlement varied according to sea temperature, the amount of larvae and competition for the substratum.     

Long term monitoring of photosystem II herbicides--correlation with remotely sensed freshwater extent to monitor changes in the quality of water entering the Great Barrier Reef, Australia

Photosystem II (PSII) herbicides are used in large quantities on agricultural lands adjoining the Great Barrier Reef (GBR). Routine monitoring at 14 sites in inshore waters of the GBR using passive sampling techniques detected diuron (32-94% of sampling periods) at maximum concentrations of 1.7-430ng L(-1) in the relatively pristine Cape York Region to the Mackay Whitsunday Region, respectively. A PSII herbicide equivalent (PSII-HEq) index developed as an indicator for reporting was dominated by diuron (average contribution 89%) and typically increased during the wet season. The maximum PSII-HEq indicates the potential for photosynthetic inhibition of diatoms, seagrass and coral-symbionts. PSII herbicides were significantly positively correlated with remotely sensed coloured dissolved organic matter, a proxy for freshwater extent. Combining these methods provides for the first time the potential to cost-effectively monitor improvements in water quality entering the GBR with respect to exposure to PSII herbicides.