Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.     

LRS Bianchi type?II disordered radiation model with a varying Λ term in self creation theory

In this paper, we study LRS Bianchi type II cosmological model with a nonzero time-dependent cosmological constant Λ for disordered radiation in the framework of Barber’s second self creation theory of gravitation. The physical and geometrical aspects of the model with singularities are also discussed.     

Stochastic finite fault modelling of M w 4.8 earthquake in Kachchh, Gujarat, India

The modified stochastic finite fault modelling technique based on dynamic corner frequency has been used to simulate the strong ground motions of M _w 4.8 earthquake in the Kachchh region of Gujarat, India. The accelerograms have been simulated for 14 strong motion accelerographs sites (11 sites in Kachchh and three sites in Saurashtra) where the earthquake has been recorded. The region-specific source, attenuation and generic site parameters, which are derived from recordings of small to moderate earthquakes, have been used for the simulations. The main characteristics of the simulated accelerograms, comprised of peak ground acceleration (pga), duration, Fourier and response spectra, predominant period, are in general in good agreement with those of observed ones at most of the sites. The rate of decay of simulated pga values with distance is found to be similar with that of observed values. The successful modelling of the empirical accelerograms indicates that the method can be used to prepare wide range of scenarios based on simulation which provide the information useful for evaluating and mitigating the seismic hazard in the region.     

Magnetic and radiometric signatures over a Proterozoic massive sulfide setting of northern fringe of Dalma Volcanics,eastern India: An implication to metallogeny

Magnetic and radiometric surveys were carried out over a felsic dominated rifted margin of Proterozoic volcanic terrain of a mobile belt in the eastern India. The studies were made in blocks I and II of 0.65 sq km and 0.70 sq km respectively over a previously identified conductor in the northern fringe of Dalma Volcanics (DVs). In general, both the blocks show high magnetic signature associated with sulfide mineralisation. The interpretation of magnetic data suggests that nature of the causative source is mainly horizontal cylinder in both the blocks. The depth to the top of the causative source is about 25 m in both the blocks and extends upto 60 m in block I and 40m in block II. Gamma count rate exhibits about a factor of two to three enhancements above the field background for both the blocks. The obtained iso-rad maps are similar to uranium and copper belt in the Singhbhum shear zone south of the study area. The anomalous radiometric signature of the residual soil/rock of the area indicates towards hydrothermal alteration. The detailed magnetic surveys and preliminary iso-rads results seems quite encouraging and may be attributed to VMS setting in the area and potential sulfide mineralisation with uranium mineral association in the DVs province.     

Anomalous Variation in GPS TEC,Land and Ocean Parameters Prior to 3 Earthquakes

The present study reports the analysis of GPS TEC prior to 3 earthquakes (M > 6.0). The earthquakes are: (1) Loyalty Island (22°36′S, 170°54′E) on 19 January 2009 (M = 6.6), (2) Samoa Island (15°29′S, 172°5′W) on 30 August 2009 (M = 6.6), and (3) Tohoku (38°19′N, 142°22′E) on 11 March 2011 (M = 9.0). In an effort to search for a precursory signature we analysed the land and ocean parameters prior to the earthquakes, namely SLHF (Land) and SST (Ocean). The GPS TEC data indicate an anomalous behaviour from 1–13 days prior to earthquakes. The main purpose of this study was to explore and demonstrate the possibility of any changes in TEC, SST, and SLHF before, during and after the earthquakes which occurred near or beneath an ocean. This study may lead to better understanding of response of land, ocean, and ionosphere parameters prior to seismic activities.     

Temporal variation of b value associated with M ��4 earthquakes in the reservoir-triggered seismic environment of the Koyna�CWarna region, Western India

It is generally found that the b values associated with reservoir-triggered seismicity (RTS) are higher than the regional b values in the frequency magnitude relation of earthquakes. In the present study, temporal and spatial variation of b value is investigated using a catalog of 3,000 earthquakes from August 2005 through December 2010 for the Koyna?CWarna region in Western India, which is a classical site of RTS globally. It is an isolated (30?×?20?km²) zone of seismicity where earthquakes of up to M ??5 are found to occur during phases of loading and unloading of the Koyna and Warna reservoirs situated 25?km apart. For the Warna region, it is found that low b values of 0.6?C0.9 are associated with earthquakes of M ??4 during the loading phase. The percentage correlation of the occurrence of an M????4 earthquake with a low b value outside the 1?? or 2?? level is as high as 78?%. A drastic drop in the b value of about 50?% being reported for an RTS site may be an important precursory parameter for short-term earthquake forecast in the future.     

A Spatial Database of Cropping System and its Characteristics to Aid Climate Change Impact Assessment Studies

Cropping system study is not only useful to understand the overall sustainability of agricultural system, but also it helps in generating many important parameters which are useful in climate change impact assessment. Considering its importance, Space Applications Centre, took up a project for mapping and characterizing major cropping systems of Indo-Gangetic Plains of India. The study area included the five states of Indo-Gangetic Plains (IGP) of India, i.e. Punjab, Haryana, Uttar Pradesh, Bihar and West Bengal. There were two aspects of the study. The first aspect included state and district level cropping system mapping using multi-date remote sensing (IRS-AWiFS and Radarsat ScanSAR) data. The second part was to characterize the cropping system using moderate spatial resolution multi-date remote sensing data (SPOT VGT NDVI) and ground survey. The remote sensing data was used to compute three cropping system performance indices (Multiple Cropping Index, Area Diversity Index and Cultivated Land Utilization Index). Ground survey was conducted using questionnaires filled up by 1,000 farmers selected from 103 villages based on the cropping systems map. Apart from ground survey, soil and water sampling and quality analysis were carried out to understand the effect of different cropping systems and their management practices. The results showed that, rice-wheat was the major cropping system of the IGP, followed by Rice-Fallow-Fallow and Maize-Wheat. Other major cropping systems of IGP included Sugarcane based, Pearl millet-Wheat, Rice-Fallow-Rice, Cotton-Wheat. The ground survey could identify 77 cropping systems, out of which 38 are rice-based systems. Out of these 77 cropping systems, there were 5 single crop systems, occupying 6.5% coverage (of all cropping system area), 56 double crop systems with 72.7% coverage, and 16 triple crop systems with 20.8% coverage. The cropping system performance analysis showed that the crop diversity was found to be highest in Haryana, while the cropping intensity was highest in Punjab state.     

Resonance in the earth-moon system around the sun including earth’s equatorial ellipticity

We have investigated the resonances in the earth-moon system around the sun including earth’s equatorial ellipticity. The resonance resulting from the commensurability between the mean motion of the moon and Γ (angle measured from the minor axis of the earth’s equatorial ellipse to the projection of the moon on the plane of the equator) is analyzed. The amplitude and the time period of the oscillation have been determined by using the procedure of Brown and Shook. We have shown the effects of Γ on the amplitude and the time period of the resonance oscillation using the data of the moon. It is observed that the amplitude decreases and the time period also decreases as Γ increases from 0^° to 45^°.     

Probabilistic Assessment of Tsunami Recurrence in the Indian Ocean

The Indian Ocean is one of the most tsunamigenic regions of the world and recently experienced a mega-tsunami in the Sumatra region on 26 December 2004 (M _W 9.2 earthquake) with tsunami intensity I (Soloviev-Imamura intensity scale) equal to 4.5, causing heavy destruction of lives and property in the Indian Ocean rim countries. In this study, probabilities of occurrences of large tsunamis with tsunami intensities I ≥ 2.0 and I ≥ 3.0 (average wave heights H ≥ 2.83 m and H ≥ 5.66 m, respectively) during a specified time interval were calculated using three stochastic models, namely, Weibull, gamma and lognormal. Tsunami recurrence was calculated for the whole Indian Ocean and the special case of the Andaman-Sumatra-Java (ASJ) region, excluding the 1945 Makran event from the main data set. For this purpose, a reliable, homogeneous and complete tsunami catalogue with I ≥ 2.0 during the period 1797–2006 was used. The tsunami hazard parameters were estimated using the method of maximum likelihood. The logarithm of likelihood function (ln L) was estimated and used to test the suitability of models in the examined region. The Weibull model was observed to be the most suitable model to estimate tsunami recurrence in the region. The sample mean intervals of occurrences of tsunamis with intensity I ≥ 2.0 and I ≥ 3.0 were calculated for the observed data as well as for the Weibull, gamma and lognormal models. The estimated cumulative and conditional probabilities in the whole Indian Ocean region show recurrence periods of about 27–30 years (2033–2036) and 35–36 years (2039–2040) for tsunami intensities I ≥ 2.0 and I ≥ 3.0, respectively, while it is about 31–35 years (2037–2041) and 41–42 years (2045–2046) for a tsunami of intensity I ≥ 2.0 and I ≥ 3.0, respectively, in the ASJ region. A high probability (>0.9) of occurrence of large tsunamis with I ≥ 2.0 in the next 30–40 years in the Indian Ocean region was revealed.