Trace metal variations in the shells of Ensis siliqua record pollution and environmental conditions in the sea to the west of mainland Britain

Shells of the pod razor shell (Ensis siliqua) from 13 locations around the west coast of mainland Britain have been analysed by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for a range of trace metals including Zn, Cd, Pb, U, Ba, Sr and Mg. The trace metal record in these shells is a proxy record for changes in seawater chemistry during the 1990s. Regional variations exist in the median concentrations of the analysed metals. Barium concentrations are related to increased productivity from sewage sludge dumping at sea. Strontium shows a local relationship to salinity, but there is no clear relationship over the study area, instead high Sr is often associated with high Ba, and may reflect ontogenetic factors such as growth rate. Magnesium shows a seasonal variation within individual shells and can be used to calculate sea surface temperatures from groups of shells. Contaminant metals show a clear regional relationship with known sources, thus high Pb and Zn are typically associated with former metal mining areas (e.g. Cardigan Bay, Anglesey), and high Pb, Zn, Cd and U are associated with industrial activity in Liverpool Bay. Anomalies such as the high U in shells from northern Scotland cannot at present be explained. A seasonal variation of Pb is also seen in Cardigan Bay and Liverpool Bay, relating to increased winter fluxes of these metals to the marine environment. The regional distribution of these metals is consistent with known sources of contamination and patterns of seawater migration around the coast of Britain.     

The effect of recent climatic trends on Urticaceae pollination in two bioclimatically different areas in the Iberian Peninsula: Malaga and Vigo

Malaga (Mediterranean coast) and Vigo (Atlantic coast) are representative of two bioclimatically different areas belonging to the Mediterranean and the Eurosiberian region, respectively. This contribution represents a study on recent trends in the principal meteorological parameters in these areas and their influence on the phenology of Urticaceae (nettle family) atmospheric pollen, one of the main causes of pollinosis in Spain. The study covers the period 1991–2006 for Malaga and 1995–2005 for Vigo, and compares the differences in climate and phenological behaviour observed at both localities. The sampling of atmospheric pollen was performed with Hirst volumetric pollen traps. The two localities present different tendencies as far as temperature is concerned: while the mean annual temperature in the Mediterranean region has increased by 0.06°C/year, the same parameter has decreased in the Atlantic area by 0.1°C/year. This tendency is even more pronounced as far as the minimum temperatures are concerned, especially during spring in Malaga and autumn in Vigo. On the other hand, wind speed has tended to increase, periods of calm have diminished and winds blowing off the sea have increased in both places. These changes in meteorological parameters have advanced the end of the pollen season in Malaga and delayed its start in Vigo. Total annual pollen counts have decreased in Vigo, while the number of pollen-free days has increased in both areas.     

Tolerance of allogromiid Foraminifera to severely elevated carbon dioxide concentrations: Implications to future ecosystem functioning and paleoceanographic interpretations

Increases in the partial pressure of carbon dioxide (pCO₂) in the atmosphere will significantly affect a wide variety of terrestrial fauna and flora. Because of tight atmospheric–oceanic coupling, shallow-water marine species are also expected to be affected by increases in atmospheric carbon dioxide concentrations. One proposed way to slow increases in atmospheric pCO₂ is to sequester CO₂ in the deep sea. Thus, over the next few centuries marine species will be exposed to changing seawater chemistry caused by ocean–atmospheric exchange and/or deep-ocean sequestration. This initial case study on one allogromiid foraminiferal species (Allogromia laticollaris) was conducted to begin to ascertain the effect of elevated pCO₂ on benthic Foraminifera, which are a major meiofaunal constituent of shallow- and deep-water marine communities. Cultures of this thecate foraminiferan protist were used for 10–14-day experiments. Experimental treatments were executed in an incubator that controlled CO₂ (15 000; 30 000; 60 000; 90 000; 200 000 ppm), temperature and humidity; atmospheric controls (i.e., ~ 375 ppm CO₂) were executed simultaneously. Although the experimental elevated pCO₂ values are far above foreseeable surface water pCO₂, they were selected to represent the spectrum of conditions expected for the benthos if deep-sea CO₂ sequestration becomes a reality. Survival was assessed in two independent ways: pseudopodial presence/absence and measurement of adenosine triphosphate (ATP), which is an indicator of cellular energy. Substantial proportions of A. laticollaris populations survived 200 000 ppm CO₂ although the mean of the median [ATP] of survivors was statistically lower for this treatment than for that of atmospheric control specimens. After individuals that had been incubated in 200 000 ppm CO₂ for 12 days were transferred to atmospheric conditions for ~ 24 h, the [ATP] of live specimens (survivors) approximated those of the comparable atmospheric control treatment. Incubation in 200 000 ppm CO₂ also resulted in reproduction by some individuals. Results suggest that certain Foraminifera are able to tolerate deep-sea CO₂ sequestration and perhaps thrive as a result of elevated pCO₂ that is predicted for the next few centuries, in a high-pCO₂ world. Thus, allogromiid foraminiferal “blooms” may result from climate change. Furthermore, because allogromiids consume a variety of prey, it is likely that they will be major players in ecosystem dynamics of future coastal sedimentary environments.     

Assessing vulnerability of selected farming communities in the Philippines based on a behavioural model of agent's adaptation to global environmental change

Behavioural models that allow simple representation of the complexity of human–environment links are important in vulnerability assessment because they allow the analysis of human adaptive processes in a changing environment. This paper applies an agent-based framework that considers the behavioural model of farmers in three villages in a municipality in the Philippines. Agent-based modelling is a useful policy tool for simulating the effects of different adaptation options on reducing vulnerability because it allows representation of not only the dynamic changes in climate and market but also the dynamic adaptive process of different groups of communities to the impacts of these changes. Model simulations of adaptation options under various global change scenarios showed that production support would significantly reduce future vulnerability only if complemented with appropriate market support. It is thus important for policy to provide a complementary bundle of adaptation measures. Lack of money and information are the most important reasons for not applying available technical adaptation measures, which currently hinder reduction of vulnerability in selected villages in the municipality. Social networks, which play an important role in adapting to environmental changes, are limited to relatives and neighbours, who are important sources of informal credit.     

Monitoring of heavy metals in wild mussels (Mytilus galloprovincialis) from the Spanish North-Atlantic coast

Concentrations of five heavy metals (Hg, Cd, Pb, Cu and Zn) were determined in tissues of wild mussels (Mytilus galloprovincialis) collected at 41 stations located on the Spanish Atlantic and Northern coasts to assess the levels and spatial distribution of metals in the environment. This study, performed in 2005, constituted a contribution to the last international OSPAR pollution monitoring survey. A pool of mussel soft tissue was prepared using 50 or more individuals, representing the size range present at the sampling points. Quantification was carried out after a nitric acid digestion by atomic absorption spectrometry, AAS (Cd and Pb by electrothermal AAS; Cu and Zn by flame AAS; and total mercury by the cold vapour technique). The quality of the chemical analyses was assessed by interlaboratory exercises carried out on a regular basis. In general, the levels of the metals were higher for the Northern region than for the Atlantic one (except for a sampling site close to Vigo, one of the main Galician industrial areas). Some Galician sampling points (Atlantic coast, NW of Spain) located far from human inputs showed high Cd concentrations, which were attributed to the annual upwelling processes in this region. The levels of Cu increased from Northwest to East, whereas Zn concentrations were very homogeneous throughout the two studied geographical regions. These results were confirmed using multivariate studies (PCA and cluster analysis), as well as international ‘background assessment concentrations’ criteria.     

Chandra monitoring of the candidate anomalous X-ray pulsar AX J1845.0-0258

The population of clearly identified anomalous X-ray pulsars has recently grown to seven, however, one candidate anomalous X-ray pulsar (AXP) still eludes re-confirmation. Here, we present a set of seven Chandra ACIS-S observations of the transient pulsar AX J1845.0-0258, obtained during 2003. Our observations reveal a faint X-ray point source within the ASCA error circle of AX J1845.0-0258’s discovery, which we designate CXOU J184454.6-025653 and tentatively identify as the quiescent AXP. Its spectrum is well described by an absorbed single-component blackbody (kT∼2.0 keV) or power law (Γ∼1.0) that is steady in flux on timescales of at least months, but fainter than AX J1845.0-0258 was during its 1993 period of X-ray enhancement by at least a factor of 13. Compared to the outburst spectrum of AX J1845.0-0258, CXOU J184454.6-025653 is considerably harder: if truly the counterpart, then its spectral behavior is contrary to that seen in the established transient AXP XTE J1810-197, which softened from kT∼0.67 keV to ∼0.18 keV in quiescence. This unexpected result prompts us to examine the possibility that we have observed an unrelated source, and we discuss the implications for AXPs, and magnetars in general.      

Searching for the source regions of martian meteorites using MGS TES: Integrating martian meteorites into the global distribution of igneous materials on Mars

Abstract— The objective of this study was to identify and map possible source regions for all 5 known martian meteorite lithologies (basalt, lherzolite, clinopyroxenite, orthopyroxenite, and dunite) using data from the Mars Global Surveyor Thermal Emission Spectrometer (MGS TES). We deconvolved the TES data set using laboratory spectra of 6 martian meteorites (Los Angeles, Zagami, ALH A77005, Nakhla, ALH 84001, and Chassigny) as end members, along with atmospheric and surface spectra previously derived from TES data. Global maps (16 pixels/degree) of the distribution of each meteorite end member show that meteorite‐like compositions are not present at or above TES detectability limits over most of the planet's dust‐free regions. However, we have confidently identified local‐scale (100s‐1000s km²) concentrations of olivine‐ and orthopyroxene‐bearing materials similar to ALH A77005, Chassigny, and ALH 84001 in Nili Fossae, in and near Ganges Chasma, in the Argyre and Hellas basin rims, and in Eos Chasma. Nakhla‐like materials are identified near the detection limit throughout the eastern Valles Marineris region and portions of Syrtis Major. Basaltic shergottites were not detected in any spatially coherent areas at the scale of this study. Martian meteorite‐like lithologies represent only a minor portion of the dust‐free surface and, thus, are not representative of the bulk composition of the ancient crust. Meteorite‐like spectral signatures identified above TES detectability limits in more spatially restricted areas (<tens of km) are targets of ongoing analysis.     

Monitoring the crystallization of water-saturated granitic melts in real time using the hydrothermal diamond anvil cell

Critical aspects of the crystallization dynamics of H₂O-saturated melts of a typical granitic composition as well as granitic melts enriched in lithium (8800 ppm) were investigated in real-time experiments using the hydrothermal diamond anvil cell at 480–700 °C and 220–960 MPa. Complete crystallization of the charges was achieved within 5–118 h with average crystal growth rates ranging from 3 to 41 cm/year for quartz and from 18 to 58 cm/year for alkali feldspars, demonstrating that crystals formed from a silicate melt in the presence of a coexisting aqueous phase crystallize rapidly. The combination of substantial nucleation delays, low nucleation densities, and rapid growth rates for quartz and alkali feldspars led to the formation of euhedral megacrysts of these minerals in the vicinity of clusters comprised of much smaller muscovite or α-spodumene crystals. Subsolidus replacement processes initiated during crystal–fluid interactions after the silicate melt was consumed were directly observed in the experiments. The experimental results underscore the important role of water as a medium for the transport of essential elements such as Si, Al, Na, and K from the silicate melt to the newly formed crystals, and provide important insights into the crystallization of miarolitic pegmatites.     

Implementation of New OPAL Tables in Eggleton's Stellar Evolution Code

Based on previous works of OPAL, we construct a series of opacity tables for various metallicities Z=0, 0.000 01, 0.000 03, 0.000 1, 0.000 3, 0.001, 0.004, 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.08 and 0.1. These tables can be easily used in Eggleton's stellar evolution code in place of the old tables without changing the code. The OPAL tables are used for log10(T/K) > 3.95 and Alexander's for log10(T/K) < 3.95. At log10(T/K) = 3.95, the two groups' data fit well for all hydrogen mass fractions. Conductive opacities are included by reciprocal addition according to the formulae of Yakovlev and Urpin. A comparison of 1 and 5 M models constructed with the older OPAL tables of Iglesias and Rogers shows that the new opacities have most effect in the late stages of evolution, the extension of the blue loop during helium burning for intermediate-mass and massive stars.