Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.     

A transformation of the two-body problem

A transformation of the differential equations of motion of the two-body problem in the spherical coordinates to oscillator form is derived. It is shown that the independent variable transformation dt/ds=r² is a transformation which makes the oscillator form possible.     

An extreme wave event in eastern Yucatán,Mexico: Evidence of a palaeotsunami event during the Mayan times

The Yucatán Peninsula, Mexico, has typically been considered a tectonically stable region with little significant seismic activity. The region though, is one that is regularly affected by hurricanes. A detailed survey of ca 100 km of the eastern Yucatán and Cozumel coast identified the presence of ridges containing individual boulders measuring >1 m in length. The boulder ridges reach 5 m in height and their origin is associated with extreme wave event activity. Previously modelled tsunami waves from known seismically active zones in the region (Muertos Thrust Belt and South Caribbean Deformed Belt) are not of sufficient scale in the area of the Yucatán Peninsula to have produced the boulder ridges recorded in this study. The occurrence of hurricanes in this region is more common, but two of the most destructive (Hurricane Gilbert 1988 and Hurricane Wilma 2005) produced coastal waves too small to have created the ridges recorded here. In this paper, a new tsunami model with a source area located on the Motagua/Swan Island Fault System has been generated that indicates a tsunami event may have caused the extreme wave events that resulted in the deposition of the boulder ridges.     

Catchment precipitation processes in the San Francisco valley in southern Ecuador: combined approach using high-resolution radar images and in situ observations

The precise estimation of precipitation quantities in tropical mountain regions is in great demand by ecological and hydrological studies, due to the heterogeneity of the rainfall distribution and the lack of meteorological station data. This study uses radar images and ground station data to provide the required high-resolution precipitation maps. Also wind data are taken into account, due to its influence on the precipitation formation and to demonstrate the relation between synoptic wind, topography and the precipitation distribution inside small mountain valleys. The study analyses the rainfall distribution and amounts of 4 days inside the San Francisco Valley, a small catchment in the tropical Andes of southern Ecuador, representing different seasons and the typical atmospheric flows, which are correlated to the annual precipitation map. The results show that the rainfall distribution and amounts are generally defined by the wind direction and velocity, besides the topographic location in relation to the main barriers and pathways. The dominant wind direction causes a division of the catchment in a wetter eastern and a dryer western part. Moreover, the annual seasons are reversed; the main rainy season for the eastern part occurs between June and August, while the western part reaches the precipitation maximum between January and March. This may have influence on the species composition at the different slopes and the annual hydrological cycle inside the catchment.     

Late Quaternary vegetation and climate dynamics in central-eastern Brazil: insights from a ~35k cal a bp peat record in the Cerrado biome

The late Quaternary evolution of central-eastern Brazil has been under-researched. Questions remain as to the origin of the Cerrado, a highly endangered biome, and other types of vegetation, such as the Capões – small vegetation islands of semi-deciduous and mountain forests. We investigated the factors that influenced the expansion and contraction of the Cerrado and Capões during the late Quaternary (last ~35 ka), using a multi-proxy approach: stable isotopes (δ¹³C, δ¹⁵N), geochemistry, pollen and multivariate statistics derived from a peat core (Pinheiro mire, Serra do Espinhaço Meridional). Five major shifts in precipitation, temperature, vegetation and landscape stability occurred at different timescales. Our study revealed that changes in the South Atlantic Convergence Zone (SACZ) seem to have been coeval with these shifts: from the Late Glacial Maximum to mid-Holocene the SACZ remained near (~29.6 to ~16.5k cal a bp ) and over (~16.5 to ~6.1 k cal a bp ) the study area, providing humidity to the region. This challenges previous research which suggested that climate was drier for this time period. At present, the Capões are likely to be a remnant of a more humid climate; meanwhile, the Cerrado biome seems to have stablished in the late Holocene, after ~3.1 k cal a bp .     

Atmospheric forcing of the eastern tropical Pacific: A review

The increase in marine, land surface, atmospheric and satellite data during recent decades has led to an improved understanding of the air–sea interaction processes in the eastern tropical Pacific. This is also thanks to extensive diagnoses from conceptual and coupled ocean–atmosphere numerical models. In this paper, mean fields of atmospheric variables, such as incoming solar radiation, sea level pressure, winds, wind stress curl, precipitation, evaporation, and surface energy fluxes, are derived from global atmospheric data sets in order to examine the dominant features of the low level atmospheric circulations of the region. The seasonal march of the atmospheric circulations is presented to depict the role of radiative forcing on atmospheric perturbations, especially those dominating the atmosphere at low levels.In the tropics, the trade winds constitute an important north–south energy and moisture exchange mechanism (as part of the low level branch of the Hadley circulation), that determines to a large extent the precipitation distribution in the region, i.e., that associated with the Inter-Tropical Convergence Zone (ITCZ). Monsoonal circulations also play an important role in determining the warm season precipitation distribution over the eastern tropical Pacific through a large variety of air–sea–land interaction mechanisms. Westward traveling waves, tropical cyclones, low latitude cold air intrusions, and other synoptic and mesoscale perturbations associated with the ITCZ are also important elements that modulate the annual rainfall cycle. The low-level jets of the Gulf of California, the Intra-Americas Sea (Gulf of Mexico and Caribbean Sea) and Chocó, Colombia are prominent features of the eastern tropical Pacific low-level circulations related to sub-regional and regional scale precipitation patterns. Observations show that the Intra-Americas Low-Level Jet intensity varies with El Niño/Southern Oscillation (ENSO) phases, however its origin and role in the westward propagation and development of disturbances that may hit the eastern tropical Pacific, such as easterly waves and tropical cyclones, are still unclear. Changes in the intensity of the trade winds in the Caribbean Sea and the Gulf of Mexico (associated with eastern tropical Pacific wind jets) exert an important control on precipitation by means of wind–topography interactions. Gaps in the mountains of southern Mexico and Central America allow strong wind jets to pass over the continent imprinting a unique signal in sea surface temperatures and ocean dynamics of the eastern tropical Pacific.The warm pools of the Americas constitute an important source of moisture for the North American Monsoon System. The northeastern tropical Pacific is a region of intense cyclogenetic activity, just west of the coast of Mesoamerica. Over the oceanic regions, large-scale properties of key variables such as precipitation, moisture, surface energy fluxes and wind stress curl are still uncertain, which inhibits a more comprehensive view of the region and stresses the importance of regional field experiments. Progress has been substantial in the understanding of the ocean and atmospheric dynamics of the eastern tropical Pacific, however, recent observational evidence such as that of a shallow meridional circulation cell in that region, in contrast to the classic concept of the Hadley-type deep meridional circulation, suggests that more in situ observations to validate theories are still necessary.This paper is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.     

Shallow necking depth and differential denudation linked to post‐rift continental reactivation: The origin of the Cenozoic basins in southeastern Brazil

The southeastern Brazilian margin presents post‐breakup Cenozoic tectonism that created a series of grabens and small sedimentary basins, known as the Continental Rift of Southeastern Brazil. The formation of this rift occurred long after the South Atlantic ocean opening and has been attributed to different mechanisms like regional uplift induced by hotspot activity, pulses of Andean orogeny and reactivation of pre‐existing faults. However, the proposed models lack an analytical or numerical verification from a geodynamic point of view. Based on finite element modelling of the lithospheric stress field evolution we conclude that a shallow necking depth, consistent with the hyperextended southeastern Brazilian margin, combined with differential denudation of the continent, resulted in an extensional stress field in the upper crust that induced the observed Cenozoic tectonism.     

Characterization of the chemical structures of natural and synthetic aluminosilicate gels and sols by infrared spectroscopy

Infrared spectra in the 300–1400 cm^?1 region indicate that the non-crystalline products of interaction between hydroxyaluminium species and orthosilicic acid in dilute aqueous solutions of pH < 5 differ markedly in structure from those formed in near-neutral and alkaline solutions of pH > 6. The compound formed in acid solution has an infrared spectrum similar to imogolite, and is termed proto-imogolite; like imogolite, it contains orthosilicate groups and 6-coordinated aluminium, and has an ideal Si:Al ratio of around 0.5, but it can incorporate some excess alumina or silica and it does not have the regular tubular structure of imogolite. Compounds formed in alkaline solutions that are not too dilute have infrared spectra resembling the feldspathoid group of minerals and are termed hydrous feldspathoids. They incorporate a condensed tetrahedral framework with an Si:Al ratio greater than one, but can also contain 6-coordinated aluminium.Natural allophanes of the proto-imogolite and hydrous feldspathoid types exist. The allophane of weathered pumice, however, contains a condensed silicate anion that incorporates little tetrahedral aluminium. Proto-imogolite forms stable sols at pH < 5 and must play an important role in the transport of aluminium in acidic natural waters containing dissolved silica.     

用超速CT机检测99例无症状香港中国人降低钙指数

回顾分析Ｍａｔｉｌｄａ医院超速ＣＴ室筛选首批病人中９９例中国人资料，很明显从通常采用１３０－１００Ｈｏｕｎｓｆｉｅｌｄ单位作为检出冠状血管钙化的基数应用至中国人身上其阈值数目需要降低，同时，我们也发现如果病人年龄按每１０年范围分组（２１－３０，３０－４０，４１－５０，５１－６０）而计算其超速ＣＴ的钙化指数会较随机男女一起按平均计算更易区分其差异．进一步分析显示，男性中年时候超速ＣＴ指数已达最高值，而女性则晚１０年方达最高值，因此，为了更易探测冠脉循环内钙化倾向应作出超速ＣＴ检出钙化的指数数目．这些实践经验对动脉粥样硬化过程的预测或预防有实际意义．     

Construction of Structural Geological Model Using Monte Carlo Simulation

Geotechnical and Geological Engineering - To optimize the prediction of structural geological conditions in the underground as of data collected at the surface, due to the usual great uncertainties...