Reconstruction of annual winter rainfall since A.D.1579 in central-eastern Spain based on calcite laminated sediment from Lake La Cruz

We present the first winter (December to March) rainfall reconstruction based in a novel proxy, the thickness of annual calcite laminations preserved in Lake La Cruz (central–eastern Spain). A previous calibration analysis between laminae thickness and the instrumental data series (1950 to present) indicated a highly significant correlation with winter rainfall. Therefore this study attempts the winter rainfall reconstruction since the onset of laminations (1579 a.d.) by means of the calibration function previously developed. The verification analysis between inferred annual values and earlier instrumental data (1859–1949) confirms the suitability of this novel proxy and the reliability of the series reconstructed. The reconstructed series show the fluctuating character of winter rainfall in the western Mediterranean area; interdecadal dry periods alternated with wetter periods following, in a board sense, the pattern recorded by documentary sources in other regions of the Iberian Peninsula. At present times regional winter rainfall anomalies are highly correlated with the phase of the North Atlantic Oscillation (NAO). However the time series analysis showed the dominance of nonstationary components at high frequencies of the climate signal over the last four centuries suggesting that the connection between winter rainfall and the NAO has not been stable over time and also other modes of variability, not only NAO, may have conditioned winter rainfall variability.     

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.     

Ontogenic shifts in predatory roles involving two invasive species

The red swamp crayfish, Procambarus clarkii, and the eastern mosquitofish, Gambusia holbrooki have been introduced worldwide, but the interactions between these invasive species are not well known. The effects of crayfish presence, crayfish size and water depth on the consumption of G. holbrooki by P. clarkii were analyzed, as were the effects of mosquitofish presence and water depth on the consumption of recently hatched crayfish (RHC) by mosquitofish. To better understand this subject we conducted aquaria and open air mesocosm experiments simulating a rice field section. Aquarium experiments showed that P. clarkii consumes G. holbrooki and that G. holbrooki consumes RHC. Adult crayfish size did not significantly affect the consumption of mosquitofish and water depth had no effect on the consumption of G. holbrooki by P. clarkii and vice versa. In the outdoor mesocosm experiments P. clarkii caused no statistically significant effect on G. holbrooki numbers or biomass when compared with controls without crayfish. In spite of this, the analysis of crayfish stomach contents clearly demonstrated that several G. holbrooki individuals were consumed, indicating that crayfish can profit from the presence of G. holbrooki. Results from our study suggest that in shallow pools there are strong interactions between the two invasive species since adult crayfish predate mosquitofish and mosquitofish predate recently hatched crayfish. Therefore, there are bidirectional trophic interactions between these invasive species which change depending on their relative size. We believe that these interactions should become more relevant in confined areas such as small shallow pools formed during the late summer and autumn.     

Impact of subsurface rock fragments on runoff and interrill soil loss from cultivated soils

Field and laboratory studies have indicated that rock fragments in the topsoil may have a large impact on soil properties, soil quality, hydraulic, hydrological and erosion processes. In most studies, the rock fragments investigated still remain visible at the soil surface and only properties of these visible rock fragments are used for predicting runoff and soil loss. However, there are indications that rock fragments completely incorporated in the topsoil could also significantly influence the percolation and water distribution in stony soils and therefore, also infiltration, runoff and soil loss rates. Therefore, in this study interrill laboratory experiments with simulated rainfall for 60 min were conducted to assess the influence of subsurface rock fragments incorporated in a disturbed silt loam soil at different depths below the soil surface (i.e. 0.001, 0.01, 0.05 and 0.10 m), on infiltration, surface runoff and interrill erosion processes for small and large rock fragment sizes (i.e. mean diameter 0.04 and 0.20 m, respectively). Although only small differences in infiltration rate and runoff volume are observed between the soil without rock fragments (control) and the one with subsurface rock fragments, considerable differences in total interrill soil loss are observed between the control treatment and both contrasting rock fragments sizes. This is explained by a rapid increase in soil moisture in the areas above the rock fragments and therefore a decrease in topsoil cohesion compared with the control soil profile. The observed differences in runoff volume and interrill soil loss between the control plots and those with subsurface rock fragments is largest after a cumulative rainfall (P_cum) of 11 mm and progressively decreases with increasing P_cum. The results highlight the impacts and complexity of subsurface rock fragments on the production of runoff volume and soil loss and requires their inclusion in process‐based runoff and erosion models. Copyright © 2011 John Wiley & Sons, Ltd.     

Performance enhancement of a GIS-based facility location problem using desktop grid infrastructure

This paper presents the integration of desktop grid infrastructure with GIS technologies, by proposing a parallel resolution method in a generic distributed environment. A case study focused on a discrete facility location problem, in the biomass area, exemplifies the high amount of computing resources (CPU, memory, HDD) required to solve the spatial problem. A comprehensive analysis is undertaken in order to analyse the behaviour of the grid-enabled GIS system. This analysis, consisting of a set of the experiments on the case study, concludes that the desktop grid infrastructure is able to use a commercial GIS system to solve the spatial problem achieving high speedup and computational resource utilization. Particularly, the results of the experiments showed an increase in speedup of fourteen times using sixteen computers and a computational efficiency greater than 87 % compared with the sequential procedure.     

Underground Temperature Measurements as a Tool for Volcanic Activity Monitoring in the Island of Tenerife, Canary Islands

The spatial distribution of groundwater temperatures in the volcanic island of Tenerife, Canary Islands, has been inferred through measurements of water temperatures collected in the vast network of wells and subhorizontal tunnels, locally called “galleries,” which constitutes the main water supply of the island. The spatial coverage of the network of galleries allows us to reach from depth almost any geological feature of the island. The complex spatial distribution of temperatures in the interior of Tenerife is the result of the complex geological evolution of the island. Groundwater temperatures are greatly affected by groundwater flow and are considerably warmer in those galleries located in areas where water circulation is reduced due to the low permeability of materials and/or to the low infiltration rate of cooling meteoric water. In this sense, groundwater temperature should be characterized in quiescent conditions (background level), in order to facilitate monitoring changes in heat flow, such as those induced by ascending gases expected with an increase in volcanic activity.     

Petrogenesis of the mafic igneous rocks of the Betic Cordilleras: A field, petrological and geochemical study

Mafic igneous rocks are widespread in the Nevado-Filábride Complex, the lowermost metamorphic unit of the internal zones of the Betic Cordilleras. They form intrusive, small, discontinuous bodies, predominantly dikes with subordinate small lava flows. The entire complex underwent alpine compressional metamorphism during the Paleogene continental collision, resulting in eclogites and blueschists in the mafic bodies and high-pressure assemblages in the intruded metasediments. Locally, weakly metamorphosed or completely unmetamorphosed igneous rocks with the same textural features occur as patches surrounded by eclogitized igneous rocks. The bulk rock chemistry of unmetamorphosed and completely metamorphosed mafic igneous rocks is consistent with an alkaline to transitional tholeiitic magmatism with typical within-plate geochemical characteristics. All but a few samples are nepheline normative and display REE and trace element characteristics typical of continental, rift-related magmatism. This conclusion is strongly supported by the mineral chemistry of the major constituents, in particular the calcic Ti-rich character of clinopyroxene, the lack of orthopyroxene, and the occurrence of kaersutitic amphibole. Incompatible trace element abundances and Sr and Nd isotopes support the provenance of these magmas from a variably metasomatized previously depleted sub-continental lithospheric mantle source. Received: 5 July 1999 / Accepted: 28 February 2000     

Stable Atmospheric Boundary-Layer Experiment in Spain (SABLES 98): A Report

This paper describes the Stable AtmosphericBoundary Layer Experiment in Spain (SABLES 98),which took place over the northern Spanish plateaucomprising relatively flat grassland,in September 1998. The main objectives of the campaign were to study the properties of themid-latitude stable boundary layer (SBL).Instrumentation deployed on two meteorologicalmasts (of heights 10 m and 100 m)included five sonic anemometers, 15 thermocouples,five cup anemometers and three propeller anemometers,humidity sensors and radiometers.A Sensitron mini-sodar and a tetheredballoon were also operated continuously. Atriangular array of cup anemometers wasinstalled to allow the detection ofwave events. Two nocturnal periods analysedon 14–15 and 20–21 September are used toillustrate the wide-ranging characteristics of the SBL.