A Parametric Approach for Dealing with Compositional Rounded Zeros

In this work, a parametric approach for replacing data below the detection limit, also known as rounded zeros, in compositional data sets is proposed. Compositional rounded zeros correspond to small proportions of some whole that cannot be reliably detected by the analytical instruments under given operating conditions. This kind of zeros appear frequently in the data collection process in geosciences. They must be treated in an adequate way before some multivariate analysis can be applied. Our procedure results from a modification of the Expectation-Maximization (EM) algorithm and is based on the additive log-ratio transformation. Its coherence with the nature of compositional data and with basic operations in the simplex sample space is checked. Using real data sets, we find that this approach improves other parametric and non-parametric techniques for compositional rounded zeros.     

Spatial and temporal structure of the Denmark Strait Overflow revealed by acoustic observations

In spite of the fundamental role the Atlantic Meridional Overturning Circulation (AMOC) plays for global climate stability, no direct current measurement of the Denmark Strait Overflow, which is the densest part of the AMOC, has been available until recently that resolve the cross-stream structure at the sill for long periods. Since 1999, an array of bottom-mounted acoustic instruments measuring current velocity and bottom-to-surface acoustic travel times was deployed at the sill. Here, the optimization of the array configuration based on a numerical overflow model is discussed. The simulation proves that more than 80% of the dense water transport variability is captured by two to three acoustic current profilers (ADCPs). The results are compared with time series from ADCPs and Inverted Echo Sounders deployed from 1999 to 2003, confirming that the dense overflow plume can be reliably measured by bottom-mounted instruments and that the overflow is largely geostrophically balanced at the sill.     

Physics of basic motions in asymmetric continuum

We consider the advantages of a formalism based on concept of the asymmetric continuum and we present some equivalence theorems relating it to the asymmetric elasticity and to micropolar and micromorphic theories as founded by Nowacki, Cosserats and Eringen. We consider the basic processes in an asymmetric continuum which could be reduced to the point basic motions/deformations. The co-action of spin and shear motions is assumed to play the main role in fracturing process, while the constitutive relation between the antisymmetric stresses and rotations replaces the friction constitutive law.     

Evolutionary properties of stochastic models of earthquake accelerograms: Their dependence on magnitude and distance

An approach to generate artificial earthquakeaccelerograms on hard soil sites is presented. Eachtime-history of accelerations is considered as arealization of a non-stationary gaussian stochasticprocess, with statistical parameters depending onmagnitude and source-to-site distance. In order tolink the values of these parameters for each groundmotion record with the corresponding magnitude andsource-to-site distance, semi-empirical functionalrelations called generalized attenuationfunctions are determined. The set of realground-motion time histories used to obtain thesefunctions correspond to shocks generated at differentsources and recorded at different sites in thevicinity of the southern coast of Mexico. The resultsshow significant dispersion in the parameters of themodel adopted, which reflect that associated with thereal earthquakes included in the sample employed.The problem of conditional simulation of artificialacceleration time histories for prescribed intensitiesis briefly presented, but its detailed study is leftfor a companion paper. The criteria and modelsproposed are applied to generate two families ofartificial acceleration records for recurrenceintervals of 100 and 200 years at a specific sitelocated in the region under study. The results shownin this article correspond to acceleration timehistories recorded on firm ground for earthquakesgenerated at the subduction zone that runs along thesouthern coast of Mexico, and cannot be generalized tocases of earthquakes generated at other sources orrecorded at other types of local conditions. Thismeans that the methods and functional forms presentedhere are applicable to these other cases, but thevalues of the parameters that characterize thosefunctions may differ from those presented here.     

Heavy metals pollution of aquatic ecosystems in the vicinity of a recently closed underground lead-zinc mine (Basque Country, Spain)

A presentation is made of the study of an underground polymetallic sulphide mine and the pollution caused by this in the adjoining aquatic ecosystems. Troya Mine is in the Basque Cantabrian region (northern Spain). The annual production of the ore deposit of over 3.7 million tons of Pb (0.9%), Zn (11.2%) and Cu (0.2%) was 300,000 t. It was open and producing from 1986-1993. The mineralization was made up of pyrite, marcasite, sphalerite, galena, chalcopyrite and arsenopyrite. Only the Zn and the Pb were mined. We studied the distribution and behaviour of the heavy metals Zn, Pb, Fe, Mn, Cu, Cr and Cd in the water column, dissolved and suspended fractions, and in the sediments of Estanda Stream and of Gezala Creek. Zn, Cd and Mn tend to be found in the water; Fe, Pb, Cu and Cr appear as an adsorbed fractionin the solid phases. Those of the second group are significantly linked to the fluvial sediments and present very high levels. The concentrations of the metals are conditioned by the waters from the mine galleries, by the leached waste, by the surface runoff, and by overflow from the spillway of the tailings pond. Our observations provide knowledge on the extent of the polluting power of the metals, the physico-chemical effects in play and the subsequent chances of recovering these highly affected environments.     

Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.     

Numerical Simulation Of Oil/Oily-Contaminant Migration And Entrapment In A Lenticular Reservoir

Numerical simulations show that water and oil/oily-contaminant migration are controlled by regional fluid-potential fields which may be modified locally by highly permeable lenses and buoyancy. In addition, fluid potentials are coupled to the distribution of oil/oily-contaminant via relative permeability and capillary-pressure curves. As saturation distributions evolve through space and time, so do the water and oil fluid-potential surfaces. The importance of capillary forces in oil contaminant migration and entrapment is illustrated by the fact that, in certain cases, lenses fill from above, even when the migrating fluid is lighter than water. Capillary forces operating in conjunction with lenticular reservoirs create excellent dynamic oil traps by allowing free passage of water, while retaining and concentrating oil. The analysis of oil (oily-contaminant) migration using numerical modeling and potentiometric-surface techniques is useful for the prediction of migration pathways and potential accumulation sites. On the other hand, identifying acatual accumulations from fluid-potential measurements (via inverse modeling) is not possible because fluid potentials are not uniquely dependent on saturation.