Mineralogical and geochemical features of authigenic carbonates on seepings and hydrothermal fields (By the examples of the Black Sea reefs and the mounds of the lost city field)

Two genetically different types of authigenic carbonate mounds are studied: those within an active hydrothermal field related to serpentinite protrusions in the zone of intersection of a transform fracture zone and the Mid-Atlantic Ridge, and those in an active field of methane seepings in the Dnieper canyon of the Black sea. The general geochemical conditions under which authigenic carbonate formation occurs in the two fields considered were found. They include the presence of reduced H₂S, H₂, and CH₄ gases at the absence of free oxygen; the high alkalinity of the waters participating in the carbonate formation; the similarity of the textural and structural features of authigenic aragonite, which represents the initial mineral of the carbonate matter of the mounds; the paragenesis of aragonite with sulfide minerals; and the close relation of carbonate mounds with communities of sulfate-reducing and methane-oxidizing microorganisms. A new mechanism of formation of hydrothermal authigenic carbonates is suggested; it implies their microbial sulfate reduction over the hydrogen of the fluid in the subsurface zone (biosphere) of mixing between the hydrothermal solution and the adjacent seawater.     

The Aleutian Low, storm tracks, and winter climate variability in the Bering Sea

Previous studies have found inconsistent results regarding how wintertime conditions in the Bering Sea relate to variations in the North Pacific climate system. This problem is addressed through analysis of data from the NCEP/NCAR Reanalysis for the period 1950–2003. Composite patterns of sea-level pressure, 500 hPa geopotential heights, storm tracks and surface air temperature are presented for four situations: periods of strong Aleutian Low, weak Aleutian Low, warm Bering Sea air temperatures, and cold Bering Sea air temperatures. Winter temperatures in the Bering Sea are only marginally related to the strength of the Aleutian Low, and are much more sensitive to the position of the Aleutian Low and to variations in storm tracks. In particular, relatively warm temperatures are associated with either an enhanced storm track off the coast of Siberia, and hence anomalous southerly low-level flow, or an enhanced storm track entering the eastern Bering Sea from the southeast. These latter storms do not systematically affect the mean meridional winds, but rather serve to transport mild air of maritime origin over the Bering Sea. The leading indices for the North Pacific, such as the NP and PNA, are more representative of the patterns of tropospheric circulation and storm track anomalies associated with the strength of the Aleutian Low than patterns associated with warm and cold wintertime conditions in the Bering Sea.     

Quasi-biennial variations in ozone and meteorological parameters over western Europe from ozonesonde data

Quasi-biennial variations in vertical profiles of ozone, temperature, air pressure, and zonal and meridional wind velocities are analyzed from ozonesonde data obtained at the western European stations of Lindenberg, Hohenpeissenberg, and Payerne. The effect of quasi-biennial variations manifests itself variously in different variables and is nonuniform in altitude. The period of quasi-biennial variations is not constant, and the values of the mean period group mainly around 2 and 2.5 years. As in the North American region, the effects of quasi-biennial variations in different parameters of the stratosphere and troposphere over western Europe are due to a combination of the effects of the quasi-biennial oscillation (QBO) in the equatorial stratosphere, the El Niño-Southern Oscillation (ENSO), and the North Atlantic Oscillation (NAO). The observed 2.5-year variations in stratospheric ozone are related to the equatorial QBO to a larger extent in comparison with variations in other variables. It seems likely that a determining influence on variations in stratospheric wind and temperature is exerted by the ENSO. Variations in tropospheric and stratospheric parameters with a mean period of about 2 years are due to the ENSO and NAO effects.     

Suspended barite as a tracer of biological activity in the Southern Ocean

During two cruises in the Southern Ocean (INDIGO 3, Indian sector and EPOS 2, Scotia-Weddell Confluence) suspended matter samples were collected for analysis of several biogenic elements including Ba, Si and particulate organic carbon (POC).The good agreement between particulate barium in subsurface water with oxygen minimum concentrations as well as with nitrate depletions suggests that it reflects the intensity of new production over the past season. As a consequence of new production in the Southern Ocean being performed mainly by diatoms, the occurrences of barite and diatoms are related in the water column. In areas characterized by diatom-poor phytoplankton, barite does occur, but in lower concentrations.     

A nomogram method for predicting the movement of oil slicks

In order to obtain quick initial guidance on a first estimation of motion of the spilled oil, a simple manual procedure incorporating advection and spreading processes has been devised. This procedure involves the utilization of a nomogram based on simplified equations. Spill displacements throughout a given forecast period can be easily read from the nomogram. The technique is demonstrated with a real spill case.     

Structure of the Wave Bottom Boundary Layer over Smooth and Rough Bottoms

The comparison of six well-known models of the wave bottom boundary layer shows that they are identical in the case of a smooth bottom but exhibit serious differences for the other types of conditions. The thickness of the wave bottom boundary layer and the coefficient of vertical diffusion of momentum are studied by using the relations of the k-ε-model. The validity of these estimates is checked by comparing the measured and computed values of the friction velocity. This comparison demonstrates fairly good agreement between the results characterized by a coefficient of correlation equal to 0.851. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 54–67, November–December, 2005.     

Co–rich Mn crusts from the Magellan Seamount cluster: the long journey through time

The Magellan seamounts began forming as large submarine shield volcanoes south of the equator during the Cretaceous. These volcanoes formed as a cluster on the small Pacific plate in a period when tectonic stress was absent. Thermal subsidence of the seafloor led to sinking of these volcanoes and the formation of guyots as the seamounts crossed the equatorial South Pacific (10–0°S) sequentially and ocean surface temperatures became too high for calcareous organisms to survive. Guyot formation was completed between about 59 and 45 Ma and the guyots became phosphatized at about 39–34 and 27–21 Ma. Ferromanganese crusts began formation as proto-crusts on the seamounts and guyots of the Magellan Seamount cluster towards the end of the Cretaceous up to 55 Ma after the formation of the seamounts themselves. The chemical composition of these crusts evolved over time in a series of steps in response to changes in global climate and ocean circulation. The great thickness of these crusts (up to 15–20 cm) reflects their very long period of growth. The high Co contents of the outer parts of the crusts are a consequence of the increasing deep circulation of the ocean and the resulting deepening of the oxygen minimum zone with time. Growth of the Co-rich Mn crusts in the Magellan Seamount cluster can be considered to be the culmination of a long journey through time.     

Viscous model of plate tectonics for the Black Sea region (in relation to the problem of the late Cenozoic evolution of the Black Sea basins)

A numerical model of the Black Sea region (Northeastern Mediterranean) is presented in which it is regarded as a part of the mosaic plate ensemble consisting of the fixed East European platform; the active Arabian, Adriatic, and Pannonian plates; and passive East and West Black Sea and Mysian microplates, which are embedded in a plastically deformable regional orogenic matrix. The fields of displacements, stresses, and deformations in the region are calculated by means of the finite element method within the framework of a linear-viscous rheology approach to a system with nonhomogeneous viscosities. The velocity field obtained is in good agreement with published data of direct observations of plate displacements in the region. In the pressure field, areas of low pressure and decompression are established in the western part of Black Sea and in the south of the Mysian microplate. The poles of rotation of the East and West Black Sea microplates and of the Mysian microplate are computed. For the latter two microplates, significant rotational components are suggested. The East Black Sea microplate acts mostly as indenter, which transmits the collisional motion from the Arabian plate to the southern edge of the East European platform including the Crimea. According to the geodynamical model, the rates of the Cenozoic sedimentation in the Black Sea depression at the collision stage (Oligocene-Pliocene) result from the greater compression of the East Black Sea microplate as compared to the West Black Sea microplate, which, probably, experienced a kind of extension.