An anthropo-ecological approach to landscape use optimization

A method of landscape evaluation based on the anthropo-ecological approach is worked out. The procedure consists of three stages, viz., general, special and optimization. Within the general stage, the structural arrangement of the landscape is evaluated by means of the concept of geo-ecological sites (GES), which are distributed into four zones (A, B, C, D) according to the degrees of their anthropic disturbance. The zoning performed makes it possible to select those geo-ecological sites where eco-critical relationships can be expected to appear; in order to eliminate such situations, transition zones are calculated for the geo-ecological sites concerned. The outcome of this approach is a proposal of a new structural arrangement of the geo-ecological sites, solving eco-critical situations and serving as a basis for the special and optimization stages of the anthropo-ecological method.     

Hydraulic Conductivity Tests for Evaluating Compatibility of Lateritic Soil—Fly Ash Mixtures with Municipal Waste Leachate

Long term competent performance of liner systems is a critical issue in the design and construction of waste repositories due to adverse interactions associated with leachate generated by wastes. This study was conducted to verify the efficacy of fly ash stabilization in enhancing compatibility between lateritic soil and municipal waste leachate. Applications investigated include soil mixtures containing 0, 5, 10, 15, and 20% fly ash compacted at approximately 2% wet of optimum moisture content with modified proctor energy. Baseline hydraulic conductivity was first established at every level of fly ash content by permeating soil mixtures with tap water before permeation with leachate in a compaction mould permeameter using the falling head test method. Results show that the trend in hydraulic conductivity of specimen containing 0% fly ash was characterized by a gradual but erratic decrease which may suggests partial entry of the leachate cations into the double layer. Conversely, specimens containing fly ash showed a general trend consisting of an initial drop in k (up to an order of magnitude) that was followed by slight decrease sustained until k stabilized and later terminated. Above 10% fly ash content, the relatively high values of k observed was not connected with the reactivity of the soil mixtures with leachate, rather it may be attributed to excessive fly ash content that altered their textural and hydraulic properties. The result of this study is potentially significant in the assessment of fly ash as a compatibility enhancing agent which can be admixed in barrier materials that are susceptible to adverse reactions with the liquid to be contained.     

Description and interpretation of the composition of fluid and alteration mineralogy in the geothermal system,at Svartsengi,Iceland

The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm³ is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO₂, 10 gm H₂S and 4 gm Na₂O and a release of 57 gm SiO₂, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K₂O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous.     

A new solid state diffusion model applied to inverse zoning and diffusion rims in minerals

Any oxide and silicate mineral which is nominally anhydrous but crystallized in the presence of H₂O incorporates traces of H₂O in solid solution. In the case of MgO it can be shown that OH^? pairs convert into H₂+O ₂ ^2? . If the H₂ molecules are lost, the O ₂ ^2? remain in the lattice as excess oxygen stabilized by excess cation vacancies. When the O ₂ ^2? anions decay either thermally or by decompression unbound O^? states (positive holes) are generated which lead to surface charges and subsurface space charge layers. Calculated space charge profiles are presented. O^? concentrations as small as 10–20 ppm suffice to create electric surface fields of the order of 4·10⁷ V·m^?1. The diffusion mechanism which derives from these premises incorporates novel features: the cation diffusion is coupled to the counterdiffusion of unbound and vacancy-bound O^? states. The cation diffusion is predicted to be very fast because first, it is field-enhanced (electrochemically driven) and second, it is not rate-limited by the intrinsic cation vacancy concentration nor by the counter-diffusion of other cations. The model may apply to cases of inverse zoning and diffusion rim formation in minerals under certain P-T conditions.     

A study on the interpretation of spontaneous potential and resistivity logs in layered aquifer sequence of Pondicherry Region,South India

Geophysical logs provide a strong mechanism for interpretation and determination of the depositional environments, facies and also help in interpretations of hydrogeologic units. Spontaneous potential (SP) and resistivity logs can be used as an indicator of textural parameters. Pondicherry region has a complicated geology and with formation of different ages. The boreholes (BH) of this region are examined for litholog, SP and resistivity from four different BH locations, viz, Ariyankuppam, Chinnaverampattinam, Thavalakuppam and Nallavadu. These locations were studied and interpreted by using the shapes of the curves to identify the depositional environments, and this was later compared with the vertical litholog profile. Comparing the variation of these logs, the lateral variation of sedimentary facies was also attempted. The average resistivity values of Ariyankuppam, Chinnaverampattinam, Thavalakuppam and Nallavadu are 42.4, 30.4, 50.4 and 28.3?Ωm, respectively. Majority of the resistivity values corresponds from fine- to medium-grained sand, clayey pebbles, fine to very coarse sand and clayey sand with lignite. Frequency of resistivity values in each BH were identified for determining the dominant representative grain size. The study has pointed out the lithological variation of the system laterally and vertically using geophysical well logs.     

Distribution of forms of sulfur in peats from saline environments in the Florida Everglades

Although there is published information on the mechanism of sedimentary pyrite formation resulting from bacterial reduction of sulfate, little is known about the distribution of forms of sulfur, including organic, in peats. In order to increase understanding of the geochemistry of sulfur in coals, we have determined distributions of forms of sulfur in five cores of saline peat and one of brackish peat, all from areas near the Shark River and Whitewater Bay in the coastal swamps of south Florida. All concentrations vary widely with depth. Total sulfur concentrations range up to 6% of dry solids. Minor amounts of sulfur are present as H₂S, S⁰, SO₄²⁻, and acid-soluble sulfide, but the principal forms are usually pyritic and organic. The ratio, organic/pyritic, is highly variable, but at a majority of levels in a profile is considerably greater than unity. It is inferred that topochemical factors are important in determining the distribution of sulfur forms in any element of volume.     

Physical Libration of the Moon: An Extended Problem

Astronomy Reports - The work is devoted to the study of the physical libration of the Moon. Interest in the traditional topic related to the rotation of the Moon is stirred up by the activity of...     

Interaction of the Atmosphere and Lithosphere in the Minute Range of Periods

Doklady Earth Sciences - The interaction between the atmosphere and the lithosphere in the minute range of periods is considered. The technique of assessment of the influence of atmospheric...