Methane and carbon dioxide sorption on a set of coals from India

Complete sorption isotherm characteristics of methane and CO₂ were studied on fourteen sub-bituminous to high-volatile bituminous Indian Gondwana coals. The mean vitrinite reflectance values of the coal samples are within the range of 0.64% to 1.30% with varying maceral composition. All isotherms were conducted at 30 °C on dry, powdered coal samples up to a maximum experimental pressure of ~ 7.8 MPa and 5.8 MPa for methane and CO₂, respectively.The nature of the isotherms varied widely within the experimental pressure range with some of the samples remained under-saturated while the others attained saturation. The CO₂ to methane adsorption ratios decreased with the increase in experimental pressure and the overall variation was between 4:1 and 1.5:1 for most of the coals. For both methane and CO₂, the lower-ranked coal samples generally exhibited higher sorption affinity compared to the higher-ranked coals. However, sorption capacity indicates a U-shaped trend with rank. Significant hysteresis was observed between the ad/desorption isotherms for CO₂. However, with methane, hysteresis was either absent or insignificant. It was also observed that the coal maceral compositions had a significant impact on the sorption capacities for both methane and CO₂. Coals with higher vitrinite contents showed higher capacities while internite content indicated a negative impact on the sorption capacity.     

Palynology, palaeoecology and palaeodepositional environment of Eocene lignites and associated sediments from Matanomadh mine, Kutch Basin, western India

Extensive Cenozoic lignite-bearing sediments in the western part of Kutch, western India provide a unique opportunity to study the floral diversity at a crucial time of early Eocene Climatic Optimum (EECO). Rock samples representing a lignite-bearing sequence from the open cast mine at Matanomadh, Gujarat, western India were collected to study the palynofloral composition and to interpret the palaeoclimate and environment of deposition. The sequence mainly composed of lignites, shales and calcareous mudstones yielded rich assemblage consists of pteridophytic spores (7 genera, 10 species), angiosperm pollens (20 genera, 26 species), fungal remains (14 genera, 16 species) and dinoflagellate cysts. The palynofloral assemblage is marked with dominance of angiospermic pollen, particularly those having affinity with the family Arecaceae. Occurrence of fungal remains in high abundance is also noticed. Based on palynomorph contents, the studied sequence is divisible into two palynozones. It is inferred that lower part of the sequences was deposited in a near-shore environment with intermittent marine incursions whereas the depositional regime of upper part was shallow marine. The climate is found to be tropical-subtropical, humid with heavy precipitation during the deposition of Matanomadh lignite-bearing sequence.     

Intensity forecast of tropical cyclones over North Indian Ocean using multilayer perceptron model: skill and performance verification

The coastal regions of India are profoundly affected by tropical cyclones during both pre- and post-monsoon seasons with enormous loss of life and property leading to natural disasters. The endeavour of the present study is to forecast the intensity of the tropical cyclones that prevail over Arabian Sea and Bay of Bengal of North Indian Ocean (NIO). A multilayer perceptron (MLP) model is developed for the purpose and compared the forecast through MLP model with other neural network and statistical models to assess the forecast skill and performances of MLP model. The central pressure, maximum sustained surface wind speed, pressure drop, total ozone column and sea surface temperature are taken to form the input matrix of the models. The target output is the intensity of the tropical cyclones as per the T??number. The result of the study reveals that the forecast error with MLP model is minimum (4.70?%) whereas the forecast error with radial basis function network (RBFN) is observed to be 14.62?%. The prediction with statistical multiple linear regression and ordinary linear regression are observed to be 9.15 and 9.8?%, respectively. The models provide the forecast beyond 72?h taking care of the change in intensity at every 3-h interval. The performance of MLP model is tested for severe and very severe cyclonic storms like Mala (2006), Sidr (2007), Nargis (2008), Aila (2009), Laila (2010) and Phet (2010). The forecast errors with MLP model for the said cyclones are also observed to be considerably less. Thus, MLP model in forecasting the intensity of tropical cyclones over NIOs may thus be considered to be an alternative of the conventional operational forecast models.     

Bifurcations of dust ion acoustic travelling waves in a magnetized quantum dusty plasma

Bifurcation behavior of nonlinear dust ion acoustic travelling waves in a magnetized quantum dusty plasma has been studied. Applying the reductive perturbation technique (RPT), we have derived a Kadomtsev-Petviashili (KP) equation for dust ion acoustic waves (DIAWs) in a magnetized quantum dusty plasma. By using the bifurcation theory of planar dynamical systems to the KP equation, we have proved that our model has solitary wave solutions and periodic travelling wave solutions. We have derived two exact explicit solutions of the above travelling waves depending on different parameters.     

Parametric study of a physically-based,plot-scale hillslope hydrological model through virtual experiments

Abstract

A physically-based hillslope hydrological model with shallow overland flow and rapid subsurface stormflow components was developed and calibrated using field experiments conducted on a preferential path nested hillslope in northeast India. Virtual experiments were carried out to perform sensitivity analysis of the model using the automated parameter estimation (PEST) algorithm. Different physical parameters of the model were varied to study the resulting effects on overland flow and subsurface stormflow responses from the theoretical hillslopes. It was observed that topographical shapes had significant effects on overland flow hydrographs. The slope profiles, surface storage, relief, rainfall intensity and infiltration rates primarily controlled the overland flow response of the hillslopes. Prompt subsurface stormflow responses were mainly dominated by lateral preferential flow, as soil matrix flow rates were very slow. Rainfall intensity and soil macropore structures were the most influential parameters on subsurface stormflow. The number of connected soil macropores was a more sensitive parameter than the size of macropores. In hillslopes with highly active vertical and lateral preferential pathways, saturation excess overland flow was not evident. However, saturation excess overland flow was generated if the lateral macropores were disconnected. Under such conditions, rainfall intensity, duration and preferential flow rate governed the process of saturation excess overland flow generation from hillslopes.

Editor D. Koutsoyiannis; Associate editor C. Perrin     

Probing the neutral fraction of the IGM with GRBs during the epoch of reionization

We show that near-infrared observations of the red side of the Lyα line from a single gamma-ray burst (GRB) afterglow cannot be used to constrain the global neutral fraction of the intergalactic medium (IGM),     , at the GRB's redshift to better than     . Some GRB sightlines will encounter more neutral hydrogen than others at fixed     owing to the patchiness of reionization. GRBs during the epoch of reionization will often bear no discernible signature of a neutral IGM in their afterglow spectra. We discuss the constraints on     from the   z = 6.3  burst, GRB050904, and quantify the probability of detecting a neutral IGM using future spectroscopic observations of high-redshift, near-infrared GRB afterglows. Assuming an observation with signal-to-noise ratio similar to the Subaru FOCAS spectrum of GRB050904 and that the column density distribution of damped Lyα absorbers is the same as measured at lower redshifts, a GRB from an epoch when     can be used to detect a partly neutral IGM at 97 per cent confidence level ≈10 per cent of the time (and, for an observation with three times the sensitivity, ≈30 per cent of the time).     

Investigation on the Influence of the Column Ozone Anomaly on the Energetics of Tropical Cyclones Over NIO and Related Air–Sea Interaction

An investigation on the temporal and spatial variation of ozone using the total column ozone (TCO) values during the cyclonic activities over North Indian Ocean (NIO) is carried out during the period from 1997 to 2012. The stepwise variation of TCO during the passage of the tropical cyclones over the Bay of Bengal and the Arabian Sea of the NIO is examined. The anomalies in TCO are estimated at each step of the life span of the cyclones starting from the genesis to landfall stages. The result reveals that the TCO values are quite high prior to the formation of the depression over NIO; however, at the stage of cyclogenesis it decreases which, with the increase in the intensity of the cyclones, further decreases and becomes minimum near the coast during the landfall. The maximum negative anomaly in TCO is observed for maximum intensity of the tropical cyclones as well as during the landfall. The result further shows that when the cyclones die out after the landfall the TCO regains the normal value. It is further observed that the reduction in TCO enhances the accumulated cyclone energy over NIO. The result finally shows that, the higher the energy of the cyclones, the lower becomes the stratospheric warming, that is, the higher the stratospheric cooling.     

Relative performance of focused and unfocused devices in a two-dimensional borehole environment

Borehole direct current (dc) resistivity problems are solved using finite difference method (FDM) primarily to extend the log interpretation in the two-dimensional (2D) domain. Transitional invaded zone, flushed zone, uncontaminated zone, shoulder beds and borehole filled with mud are simulated simultaneously in the model. Linear variation of resistivity is assumed for transitional invaded zone. Normal, lateral and modified laterolog7 (LL7⁴) electrode configuration (discussed in the text) responses were computed using expanding rectangular grid system. LL7⁴ responses with variable geometric factor did show some superiority over the conventional normal and lateral for conductive target beds sandwiched between the resistive beds. For relatively small borehole diameter, all three probes can detect resistive target bed satisfactorily. However, for highly conductive mud both LL7⁴ and normal electrode configuration fail to detect any signal from the target bed. Bypassing effect of the current for LL7⁴ is more than that in normal log. Lateral log shows a signal of conductive invaded zone generated by the conductive mud. Bucking current ratio peaks and the geometric factor peaks in LL7⁴ can detect the bed boundaries.     

First report of trace fossils from Palaeogene succession (Namunagarh grit) of Andaman and Nicobar islands

The Namunagarh grit of Eocene age in South Andaman island is a submarine fan deposit where sedimentation occurred in deep marine environment mainly by turbidity currents. The mudstone and fine-grained sandstone of the turbidite sequence yielded three ichnogenera viz Thalassinoides, Teichichnus and Lorenzinia. Typically shallow marine Thalassinoides burrows co-occur with deep water burrows represented by Teichichnus and Lorenzinia, indicating a dominant control of substrate, availability of food and rate of sedimentation against bathymetry on distribution of trace fossils. Trace fossils are particularly abundant in the mudstones pointing to a strong lithofacies control. A well-oxygenated muddy bottom with a low rate of sedimentation is envisaged. An order in the succession of traces could be deciphered. Simply constructed burrows of Thalassinoides appeared initially followed by complex structures of Teichichnus and ornate Lorenzinia.