Variability and alterations of water temperatures across the Elbe and Danube River Basins

Climate change is predicted to be a major threat to river ecosystems in the 21st century, but long-term records of water temperature in streams and rivers are rare. This study uses long-term water temperature series from the Elbe and the Danube River Basin to quantify the variability, magnitude, and extent of temperature alterations at different time scales. The observed patterns in monthly and daily water temperatures have been successfully described through statistical models based on air temperature, river discharge and the North Atlantic Oscillation Index. These models reveal that air temperature variability describes more than 80 % of the total water-temperature variability, linking anticipated changes in water temperature mainly to those in air temperature. The North Atlantic Oscillation effect deteriorates with decreasing latitude, while the discharge effect becomes more important and increases with the increase in discharge amount. The detected water temperature alterations include a phase shift in spring warming of almost 2 weeks, an increase in the number of days with temperatures above 25 °C and an increase in the duration of summer heat stress. These findings underline a significant risk for fundamental changes in river ecosystems, specifically in disruption of established patterns in food-web synchrony, and may lead to significant distortions in community structure and composition.     

Redox-dependent removal of 27 organic trace pollutants: compilation of results from tank aeration experiments

The biodegradation of various wastewater-derived organic trace pollutants occurring in different aquatic compartments of the environment was previously reported to be influenced by the prevailing redox conditions. However, comparative studies on the redox-dependent degradation behavior of organic trace pollutants are scarce. The objective of the study presented herein, was to compile and evaluate data from several comparable previous tank experiments, thus, providing an overview on the redox-dependent removal of a total of 27 wastewater-derived trace compounds, including phenazone type compounds, antimicrobials, ß-blockers, psychoactive drugs and sulfonamides. Removal rate constants were fitted assuming first-order degradation kinetics. Six compounds were identified to be removed solely under oxic, three compounds solely under anoxic conditions. Others persisted under all experimental conditions, while some were removed under both oxic and anoxic conditions.     

Reference Values Following ISO Guidelines for Frequently Requested Rock Reference Materials

We present new reference values for nineteen USGS, GSJ and GIT‐IWG rock reference materials that belong to the most accessed samples of the GeoReM database. The determination of the reference values and their uncertainties at the 95% confidence level follows as closely as possible ISO guidelines and the Certification Protocol of the International Association of Geoanalysts. We used analytical data obtained by the state‐of‐the‐art techniques published mainly in the last 20 years and available in GeoReM. The data are grouped into four categories of different levels of metrological confidence, starting with isotope dilution mass spectrometry as a primary method. Data quality was checked by careful investigation of analytical procedures and by the application of the Horwitz function. As a result, we assign a new and more reliable set of reference values and respective uncertainties for major, minor and a large group of trace elements of the nineteen investigated rock reference materials.