Mg-Fe partitioning between silicate spinel and magnesiowüstite at high pressure: experimental determination and calculation of phase relations in the system Mg2SiO4-Fe2SiO4

 Mg-Fe partitioning experiments between (Mg,Fe)₂SiO₄ spinel and (Mg,Fe)O magnesiowüstite were carried out at pressures of 17–21.3 GPa at temperatures of 1400 and 1600 °C, using a multi-anvil apparatus, in order to determine interaction parameters of spinel and magnesiowüstite solid solutions and also to constrain the equilibrium boundaries of the postspinel transition in the Fe-rich side in the system Mg₂SiO₄-Fe₂SiO₄. The obtained values of the interaction parameters were 3.4 ± 1.5 and 13.9 ± 1.4 kJ mol⁻¹, respectively, for spinel and magnesiowüstite solid solutions at 19 GPa and 1600 °C. The partitioning data in the system Mg₂SiO₄-Fe₂SiO₄ at 1400 and 1600 °C showed that the transition boundary between spinel and the mixture of magnesiowüstite and stishovite has a negative dP/dT slope. Using the above interaction parameters and available thermodynamic data of the Mg₂SiO₄ and Fe₂SiO₄ end members, the transition boundaries of spinel to the mixture of magnesiowüstite and stishovite were calculated. Within the uncertainties of the data used, the calculated boundaries are in good agreement with the boundaries at 1400 and 1600 °C experimentally determined in this study. The dissociation boundary of Fe₂SiO₄ spinel to wüstite and stishovite, calculated from the thermodynamic data, has a negative slope of −1.5 ± 0.6 MPa K⁻¹. Received: 18 February 1998 / Revised, accepted: 18 October 1999     

Reliability analysis of soil liquefaction based on standard penetration test

A review of probabilistic and deterministic liquefaction evaluation procedures reveals that there is a need for a comprehensive approach that accounts for different sources of uncertainty in liquefaction evaluations. For the same set of input parameters, different models provide different factors of safety and/or probabilities of liquefaction. To account for the different uncertainties, including both the model and measurement uncertainties, reliability analysis is necessary. This paper presents a review and comparative study of such reliability approaches that can be used to obtain the probability of liquefaction and the corresponding factor of safety. Using a simplified deterministic Seed method, this reliability analysis has been performed. The probability of liquefaction along with the corresponding factor of safety have been determined based on a first order second moment (FOSM) method, an advanced FOSM (Hasofer–Lind) reliability method, a point estimation method (PEM) and a Monte Carlo simulation (MCS) method. A combined method that uses both FOSM and PEM is presented and found to be simple and reliable for liquefaction analysis. Based on the FOSM reliability approach, the minimum safety factor value to be adopted for soil liquefaction analysis (depending on the variability of soil resistance, shear stress parameters and acceptable risk) has been studied and a new design safety factor based on a reliability approach is proposed.     

Provenance implications of Th–U–Pb electron microprobe ages from detrital monazite in the Carboniferous Upper Silesia Coal Basin, Poland

This paper reports the results of CHIME (chemical Th–U–Pb isochron method) dating of detrital monazites from Carboniferous sandstones in the Upper Silesia Coal Basin (USCB). A total of 4739 spots on 863 monazite grains were analyzed from samples of sandstone derived from six stratigraphic units in the sedimentary sequence. Age distributions were identified in detrital monazites from the USCB sequence and correlated with specific dated domains in potential source areas. Most monazites in all samples yielded ca. 300–320 Ma (Variscan) ages; however, eo-Variscan, Caledonian and Cadomian ages were also obtained. The predominant ages are comparable to reported ages of certain tectonostratigraphic domains in the polyorogenic Bohemian Massif (BM), which suggests that various crystalline lithologies in the BM were the dominant sources of USCB sediments.     

Seismic performance evaluation of steel arch bridges against major earthquakes. Part 2: simplified verification procedure

The performance‐based philosophy has been accepted as a more reasonable design concept for engineering structures. For this purpose, capacity evaluation and demand prediction procedures for civil engineering structures under earthquake excitations are of great significance. This work presents a displacement‐based seismic performance verification procedure including capacity and seismic demand predictions for steel arch bridges and investigates its applicability. Pushover analyses is employed as a basis in this method to investigate the structure's behaviors. A failure criterion for steel members accounting for the effect of local buckling is involved and an equivalent single‐degree‐of‐freedom (ESDOF) system with a simplified bilinear hysteretic model formulated using pushover analyses results is introduced to estimate the displacement capacity and maximum demand of steel arch bridges under major earthquakes. To check the accuracy of the proposed method, seismic capacities and demands from multi‐degree‐of‐freedom (MDOF) time‐history analyses with Level‐II design earthquake record inputs modeling major earthquakes are used as benchmarks for comparison. By a case study, it is clarified that the proposed prediction procedure can give accurate estimations of displacement capacities and demands of the steel arch bridge in the transverse direction, while insufficient for the longitudinal direction, which confirms the conclusion drawn in other structure types about the applicability of pushover analyses. Copyright © 2004 John Wiley & Sons, Ltd.     

Evaluation of sheet pile-ring countermeasure against liquefaction for oil tank site

The evaluation of a countermeasure against liquefaction which uses a sheet pilering for oil tank sites is presented. The simulation of earthquake responses observed at tank sites with and without sheet pile-ring is first performed to validate the three-dimensional finite element numerical model. Using the numerical model, liquefaction analysis is performed and the excess pore water pressure generated in the soil and the settlement of tank are investigated. The comparison of two- and three-dimensional models is also conducted to assess the applicability of two-dimensional analysis. The results show that the numerical model could simulate the observed earthquake responses of tank-ring-soil system, and that the excess pore water pressure and the settlement of the tank could be significantly reduced using a sheet pile-ring. The two-dimensional analysis proves to be capable of representing the main features of the dynamic response of the three-dimensional tank-ring-soil system.     

Light utilization efficiency of phytoplankton in the Western Subarctic Gyre of the North Pacific during summer

We investigated the water-column light utilization efficiency (Ψ) of phytoplankton photosynthesis in the Western Subarctic Gyre (WSG) of the North Pacific during summer 2008. The Ψ values (0.64–1.86 g C [g Chl a]^?1 [mol photon]^?1 m²) obtained were observed to increase significantly with decreasing daily photosynthetic available radiation (PAR) and were generally higher than those of previous studies, not only from the subarctic Pacific but also from the world’s oceans. To examine the effect of iron availability on Ψ in the WSG, Ψ values were estimated from the data of two in situ iron fertilization experiments: the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study I (SEEDS-I) and II (SEEDS-II). We found that iron availability did not affect Ψ values. Overall, this study revealed that Ψ values changed remarkably in the WSG during the summer, and that higher values were found at the stations where moderate PAR levels (ca. 10–30 mol photons m^?2 day^?1) were observed and where autotrophic flagellates predominated in the phytoplankton assemblages.     

Basin-scale distribution of prokaryotic phylotypes in the epipelagic layer of the Central South Pacific Ocean during austral summer

In the present study, we used catalyzed reporter deposition-fluorescence in situ hybridization to quantify the abundance of five bacterial (Alphaproteobacteria, SAR11, Gammaproteobacteria, SAR86, and Bacteroidetes) and two archaeal (Crenarchaeota and Euryarchaeota) phylotypes in the epipelagic layer (0–200 m) of the Central South Pacific Ocean along 170°W from 0° to 40°S. We found that the distribution patterns of these phylotypes differed from each other. All phylotypes except Gammaproteobacteria were particularly abundant at the surface water of the equatorial region, whereas Gammaproteobacteria was relatively abundant in the area from the southern part of the South Pacific Ocean. SAR11, affiliated with Alphaproteobacteria was the dominant phylotype at all depths, throughout the study area. The abundance of SAR11 significantly increased with chlorophyll a concentration, suggesting that phytoplankton could affect their distribution pattern. There was a positive correlation between Bacteroidetes abundance and water temperature, suggesting that the temperature gradient could be a critical factor determining their distribution in the South Pacific Ocean. Crenarchaeota and Euryarchaeota were more abundant at the equatorial region than in other study areas. Euryarchaeota abundance significantly decreased with depth, and increased with chlorophyll a concentration. This suggests that there was ecological interaction between Euryarchaeota and phytoplankton in the equatorial surface. Our data indicate that distinct hydrographic properties such as seawater temperature, salinity, and the concentrations of chlorophyll a and nutrients can principally control the basin-scale distribution of different prokaryotic phylotypes in the epipelagic layer of the Central South Pacific Ocean.     

The 17-month periodicity of sunspot activity

A statistical study of sunspot activity during 1969 to 1986 was carried out by using the number of sunspot groups and their areas. We found a 17-month periodicity, which is consistent with the 500-day periodicity of flare occurrence (Ichimoto et al., 1985).Contributions from the Kwasan and Hida Observatories, University of Kyoto, No. 281.