Visual pollution in a national park

National Parks in Britain are not in areas of wilderness, but inhabited and farmed land. This makes management of the Parks difficult and insufficient moral and financial support from local authorities has led to their progressive deterioration. They are designed for the enjoyment of the public, but can they survive ‘people pollution’?     

Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy

A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A²Π_3/2 ← X²Π_3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N₂O/CF₃I/N₂ mixtures with O₃ actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.     

Experimental duplication of a high-pressure megacryst/cumulate assemblage in a near-saturated hawaiite

The occurrence of corroded megacrysts and cumulates of olivine, clinopyroxene, orthopyroxene, plagioclase, ilmenite and apatite in near-saturated hawaiites from the mid-north coast of New South Wales point to the derivation of these hawaiites at elevated pressures. In an experimental study on one of these hawaiites under conditions ranging from 5–15 kb and 0–5% H₂O, orthopyroxene was identified in only one run with 2% H₂O at 1040° C and 6.5 kb. In this run it was associated with olivine, clinopyroxene and Fe-Ti oxide. The early appearance of plagioclase in the “dry” experimental runs and amphibole in runs with 5% H₂O, indicates that the water content in the natural hawaiite was intermediate to these values. The near-duplication of the natural megacryst-cumulate assemblage suggests that the hawaiite host precipitated these phases at a depth of approximately 20–24 km, prior to rapid eruption to higher crustal levels.     

Small oil spill kills 10–20 000 seabirds in North Norway

An estimated 10–20 000 seabirds were killed by a very small oil spill off the coast of North Norway in March 1979. Despite the fact that over 90% of these were Brunnich's Guillemots Uria lomvia, the breeding population of this species was not considered to have been seriously threatened by this spill. On the other hand, this episode did illustrate how extremely vulnerable certain seabird species are to oil.     

Ophiolitic breccias associated with allochthonous oceanic crustal rocks in the East Ligurian Apennines,Italy — a comparison with observations from rifted oceanic ridges

In the East Ligurian segment of the North Apennines, eugeosynclinal sequences which contain ophiolitic rocks have been tectonically emplaced onto approximately coeval miogeosynclinal sediments. These allochthonous sequences represent the floor of a Mesozoic ocean which closed during the early Tertiary. The ophiolitic rocks consist of serpentinite, gabbro, pillowed and massive basalts, and breccias derived from these lithologies. They are overlain with depositional contacts by Upper Jurassic-Cretaceous pelagic cherts, limestones, and a shale/limestone sequence.The ophiolitic breccias attain thicknesses up to 100 m and strike lengths up to a few kilometres, and consist largely of unorganized accumulations of sand- to block-sized clasts. Compositions at specific horizons may range from oligomict breccias containing gabbro, basalt, or serpentinite fragments, to polymict breccias consisting of any mixture of these lithologies. Most of the breccias probably represent slow talus accumulations at the base of major submarine fault scarps which have exposed gabbro and serpentinite to submarine erosion. Direct exposure of gabbro and serpentinite on the ocean floor is also indicated by the occurrence of stratigraphically intact contacts between these lithologies and overlying pelagic sediments (generally cherts). The distribution and thickness of the breccias and volcanics, and the distribution of the gabbro and serpentinite, can vary greatly within distances of a few kilometres, thus producing complex heterogeneous sequences consisting of laterally impersistent lithological units.Recent observations and deep drilling of the Mid-Atlantic Ridge and other rifted ridges have revealed occurrences of significant thicknesses of basaltic, serpentinitic, and gabbroic breccias upon and within the volcanic layer of the oceanic crust, as well as the direct submarine exposure of plutonic rocks. It is therefore likely that the East Ligurian sequences represent parts of rifted ridge-generated crust. If so, then the complexity of the East Ligurian sequences suggests that the upper part of rifted ridge-generated crust may in places possess large variations in its stratigraphy over small (<10 km²) areas.Smooth, non-rifted (fast-spreading) ridges, which have very reduced topography and lack major fault scarps, should form ophiolitic complexes deficient in breccias containing fragments of plutonic igneous rocks. Most large ophiolitic complexes do not contain plutonic rock-bearing breccias, and were therefore probably formed at smooth ridges. The apparently preferential preservation of this type of ophiolitic complex, as opposed to the rifted ridge-type crust in East Liguria, may be related to the less pervasive and less intense fracturing of smooth ridges. This resulted in greater “cohesion” and lateral continuity of smooth ridge-generated crust during later tectonic emplacement into allochthonous positions in orogenic belts.     

Cordierite breakdown under high-pressure,hydrous conditions

Clear evidence exists for a cordierite breakdown reaction to amphibole-kyanite-quartz in high-grade metamorphic rocks of the Arunta Complex, Australia. Using the natural minerals this reaction has been duplicated experimentally. It proceeds over a divariant band with a slope of 12±4 bars/°C, occurring between 8 and 10.4 kb at 750° C and between 9.5 and 11.3 kb at 850°C. The reaction is cut off at low temperature by the appearance of talc and at high temperature by the appearance of orthopyroxene. The maximum pressure stability of the amphibole-kyanite-quartz assemblage is about 20 kb. These data suggest that the natural rock was subjected to pressures of at least 8 kb at 750–850° C for high water fugacities. Other experimental data on the hydration of hypersthene and cordierite-hypersthene stability, point to a temperature below 820° C and an upper pressure limit of 9.5 kb at 750–820°C. Experiments at \(P_{{\text{H}}_{\text{2}} {\text{O}}}\) total indicate that the breakdown of cordierite to amphibole-kyanite-quartz is a hydration reaction, and occurred in the natural rock as a result of an increase of water fugacity at constant total pressure (8–9.5 kb) and temperature (750–820°C).     

Bayesian modelling of the cool core galaxy group NGC 4325

We present an X-ray analysis of the radio-quiet cool-core galaxy group NGC 4325  ( z = 0.026)  based on Chandra and ROSAT observations. The Chandra data were analysed using xspec deprojection, 2D spectral mapping and forward-fitting with parametric models. Additionally, a Markov Chain Monte Carlo method was used to perform a joint Bayesian analysis of the Chandra and ROSAT data. The results of the various analysis methods are compared, particularly those obtained by forward-fitting and deprojection. The spectral mapping reveals the presence of cool gas displaced up to 10 kpc from the group centre. The Chandra X-ray surface brightness shows the group core to be highly disturbed, and indicates the presence of two small X-ray cavities within 15 kpc of the group core. The xspec deprojection analysis shows that the group has a particularly steep entropy profile, suggesting that an active galactic nucleus (AGN) outburst may be about to occur. With the evidence of prior AGN activity, but with no radio emission currently observed, we suggest that the group in a pre-outburst state, with the cavities and displaced gas providing evidence of a previous, weak AGN outburst.     

Hydrologic characteristics of lake‐ and stream‐side riparian wetted margins in the McMurdo Dry Valleys,Antarctica

Water is a limiting factor for life in the McMurdo Dry Valleys (MDV), Antarctica. The active layer (seasonally thawed soil overlying permafrost) accommodates dynamic hydrological and biological processes for 10–16 weeks per year. Wetted margins (visually wetted areas with high moisture content) adjacent to lakes and streams are potential locations of great importance in the MDV because of the regular presence of liquid water, compared with the rest of the landscape where liquid water is rare. At 11 plots (four adjacent to lakes, seven adjacent to streams), soil particle size distribution, soil electrical conductivity, soil water content and isotopic signature, width of the wetted margin, and active layer thaw depth were characterised to determine how these gradients influence physicochemical properties that determine microbial habitat and biogeochemical cycling. Sediments were generally coarse‐grained in wetted margins adjacent to both lakes and streams. Wetted margins ranged from 1·04 to 11·01 m in average length and were found to be longer at lakeside sites than streamside. Average thaw depths ranged from 0·12 to 0·85 m, and were found to be deepest under lake margins. Lake margins also had much higher soil electrical conductivity, steeper topographic gradients, but more gradual soil moisture gradients than stream margins. Patterns of soil water δ¹⁸O and δD distribution indicate capillary action and evaporation from wetted margins; margin pore waters generally demonstrated isotopic enrichment with distance from the shore, indicating evaporation of soil water. Lake margin pore waters were significantly more negative in D_XS (D_XS = δD‐8δ¹⁸O) than streamside pore waters, indicating a longer history of evaporation there. Differences between lake and stream margins can be explained by the more consistent availability of water to lake margins than stream margins. Differences in margin characteristics between lakes and streams have important consequences for the microbial habitat of these margins and their functional role in biogeochemical cycling at these terrestrial–aquatic interfaces. Copyright © 2009 John Wiley & Sons, Ltd.