Observations of H2S toward OMC-1

Interstellar hydrogen sulfide (H2S) and its isotopic variant (H2(34)S) have been observed toward several positions in OMC-1 via their 1(10)-1(01) transitions near 168 GHz using the FCRAO 14 m telescope. We derive total column densities toward Orion(KL) for the extended ridge, for the plateau, and for the hot core, in addition to values for other positions in OMC-1. The fractional abundance of H2S (approximately 10(-9)) in the quiescent regions of OMC-1 seems to be difficult to explain by currently known ion-molecule reactions. The fractional abundance of H2S relative to H2 is enhanced by a factor of 1000 in the hot core and the plateau relative to the quiescent clouds. This enhancement may be a result of grain surface chemistry and/or of high-temperature gas-phase chemistry. From the nondetection of HDS in its 2(11)-2(12) transition, we estimate the abundance ratio [HDS]/H2S] < or = 0.02 in the hot core.     

Origin of the Permian-Triassic komatiites,northwestern Vietnam

Abstract Rare examples of Phanerozoic komatiites are found in the Song Da zone, NW Vietnam. These komatiites were erupted through continental crust and may belong to the SE extension of the Permo-Triassic Emeishan volcanic province located in SW China. They provide a good opportunity to study the source characteristics of starting plume magmas in a continental flood basalt province. Erupted on late-Permian carbonate rocks, the komatiitic rocks are interbedded with low-Ti olivine basalts. Basaltic komatiites display pyroxene spinifex textures, while more magnesian rocks (MgO up to 32 wt.%) are porphyritic, containing a single, cognate population of euhedral to elongated olivine phenocrysts with Fo up to 93.0%. This suggests a highly magnesian parental magma with 22–23 wt.% MgO. In terms of major and minor elements, the komatiites are similar to the ca. 89 Ma old Gorgona Island komatiites of Colombia. The Song Da komatiites are also strongly light-rare-earth-element- (LREE) depleted (Ce_N/Yb_N 0.30–0.62) and have unfractionated heavy rare earth element (HREE) patterns. The komatiites have high Os concentrations (up to 7.0 ppb), low but variable Re/Os ratios, and define an isochron with an age of 270±21 Ma, and an initial ¹⁸⁸Os/¹⁸⁷Os ratio of 0.12506± 0.00041 (_Os=+0.02±0.40). The Os isotopic systematics of the komatiites show no effects of crustal contamination. In contrast, their initial _Nd values range from +3 to +8, reflecting varying but generally small degrees of contamination with Proterozoic sialic basement material. Associated low-Ti basalts have low initial _Nd values (–0.8 to –7.5), high initial _Os values (15), flat or LREE-enriched REE patterns, and Nb-Ta depletion. These characteristics are also attributed to variable extents of crustal contamination.Editorial responsibility: T.L. Grove     

Predicting Blast-induced Ground Vibration in Quarries Using Adaptive Fuzzy Inference Neural Network and Moth–Flame Optimization

Natural Resources Research - Blasting is a first preparatory stage that plays a fundamental role in the subsequent operations of an open pit mine. However, its adverse effects can seriously affect...     

Observations of some oxygen-containing and sulfur-containing organic molecules in cold dark clouds

Observations of nine oxygen- and sulfur-containing organic molecules have been made toward the cold dark clouds TMC-1 and L134N. We have confirmed the presence of para-ketene (H2C2O) in TMC-1, have for the first time observed ortho-ketene, and find a total ketene column density approximately 1 x 10(13) cm-2. Thioformaldehyde (H2CS) is easily detectable in both TMC-1 and L134N, with a column density about 5 times larger in the former source (approximately 3 x 10(13) cm-2). The fractional abundance of ketene is comparable to the predictions of ion-molecule chemistry, while that of thioformaldehyde in TMC-1 is one to two orders of magnitude greater than that expected from such models at steady state. Interstellar sulfur chemistry thus continues to be poorly understood. We set upper limits for the column densities of formic acid (HCOOH), vinyl alcohol (CH2CHOH), methyl formate (HCO2CH3), formamide (NH2CHO), methyl mercaptan (CH3SH), isothiocyanic acid (HNCS), and thioketene (H2C2S) in both sources.     

Simulation of mixed-mode fracture using SPH particles with an embedded fracture process zone

This paper focuses on the modelling of mixed-mode fracture using the conventional smoothed particle hydrodynamics (SPH) method and a mixed-mode cohesive fracture law embedded in the particles. The combination of conventional SPH and a mixed-mode cohesive model allows capturing fracture and separation under various loading conditions efficiently. The key advantage of this framework is its capability to represent complex fracture geometries by a set of cracked SPH particles, each of which can possess its own mixed-mode cohesive fracture with arbitrary orientations. Therefore, this can naturally capture complex fracture patterns without any predefined fracture topologies. Because a characteristic length scale related to the size of the fracture process zone is incorporated in the constitutive formulation, the proposed approach is independent from the spatial discretisation of the computational domain (or mesh independent). Furthermore, the anisotropic fracture responses of materials can be naturally captured thanks to the orientation of the fracture process zone embedded at the particle level. The performance of the proposed approach demonstrates its potentials in modelling mixed-mode fracture of rocks and similar quasi-brittle materials.     

Modelling of steady‐state fluid flow in 3D fractured isotropic porous media: application to effective permeability calculation

In this paper, 3D steady‐state fluid flow in a porous medium with a large number of intersecting fractures is derived numerically by using collocation method. Fluid flow in the matrix and fractures is described by Darcy's law and Poiseuille's law, respectively. The recent theoretical development presented a general potential solution to model the steady‐state flow in fractured porous media under a far‐field condition. This solution is a hypersingular integral equation with pressure field in the fracture surfaces as the main unknown. The numerical procedure can resolve the problem for any form of fractures and also takes into account the interactions and the intersection between fractures. Once the pressure field and then the flux field in fractures have been determined, the pressure field in the porous matrix is computed completely. The basic problem of a single fracture is investigated, and a semi‐analytical solution is presented. Using the solution obtained for a single fracture, Mori‐Tanaka and self‐consistent schemes are employed for upscaling the effective permeability of 3D fractured porous media. Copyright © 2012 John Wiley & Sons, Ltd.     

Lumped surface and sub‐surface runoff for erosion modeling within a small hilly watershed in northern Vietnam

Developing models to predict on‐site soil erosion and off‐site sediment transport at the agricultural watershed scale represent an on‐going challenge in research today. This study attempts to simulate the daily discharge and sediment loss using a distributed model that combines surface and sub‐surface runoffs in a small hilly watershed (< 1 km²). The semi‐quantitative model, Predict and Localize Erosion and Runoff (PLER), integrates the Manning–Strickler equation to simulate runoff and the Griffith University Erosion System Template equation to simulate soil detachment, sediment storage and soil loss based on a map resolution of 30 m × 30 m and over a daily time interval. By using a basic input data set and only two calibration coefficients based, respectively, on water velocity and soil detachment, the PLER model is easily applicable to different agricultural scenarios. The results indicate appropriate model performance and a high correlation between measured and predicted data with both Nash–Sutcliffe efficiency (Ef) and correlation coefficient (r²) having values > 0.9. With the simple input data needs, PLER model is a useful tool for daily runoff and soil erosion modeling in small hilly watersheds in humid tropical areas. Copyright © 2013 John Wiley & Sons, Ltd.     

Theoretical and numerical study of the steady‐state flow through finite fractured porous media

This paper investigates the two‐dimensional flow problem through an anisotropic porous medium containing several intersecting curved fractures. First, the governing equations of steady‐state fluid flow in a fractured porous body are summarized. The flow follows Darcy's law in matrix and Poiseuille's law in fractures. An infinite transversal permeability is considered for the fractures. A multi‐region boundary element method is used to derive a general pressure solution as a function of discharge through the fractures and the pressure and the normal flux on the domain boundary. The obtained solution fully accounts for the interaction and the intersection between fractures. A numerical procedure based on collocation method is presented to compute the unknowns on the boundaries and on the fractures. The numerical solution is validated by comparing with finite element solution or the results obtained for an infinite matrix. Pressure fields in the matrix are illustrated for domains containing several interconnected fractures, and mass balance at the intersection points is also checked. Copyright © 2013 John Wiley & Sons, Ltd.     

The Sin Quyen Cu–Fe–Au–REE deposit (northern Vietnam): composition and formation conditions

The Sin Quyen Cu–Fe–Au–REE deposit is localized in the Proterozoic deposits of the Phan Xi Pang zone, northern Vietnam. The mineralization is formed by lenticular and sheet-like bodies occurring concordantly with the host rocks. Seventeen orebodies have been recognized in the deposit, which form an ore horizon up to 140 m in total thickness, about 2 km in strike, and up to 350 m in dip. The ores are of simple mineral composition: Au-rich copper and iron sulfides (chalcopyrite, pyrite, pyrrhotite) and iron oxides (magnetite, hematite). Gold and silver are distributed unevenly in the ores: Their contents vary from hundredths and tenths of ppm to 1.8 ppm. Copper sulfide ores are the main concentrator of gold and silver. All ores are characterized by high REE contents, tens and hundreds of times exceeding the element clarkes. The highest contents have been revealed for Ce and La. Orthite is the main carrier of REE. No correlation between REE and ore elements of sulfide-oxide ores has been revealed, which points to the independent formation of the mineralization. Orebodies together with the host rocks underwent metamorphism at 500–600 to 630–685 °C and 3–7 kbar. The spatial association of the mineralization with amphibolites (metamorphosed basites) and the mineral composition of ores suggest that the Sin Quyen deposit is of Cyprian volcanogenic type.