Simulation of risk-consistent earthquake motion

A method to combine probabilistic seismic hazard analysis and stochastic earthquake motion models is presented. A set of parameters characterizing stochastic earthquake motion models is determined on a consistent probabilistic basis. The method proposed herein consists of two steps. First, the ground motion intensity is determined in the context of the conventional hazard curve technique. Next, other ground motion parameters such as duration, predominant frequency and spectral shape parameters are determined as conditional means corresponding to the annual probability of exceedance for the ground motion intensity. Some example applications are presented.     

Ventilation of the North Pacific subtropical pycnocline and mode water formation

The annual subduction rate of the North Pacific was calculated based on isopycnally averaged hydrographic climatology (HydroBase), high-resolution winter mixed-layer climatology (NWMLC), and various wind stress climatologies from ship reports, numerical weather prediction products, and satellite products. The calculation was performed using Lagrangian coordinates in the same manner as in previous works, except a less smoothed oceanic climatology (HydroBase and NWMLC) was used instead of a World Ocean Atlas. Differences in the wind stress climatologies have very little effect on subduction rate estimates. The subduction rate census for density classes showed peaks corresponding to subtropical mode water (STMW), central mode water (CMW), and eastern subtropical mode water (ESTMW). The deeper mixed layer and the associated sharper mixed-layer fronts in the present climatology resulted in a larger lateral induction, which boosted the subduction rate, especially for the potential density anomaly (σ_θ) range of the lighter STMW (25.0 < σ_θ < 25.2 kg m⁻³) and lighter CMW (26.0 < σ_θ < 26.2 kg m⁻³), compared to previous estimates. The renewal time of permanent pycnocline water was estimated as the volume of water divided by the subduction rate for each σ_θ class: 2–4 years for ESTMW (24.5 < σ_θ < 25.2 kg m⁻³), 2 years for the lighter STMW (25.0 < σ_θ < 25.3 kg m⁻³), 5–9 years for the denser STMW (25.3 < σ_θ < 25.6 kg m⁻³), 10–20 years for the lighter CMW (26.0 < σ_θ < 26.2 kg m⁻³), 20–30 years for the middle CMW (26.2 < σ_θ < 26.3 kg m⁻³), and 60 years or longer for the denser CMW (26.3 < σ_θ < 26.6 kg m⁻³). A comparison of the water volume and subduction rate in potential temperature–salinity (θ–S) space indicated that the upper permanent pycnocline water (25.0 < σ_θ < 26.2 kg m⁻³) was directly maintained by nondiffusive subduction of winter surface water, including STMW and lighter CMW. The lower permanent pycnocline water (26.2 < σ_θ < 26.6 kg m⁻³) may be maintained through the subduction of fresher and colder water from the subarctic–subtropical transition region and subsequent mixing with saltier and warmer water. Diagnosis of the potential vorticity (PV) of the subducted water demonstrated that the low PV of STMW was mainly due to the large subduction rate, whereas that of both ESTMW and CMW was due mainly to the small density advection rate (cross-isopycnal flow). Additionally, a relatively large subduction rate probably contributes to the low PV of part of the lighter CMW (ESTMW) formed in the region around 38°N and 170°W (28°N and 145°W), which is characterized by a relatively thick winter mixed layer and an associated mixed-layer front, causing a large lateral induction rate.     

Coexistence of a Fluid Phase with Granitic Magma: Geochemical Characteristics of REE and Cu in Miyako Granite and in Scheelite-bearing Aplitic Veins at the Yamaguchi Cu-W Skarn Deposit, Iwate, Japan

Abstract: The North granitic body of the Miyako pluton is located in the Northern Kitakami belt, Northeast Japan. The formation of the scheelite–chalcopyrite–magnetite–bearing aplitic veins and scheelite–chalcopyrite–magnetite–bearing Yamaguchi skarn deposit was closely associated with the formation of the Miyako plutons. Petrographic facies of the North granitic body vary from quartz diorite in marginal zone (zone A), to tonalite and granodiorite (zone B), and to granite (zone C) in the central. The large numbers of aplitic veins distributed around the Yamaguchi mining area are divided into two groups: barren and scheelite–mag–netite–chalcopyrite–bearing aplitic veins. The latter cut massive clinopyroxene skarns of the Yamaguchi deposit, and are composed of plagioclase, K‐feldspar and titanite. Some plagioclase crystals have dusty cores with irregularly shaped K‐feldspar flakes, and clear rims of albite. Textures of plagioclase in the mineralized aplitic veins are different from the idiomorphic textures with sharp plagioclase crystal boundaries that occur in the North granitic body and barren aplitic veins. These textural data suggest that the mineralized aplitic veins were formed from hydrothermal fluid. Changes in the contents of major and minor (Rb, Sr, Sc, Co, Th, U) elements in the North Miyako granitic body are similar to those of zoned plutons formed by typical magmatic differentiation processes. On the other hand, concentrations of REE, especially middle to heavy REE, of granitic rocks in zone C and barren aplitic veins are significantly lower than those of granitic rocks in zones A and B. The hypothetical chondrite‐normalized REE patterns, calculated assuming fractional crystallization from zone B granitic melt, suggest that REE concentrations of the residual melt increased with the degree of fractional crystallization, and changed into a pattern with enriched LREE and strongly negative Eu anomaly. However, the REE patterns of granitic rocks in zone C are different from the hypothetical patterns. Moreover, the REE patterns of magnetite–scheelite–chalcopyrite aplitic veins are quite different from those of granitic rocks. The Cu contents of granitic rocks in the North Miyako body increase from zone A (5–26 ppm) to zone B (10–26 ppm), and then clearly decrease to zone C (5–7 ppm) and drastically increase to the barren aplitic veins (39–235 ppm). Concentrations of Cu in the mineralized aplitic veins are also higher than those of the granitic rocks in zone C. The decrease in REE and Cu contents of granitic rocks from zone B to zone C is not a result of simple magmatic fractional differentiation. Fluid inclusions in quartz from mineralized aplitic veins contain 3.3 wt% NaCl equivalent and 5.8 wt% CO₂. It was also demonstrated experimentally that the removal of MREE and HREE by fluid from melt enabled the formation of complexes of REE and ligands of OH^‐ and CO₃^2‐. Based on the possibility that the melt of the granitic rocks of zone C and the mineralized aplitic veins coexisted with CO₂‐bearing fluid, it is thought that REE were extracted from the melt to the CO₂‐bearing fluid, and that the REE in the mineralized aplitic veins were transported by the CO₂‐bearing fluid. It is likely that the low HREE and Cu contents of the granitic rocks in zone C could have been caused by the removal of those elements from the granitic melt by the fluid coexisting with the melt. The expelled materials could have been the sources of scheelite–magnetite–chalcopyrite–bearing aplitic veins and copper mineralization of the Yamaguchi Cu‐W skarn deposit.     

Roles of mode waters in the formation and maintenance of central water in the North Pacific

This study describes the three-dimensional distributions of the Turner angle (Tu) and the potential vorticity (PV) of the main pycnocline water in the subtropical North Pacific (10–50°N, 120°E–120°W) using a large in situ CTD data set taken by the Argo profiling floats during June to October of 2001–2009 to clarify the detailed distribution of the central water and the mode waters as well as the relationship between these water masses. The ventilated part of the main pycnocline water (σ _θ < 26.7 kg m⁻³) in the subtropical gyre generally displays a sharp peak in Tu value of 59° in the histogram. The Tu histograms for 10° × 10° geographical boxes mostly show that the mode for the Tu value is 59° too, but they also show some regional differences, suggesting some types of relations with the North Pacific mode waters. To further investigate this relationship, the appearance probability density function of the central water (defined as the main pycnocline water with Tu = 56°–63°) and those of the mode waters with PVs lower than the critical value on each isopycnal surface were analyzed. The distribution area of the central mode water (CMW) corresponds so well with that of the central water that a direct contribution of the CMW to the formation and maintenance of the central water is suggested. On the other hand, the distribution areas of subtropical mode water (STMW), Eastern STMW, and transition region mode water do not correspond to that of the central water. Nevertheless, indirect contributions of these mode waters to the formation and maintenance of the central water through salt finger type convection or diapycnal mixing are suggested.     

Hydrothermal Alteration of Oman Ophiolite Extrusives in Ghuzayn Area

Abstract. The hydrothermal alteration in Ghuzayn Volcanics was associated with mineralization and accumulation of three massive sulfide deposits. The Ghuzayn Volcanics were discriminated into basaltic and andesitic lavas. The crossplots of Zr versus Nb, Y, Hf, La and Lu show that they fall in the same linear fractionation trends with more evolved affinities in the andesitic lavas compared to the less evolved affinities in the basaltic lavas. The immobile trace element contents of the Ghuzayn Volcanics show that they are of oceanic to continental tholeiitic affinity which fall in the fields of back‐arc basin basalt, N‐MORB and island arc tholeiite all meet and match with the field of the Lau‐Tonga back‐arc basin lavas. The ore‐body No. 2 is underlain by a zone of intense argillization and silicification which are so‐called alteration pipe as in some of the Cyprus‐type massive sulfide deposits. The alteration in the proximity of the ore‐body No. 2 is characterized by a zone of epidotization and slight silicification and sulfide disseminations, and surrounded by another zone of slight silicification and sulfide dissemination in the outermost rim around the ore‐body No. 2. The alteration zones in the proximity of the ore‐body No. 2 were divided into Zones I and II based on the abundance of the secondary minerals in the altered basaltic lavas. The Zone I is located in the most northern upper part of the ore‐body No. 2 and characterized by corrensite, saponite and prehnite. However, the Zone II is located in the southern part of the ore‐body No. 2 and characterized by chlorite and epidote. Both alteration zones were formed by different alteration stages. Stage 1 was formed by non to partly reacted fluids, to crystallize Mg‐chlorite and albite at temperatures ranging from 150 to 250d?C. Further, these fluids evolved with time and became Mg‐depleted, Si‐ and metal‐enriched to crystallize Fe²⁺‐chlorite, epidote, quartz and sulfides at temperatures ranging from 250 to 350d?C in stage 2. Later, these fluids were evolved again to be Mg‐ and Ca‐enriched in stage 3 to crystallize prehnite, laumontite, corrensite and saponite at temperatures ranging from 150 to 220d?C. Late zeolite and calcite have overgrown the previously crystallized phases and crosscutting veins along the altered basaltic lavas in stage 4. Finally, the lavas were cracked and refractured to facilitate penetration of seawater into deeper parts to heat up again and re‐leach the silica and metals in a new mineralizing event.     

Removal of lead from cathode ray tube funnel glass by chloride volatilization

Cathode ray tube funnel glass is an environmentally problematic relict of old television sets. In particular, landfilling of this material is strongly discouraged because of its high lead content. However, recovery of this toxic lead could prevent its release into the environment and allow its reuse. In this research, lead was separated from the glass matrix by a chloride volatilization process. Melting of the funnel glass together with CaCl₂ resulted in the volatilization of 80 % of lead at 1,000 °C. The use of NaCl as a chlorination agent yielded less volatile lead, while poly(vinyl chloride) and gaseous HCl proved to be ineffective chlorination agents. The differences in the chlorination agent efficiencies could be attributed to differences in the corresponding formation of silicates. Energy-dispersive X-ray spectroscopy showed that diffusion plays an important role in the volatilization of PbCl₂.     

Q-bursts from various distances on the Earth

The mechanism of the Q-burst is investigated in the time and frequency domains. Electric fields in the ELF (extremely low frequency) to VLF (very low frequency) range have been observed with a ball antenna since 2003 in Kochi City, Japan (latitude 33.3°north, longitude 133.4°east). Source-to-observer distances (SODs) of Q-bursts are estimated by analyzing the waveforms. It is found as a result that the Q-burst is produced by combination of direct and antipodal pulses from a source lightning stroke occurring all over the world.     

Long-term variations of surface and intermediate waters in the southern Indian Ocean along 32°S

Variations of water properties in surface and intermediate layers along 32°S in the southern Indian Ocean were examined using a 50-year (1960–2010) time series reproduced from historical hydrographic and Argo data by using optimum interpolation. Salinity in the 26.7–27.3σ_θ density layer decreased significantly over the whole section, at a maximum rate of 0.02 decade⁻¹ at 26.8–26.9σ_θ, for the 50-year average. Three deoxygenating cores were identified east of 75°E, and the increasing rate of apparent oxygen utilization in the most prominent core (26.9–27.0σ_θ) exceeded 0.05 ml l⁻¹ decade⁻¹. The pycnostad core of Subantarctic Mode Water (SAMW) and the salinity minimum of Antarctic Intermediate Water shifted slightly toward the lighter layers. Comparisons with trans-Indian Ocean survey data from 1936 suggest that the tendencies found in the time series began before 1960. Interestingly, cores of many prominent trends were located just offshore of Australia at 26.7–27.0σ_θ, which is in the SAMW density range. Spectrum analysis revealed that two oscillation components with time scales of about 40 and 10 years were dominant in the subsurface layers. Our results are fairly consistent with, and thus support, the oceanic responses in the southern Indian Ocean to anthropogenic climate change predicted by model studies.     

New type of pycnostad in the western subtropical-subarctic transition region of the North Pacific: Transition Region Mode Water

A new type of pycnostad has been identified in the western subtropical-subarctic transition region of the North Pacific, based on the intensive hydrographic survey carried out in July, 2002. The potential density, temperature and salinity of the pycnostad were found to be 26.5–26.7 σ _θ , 5°–7°C and 33.5–33.9 psu respectively. The pycnostad is denser, colder and fresher than those of the North Pacific Central Mode Water and different from those of other known mode waters in the North Pacific. The thickness of the pycnostad is comparable to that of other mode waters, spreading over an area of at least 650 × 500 km around 43°N and 160°E in the western transition region. Hence, we refer to the pycnostad as Transition Region Mode Water (TRMW). Oxygen data, geostrophic current speed and climatology of mixed layer depth in the winter suggest that the TRMW is formed regularly in the deep winter mixed layer near the region where it was observed. Analysis of surface heat flux also supports the idea and suggests that there is significant interannual variability in the property of the TRMW. The TRMW is consistently distributed between the Subarctic Boundary and the Subarctic Front. It is also characterized by a wide T-S range with similar density, which is the characteristic of such a transition region between subtropical and subarctic water masses, which forms a density-compensating temperature and salinity front. The frontal nature also tends to cause isopycnal intrusions within the pycnostad of the TRMW.