Sedimentary indications and absolute chronology of Holocene relative sea‐level changes retrieved from coastal lagoon deposits on Samsø, Denmark

Coastal lagoons are a typical feature of the landscape in central Denmark. The lagoons formed when basins within the inherited glacial topography were flooded by the mid‐Holocene sea‐level rise. The transgression initiated coastal geomorphological processes and prompted marine sedimentation in the inundated areas. Despite their common occurrence and wide distribution in the area, coastal lagoons and their deposits have rarely been studied as sedimentary archives. The absolute chronology established for the basal marine deposits in sediment cores retrieved from coastal lagoons on the island of Samsø, southern Kattegat Sea, central Denmark, is evidence of a nearly synchronous onset of marine sedimentation at different elevations. This is interpreted as a new indication of a period of very rapid relative sea‐level (RSL) rise between 7.6 and 7.2 ka BP. Following a period of RSL highstand, a marked facies change in the deposits from an inactive lagoon yields consistent ages of around 4.1 ka BP and may be an indication of a marked RSL fall. This study illustrates the potential of coastal lagoons as sedimentary archives for the reconstruction of RSL in SW Scandinavia and in similar coastal environments elsewhere.     

Monsoonal forcing of Holocene paleoenvironmental change on the central Tibetan Plateau inferred using a sediment record from Lake Nam Co (Xizang,China)

This study focuses on Holocene monsoon dynamics on the central Tibetan Plateau (TP) inferred using a sediment record from Lake Nam Co. A high-resolution (decadal) multi-proxy approach, using geochemical, micropaleontological, and sedimentological methods was applied. Fifteen AMS-¹⁴C ages were used to establish the chronology, assuming a reservoir effect of 1,420 years. Our results point to a first strong monsoonal pulse at Lake Nam Co ~11.3 cal ka BP, followed by colder and drier conditions until ~10.8 cal ka BP. A warm and humid climate from ~10.8 to ~9.5 cal ka BP is related to a strong summer monsoon on the central TP, triggering a lake-level highstand at ~9.5 cal ka BP. Declining minerogenic input after ~9.5 cal ka BP indicates less moisture availability until ~7.7 cal ka BP. Following stable conditions between ~7.7 and ~6.6 cal ka BP, a warm and wet climate is inferred for the time span from ~6.6 to ~4.8 cal ka BP. A change towards drier conditions after ~4.8 cal ka BP points to a weakening of the Indian Ocean Summer Monsoon on the central TP, further diminished after ~2.0 cal ka BP. A short-term wet spell occurred from ~1.5 to ~1.3 cal ka BP. By comparing the results derived from Lake Nam Co with several lacustrine records from the central, northern, and eastern TP, a similar but not synchronous pattern of monsoon-driven paleoenvironmental change is observed. Although the general trend of lake and catchment evolution on the TP during the Holocene is also reproduced in this record, pronounced spatial and temporal offsets with respect to distinct climate events were detected, suggesting periods of non-uniform moisture and temperature evolution.     

Rapid directivity detection by azimuthal amplitude spectra inversion

An early detection of the presence of rupture directivity plays a major role in the correct estimation of ground motions and risks associated to the earthquake occurrence. We present here a simple method for a fast detection of rupture directivity, which may be additionally used to discriminate fault and auxiliary planes and have first estimations of important kinematic source parameters, such as rupture length and rupture time. Our method is based on the inversion of amplitude spectra from P-wave seismograms to derive the apparent duration at each station and on the successive modelling of its azimuthal behaviour. Synthetic waveforms are built assuming a spatial point source approximation, and the finite apparent duration of the spatial point source is interpreted in terms of rupture directivity. Since synthetic seismograms for a point source are calculated very quickly, the presence of directivity may be detected within few seconds, once a focal mechanism has been derived. The method is here first tested using synthetic datasets, both for linear and planar sources, and then successfully applied to recent Mw 6.2–6.8 shallow earthquakes in Peloponnese, Greece. The method is suitable for automated application and may be used to improve kinematic waveform modelling approaches.     

Timescales and mechanisms of REE and Hf uptake in fossil bones

Rare earth element (REE) patterns of fossil bones and teeth are widely used as proxies for provenance, taphonomy, and palaeoenvironment. In order to investigate if fossil bones behave as closed systems over geologic time, REE profiles were analysed by LA-ICPMS along cross sections of 54 bones from various well-characterised and well-dated settings. These include terrestrial and marine diagenetic environments, covering Early Triassic to Holocene ages. In general, all fossil bones exhibit the highest REE concentrations at the outer rim, gradually decreasing by up to four orders of magnitude toward the inner bone cortex. Intra-bone REE concentration gradients decrease significantly from Quaternary via Tertiary to Mesozoic specimens, suggesting long term REE uptake and open system behaviour of fossil bone. This view is further corroborated by ¹⁷⁶Lu-¹⁷⁶Hf dating of selected samples, all yielding significantly younger ages than the known chronostratigraphic ages. Hence, there is clear evidence for long term open system behaviour of fossil bones with respect to REE, which is in marked contrast to currently accepted models suggesting that REE uptake is only early diagenetic. Although unexpected, statistically significant four to seven point isochrons are observed for four fossil dinosaur bone samples and one Upper Triassic Mastodonsaurus tooth with MSWDs ranging from 0.083 to 4.5. Notably, mobility of Lu alone cannot account for the observed age patterns. Assuming constant Lu uptake rates over time, the radiometric ages should only be as low as half of the chronostratigraphic age. However, a six-point isochron defined by subsamples of a single Upper Triassic Mastodonsaurus tooth yields an age of 65.2 ± 1.1 Ma (MSWD = 0.68), much younger than half of the stratigraphic age (ca. 234 Ma). Hence, Hf must also undergo late diagenetic exchange. Likely mechanisms to account for the presence of statistically meaningful isochrons as well as for the late diagenetic exchange of both REE and Hf are diffusion, adsorption, and dissolution-reprecipitation processes.     

Controls on ostracod valve geochemistry, Part 1: Variations of environmental parameters in ostracod (micro-)habitats

The variations of environmental conditions (T°, pH, δ¹³C_DIC, [DIC], δ¹⁸O, Mg/Ca, and Sr/Ca) of ostracod habitats were examined to determine the controls of environmental parameters on the chemical and isotopic composition of ostracod valves. Results of a one-year monitoring of environmental parameters at five sites, with depths of between 2 and 70 m, in Lake Geneva indicate that in littoral to sub-littoral zones (2, 5, and 13 m), the chemical composition of bottom water varies seasonally in concert with changes in temperature and photosynthetic activity. An increase of temperature and photosynthetic activity leads to an increase in δ¹³C values of DIC and to precipitation of authigenic calcite, which results in a concomitant increase of Mg/Ca and Sr/Ca ratios of water. In deeper sites (33 and 70 m), the composition of bottom water remains constant throughout the year and isotopic values and trace element contents are similar to those of deep water within the lake. The chemical composition of interstitial pore water also does not reflect seasonal variations but is controlled by calcite dissolution, aerobic respiration, anaerobic respiration with reduction of sulphate and/or nitrate, and methanogenesis that may occur in the sediment pores. Relative influence of each of these factors on the pore water geochemistry depends on sediment thickness and texture, oxygen content in bottom as well as pore water. Variations of chemical compositions of the ostracod valves of this study vary according to the specific ecology of the ostracod species analysed, that is its life-cycle and its (micro-)habitat. Littoral species have compositions that are related to the seasonal variations of temperature, δ¹³C values of DIC, and of Mg/Ca and Sr/Ca ratios of water. In contrast, the compositions of profundal species are largely controlled by variations of pore fluids along sediment depth profiles according to the specific depth preference of the species. The control on the geochemistry of sub-littoral species is a combination of controls for the littoral and profundal species as well as the specific ecology of the species.     

Assessing the redox properties of iron-bearing clay minerals using homogeneous electrocatalysis

Iron-bearing clay minerals are ubiquitous in the environment and have been shown to play important roles in several biogeochemical processes. Previous efforts to characterize the Fe²⁺–Fe³⁺ redox couple in clay minerals using electrochemical techniques have been limited by experimental difficulties due to inadequate reactivity between clay minerals and electrodes. The current work overcomes this limitation by utilizing organic electron transfer mediators that rapidly transfer electrons with both the Fe-bearing clay minerals and electrodes. Here, an Fe-rich source clay mineral (ferruginous smectite, SWa-1) is examined with respect to what fraction of structural Fe participates in oxidation/reduction reactions and the relationship between bulk Fe²⁺/Fe³⁺ ratios to the reduction potential (E_h).     

Geochemical Fingerprinting of Coltan Ores by Machine Learning on Uneven Datasets

Two modern machine learning techniques, Linear Programming Boosting (LPBoost) and Support Vector Machines (SVMs), are introduced and applied to a geochemical dataset of niobium–tantalum (“coltan”) ores from Central Africa to demonstrate how such information may be used to distinguish ore provenance, i.e., place of origin. The compositional data used include uni- and multivariate outliers and elemental distributions are not described by parametric frequency distribution functions. The “soft margin” techniques of LPBoost and SVMs can be applied to such data. Optimization of their learning parameters results in an average accuracy of up to c. 92%, if spot measurements are assessed to estimate the provenance of ore samples originating from two geographically defined source areas. A parameterized performance measure, together with common methods for its optimization, was evaluated to account for the presence of uneven datasets. Optimization of the classification function threshold improves the performance, as class importance is shifted towards one of those classes. For this dataset, the average performance of the SVMs is significantly better compared to that of LPBoost.     

Magnetic aggregation: II. Laboratory and microgravity experiments

In a previous publication (Dominik and Nübold, 2002, Icarus 157, 173-186), we presented analytical expressions and theoretical considerations concerning preplanetary dust aggregation with magnetized grains in the solar nebula. The present work is dedicated to the experimental study of magnetic aggregation in a ground-based laboratory as well as under microgravity conditions on parabolic flights. We conducted aggregation experiments with dust analogues in order to study the temporal evolution and the structural outcome of grain growth processes dominated by or comprising exclusively magnetic grains. Within aggregation times ranging from a couple of seconds to a few minutes only, formation of huge chain-like and/or web-like dust aggregates was observed. After aggregate retrieval we were able to study the sizes and structures of the aggregates in great detail. We established the fractal dimension of the aggregates as D_fs=1.20±0.05 for single chains and D_fc=1.50±0.21 for inter-connected web-like structures. This is considerably lower than for non-magnetic grain growth. The dynamic exponent z for the mass increase with time according to t^z was found to be z=2.7 from in-situ video images of the microgravity aggregation runs. The results are compared with the theoretical considerations presented earlier as well as with previous experimental work on the same and on related topics, respectively.     

Monotonic and cyclic tests on kaolin: a database for the development,calibration and verification of constitutive models for cohesive soils with focus to cyclic loading

A database with about 60 undrained monotonic and cyclic triaxial tests on kaolin is presented. In the monotonic tests, the influences of consolidation pressure, overconsolidation ratio, displacement rate and sample cutting direction have been studied. In the cyclic tests, the stress amplitude, the initial stress ratio and the control (stress vs. strain cycles) have been additionally varied. Isotropic consolidation leads to a failure due to large strain amplitudes with eight-shaped effective stress paths in the final phase of the cyclic tests, while a failure due to an excessive accumulation of axial strain and lens-shaped effective stress paths was observed in the case of anisotropic consolidation with \(q^{\text{ ampl }}< |q^{\text{ av }}|\). The rate of pore pressure accumulation grew with increasing amplitude and void ratio (i.e. decreasing consolidation pressure and overconsolidation ratio). The “cyclic flow rule” well known for sand has been confirmed also for kaolin: With increasing value of the average stress ratio \(|\eta ^{\text{ av }}| = |q^{\text{ av }}|/p^{\text{ av }}, \) the accumulation of deviatoric strain becomes predominant over the accumulation of pore water pressure. The tests on the samples cut out either horizontally or vertically revealed a significant effect of anisotropy. In the cyclic tests, the two kinds of samples exhibited an opposite inclination of the effective stress path. Furthermore, the horizontal samples showed a higher stiffness and could sustain a much larger number of cycles to failure. All data of the present study are available from the homepage of the first author. They may serve for the examination, calibration or improvement in constitutive models dedicated to cohesive soils under cyclic loading, or for the development of new models.     

The Blacktail Creek Tuff: an analytical and experimental study of rhyolites from the Heise volcanic field,Yellowstone hotspot system

The magma storage conditions of the 6.62 Ma Blacktail Creek Tuff eruption, belonging to the Heise volcanic field (6.62–4.45 Ma old) of the Yellowstone hotspot system, have been investigated by combining thermobarometric and experimental approaches. The results from different geothermometers (e.g., Fe–Ti oxides, feldspar pairs, apatite and zircon solubility, and Ti in quartz) indicate a pre-eruptive temperature in the range 825–875 °C. The temperature estimated using two-pyroxene pairs varies in a range of 810–950 °C, but the pyroxenes are probably not in equilibrium with each other, and the analytical results of melt inclusion in pyroxenes indicate a complex history for clinopyroxene, which hosts two compositionally different inclusion types. One natural Blacktail Creek Tuff rock sample has been used to determine experimentally the equilibrium phase assemblages in the pressure range 100–500 MPa and a water activity range 0.1–1.0. The experiments have been performed at fluid-present conditions, with a fluid phase composed of H₂O and CO₂, as well as at fluid-absent conditions. The stability of the quartzo-feldspathic phases is similar in both types of experiments, but the presence of mafic minerals such as biotite and clinopyroxene is strongly dependent on the experimental approach. Possible explanations are given for this discrepancy which may have strong impacts on the choice of appropriate experimental approaches for the determination of magma storage conditions. The comparison of the composition of natural phases and of experimentally synthesized phases confirms magma storage temperatures of 845–875 °C. Melt water contents of 1.5–2.5 wt% H₂O are required to reproduce the natural Blacktail Creek Tuff mineral assemblage at these temperatures. Using the Ti-in-quartz barometer and the Qz–Ab–Or proportions of natural matrix glasses, coexisting with quartz, plagioclase and sanidine, the depth of magma storage is estimated to be in a pressure range between 130 and 250 MPa.