Anthropogenic changes in the sediment composition of Lake Gości& aogon;ż (central Poland), during the last 330 yrs*

According to historical sources, the development of settlement around Lake Goci& aogon; during the last 330 yrs was intense at two time periods: the second half of the 1700's, and from ca. 1880 until 1944. The small farms were then abandoned, following which the lake surroundings were planted with forest trees. The presented study of human influence on the lake ecosystem and surrounding vegetation has been based on analyses of general sediment composition and its chemistry, pollen, Cyanobacteria, Chlorophyceae, Rotatoria, Cladocera, and a preliminary diatom survey. The history of human impact has been divided into four phases: 1. Phase of small local hamlets (before ca. 1770): The human impact was rather moderate then, but the cultivation of Canabis sativa, Secale cereale and later of Fagopyrum is evidenced from that time. 2. Phase of Hollandii settlement (ca. 1770-1863). Its influence is indicated first by the recession of deciduous wood (Corylus, Carpinus) stands, which triggered drastic drop of calcium in sediments. The development of rural economy in the area, including, an extension of agriculture (Secale and other cereals, crucifers, potatoes), and animal breeding based partly on grazing in the forest, is evidenced only after 1820. 3. Phase of German colonization (1863-1944): In the early periods (before 1910) the pollen spectra do not document any essential change in the type of farming, however, a serious disturbance of the lake ecosystem and sediment chemistry is evidenced by the blooms of Araphidinae diatoms and Tetraedron minimum, a maximum frequency of Bosmina longirostris, disturbances of the regular spring blooms of Chrysophyceae, appearance of vivianite, distinct maxima of organic matter, potassium, and iron concentration in sediments and an increase of the sedimentation rate. An intensification of agricultural activities commenced around 1910; woods, including also pinewoods, were then heavily devastated, and farming extended on poor soils, what was symptomatic for the general poverty of population. Coincidently in the lake, Centriceae showed blooms, Araphidinae diatoms and Tetraedron minimum developed, and the content of potassium, iron and phosphorus increased substantially, indicating altogether rising eutrophication. 4. Phase of restoration of the natural landscape (after 1945): The farm degradation from ca. 1944 is very weakly expressed in pollen data, which show a substantial fall of farming indicators from 1953/6 only, when the whole area was used for forest plantation. It was accompanied by a certainly spontaneous development of Betula and Alnus woods, this process progressing till recent time. The gradual extinction of farming activity near Lake Goci was accompanied by abrupt changes in the lake ecosystem, expressed by the restored blooms of Chrysophyceae expansion of planktonic Cladocera, rapid decline of phosphorus and extinction of vivianite from sediments. As documented by the drop of Cu/Zn ratio, lake hypolimnion has been weakly oxidized since 1949, what was probably responsible for the drop of Fe and Mn content in sediments. Increasing strength of overturns affected preservation of laminae in sediments, which almost completely disappeared after 1966.     

Biomarker patterns in a time-resolved holocene/terminal Pleistocene sedimentary sequence from the Guadiana river estuarine area (SW Portugal/Spain border)

The vertical distribution of terrestrial and phytoplankton biomarker compounds in a sediment core from the coastal estuarine zone of the Guadiana river (southwest border between Portugal and Spain) was determined by gas chromatography–mass spectrometry. Significant downcore fluctuations were observed in the patterns of the most abundant alkyl series (n-alkanes and n-fatty acids), as well as in several biomarker ratios. In addition, a specific contribution from conifers is reflected in the presence of a resin acid series that first appears 6500 years BP. The observed changes in the lipid assemblage within the Holocene suggest recent variations in the planktonic and terrigenous supply, which are attributed mainly to the evolution of the circulation pattern in the estuary and to the alteration of vegetation cover within the Guadiana drainage basin. Our data suggest that on a 10³–10⁴ year time-scale, little or no diagenetic change occurred with respect to the compounds in question.     

Lithospheric structure of the Trans-European Suture Zone along the TTZ–CEL03 seismic transect (from NW to SE Poland)

The large-scale CELEBRATION 2000 seismic experiment investigated the velocity structure of the crust and upper mantle between western portion of the East European Craton (EEC) and the eastern Alps. This area comprises: the Trans-European Suture Zone, the Carpathian Mountains, the Pannonian Basin and the Bohemian Massif. This experiment included 147 chemical shots recorded by 1230 seismic stations during two deployments. Good quality data along 16 main and a few additional profiles were recorded. One of them, profile CEL03, was located in southeastern Poland and was laid out as a prolongation of the TTZ profile performed in 1993. This paper focuses on the joint interpretation of seismic data along the NW–SE trending TTZ–CEL03 transect, located in the central portion of the Trans-European Suture Zone. First arrivals and later phases of waves reflected/refracted in the crust and upper mantle were interpreted using two-dimensional tomographic inversion and ray-tracing techniques. This modelling established a 2-D (quasi 3-D) P-wave velocity lithospheric model. Four crustal units were identified along the transect. From northwest to southeast, thickness of the crust varies from 35 km in the Pomeranian Unit (NW) to 40 km in the Kuiavian Unit, to 50 km in the Radom–Łysogóry Unit and again to 43 km in the Narol Unit (SE). The first two units are thought to be proximal terranes detached from the EEC farther to the southeast and re-accreted to the edge of the EEC during the Early Palaeozoic. The origin of the remaining two units is a matter of dispute: they are either portions of the EEC or other proximal terranes. In the area of the Polish Basin (first two units), the P-wave velocity is very low (V_p < 6.1 km/s) down to depths of 15–20 km indicating that a very thick sedimentary and possibly volcanic rock sequence, whose lower portion may be metamorphosed, is present. The velocity beneath the Moho was found to be rather high, being 8.25 km/s in the northwestern portion of the transect, 8.4 km/s in the central sector, and 8.1 km/s in the southeastern sector.     

Is There Evidence for Solar Forcing of Climate in the GISP2 Oxygen Isotope Record?

Changes in solar constant over an 11 yr cycle suggest a certain, but limited, degree of solar forcing of climate. The high-resolution climate (oxygen isotope) record of the Greenland GISP2 (Greenland Ice Sheet Project 2) ice core has been analyzed for solar (and volcanic) influences. The atmospheric¹⁴C record is used as a proxy of solar change and compared to the oxygen isotope profile in the GISP2 ice core. An annual oxygen isotope profile is derived from centimeter-scale isotope measurements available for the post-A.D. 818 interval. Associated extreme summer and winter isotope ratios were found to yield similar climate information over the last millennium. The detailed record of volcanic aerosols, converted to optical depth and volcanic explosivity change, was also compared to the isotope record and the oxygen isotope response calibrated to short-term volcanic influences on climate. This calibration shows that century-scale volcanic modulation of the GISP2 oxygen isotope record can be neglected in our analysis of solar forcing. The timing, estimated order of temperature change, and phase lag of several maxima in¹⁴C and minima in¹⁸O are suggestive of a solar component to the forcing of Greenland climate over the current millennium. The fractional climate response of the cold interval associated with the Maunder sunspot minimum (and¹⁴C maximum), as well as the Medieval Warm Period and Little Ice Age temperature trend of the past millennium, are compatible with solar climate forcing, with an order of magnitude of solar constant change of 0.3%. Even though solar forcing of climate for the current millennium is a reasonable hypothesis, for the rest of the Holocene the century-scale events are more frequent in the oxygen isotope record than in the¹⁴C record and a significant correlation is absent. For this interval, oceanic/atmospheric circulation forcing of climate may dominate. Solar forcing during the surprisingly strong 1470 yr climate cycle of the 11,000–75,000 yr B.P. interval is rather hypothetical.     

Response of douglas fir (Pseudotsuga menziesii) to uraniferous groundwater in a small glaciated drainage, Northeastern Washington State

Douglas fir trees and associated soils were sampled from the slopes of a small ( 4 km²) drainage basin in northeastern Washington to investigate the biogeochemical response to locally uraniferous groundwater. Uranium is preferentially incorporated in needles and twigs compared to larger branches or the trunk. The U concentration in needle ash ranges from 0.2 to 5.8 μg g⁻¹ (ppm) and shows no correlation with the U concentration in associated soils. Rather, the distribution of anomalously uraniferous douglas fir (>1.0μg g⁻¹ U in needle ash) appears to be controlled by observed or readily inferred pathways of near-surface groundwater movement in the drainage. These pathways include: (1) general downslope movement of subsurface runoff; (2) increased flux of near-surface groundwater near the toe of an alluvial fan; and (3) emergence of uraniferous (100–150 ng ml⁻¹ [ppb] groundwater in the vicinity of a slope spring. The data also indicate the presence of near-surface uraniferous groundwater along a structurally controlled zone that parallels the north-south strike of the valley, and that includes the slope spring. The results suggest that biogeochemical sampling may be used to supplement more direct, but more limited, measurements of groundwater quality and flow regime in areas of near-surface contaminated groundwater.     

Stochastic analysis of lithologic sequences: Bed thickness distribution

A stochastic model of bed thickness distribution is given. The following scheme of sedimentation and bed formation is assumed: (1)sedimentation consists of an unending sequence of alternating periods of deposition and erosion; (2)succession of sedimentary environments is described in terms of a transition probability matrix; (3)each depositional period accumulates a bed of sediments; (4)net accumulation exceeds erosion; (5)amounts of deposition and erosion are independent random variables. The equations for transformation of bed thickness distribution from sedimentary environment to geologic record are obtained. The sedimentological significance of these equations is discussed.     

Mode of occurrence and environmental mobility of oil-field radioactive material at US Geological Survey research site B,Osage-Skiatook Project,northeastern Oklahoma

Two samples of produced-water collected from a storage tank at US Geological Survey research site B, near Skiatook Lake in northeastern Oklahoma, have activity concentrations of dissolved ²²⁶Ra and ²²⁸Ra that are about 1500 disintegrations/min/L (dpm/L). Produced-water also contains minor amounts of small (5–50 μm) suspended grains of Ra-bearing BaSO₄ (barite). Precipitation of radioactive barite scale in the storage tank is probably hindered by low concentrations of dissolved SO₄ (2.5 mg/L) in the produced-water. Sediments in a storage pit used to temporarily collect releases of produced-water have marginally elevated concentrations of “excess” Ra (several dpm/g), that are 15–65% above natural background values. Tank and pit waters are chemically oversaturated with barite, and some small (2–20 μm) barite grains observed in the pit sediments could be transferred from the tank or formed in place. Measurements of the concentrations of Ba and excess Ra isotopes in the pit sediments show variations with depth that are consistent with relatively uniform deposition and progressive burial of an insoluble Ra-bearing host (barite?). The short-lived ²²⁸Ra isotope (half-life = 5.76 a) shows greater reductions with depth than ²²⁶Ra (half-life = 1600 a), that are likely explained by radioactive decay. The ²²⁸Ra/²²⁶Ra activity ratio of excess Ra in uppermost pit sediments (1.13–1.17) is close to the ratio measured in the samples of produced-water (0.97, 1.14). Declines in Ra activity ratio (excess) with sediment depth can be used to estimate an average rate of burial of 4 cm/a for the Ra-bearing contaminant. Local shallow ground waters contaminated with NaCl from produced-water have low dissolved Ra (<20 dpm/L) and also are oversaturated with barite. Barite is a highly insoluble Ra host that probably limits the environmental mobility of Ra at site B.     

Use of dissolved chloride concentrations in tributary streams to support geospatial estimates of Cl contamination potential near Skiatook Lake,northeastern Oklahoma

Releases of NaCl-rich (>100 000 mg/L) water that is co-produced from petroleum wells can adversely affect the quality of ground and surface waters. To evaluate produced water impacts on lakes, rivers and streams, an assessment of the contamination potential must be attainable using reliable and cost-effective methods. This study examines the feasibility of using geographic information system (GIS) analysis to assess the contamination potential of Cl to Skiatook Lake in the Hominy Creek drainage basin in northeastern Oklahoma. GIS-based predictions of affects of Cl within individual subdrainages are supported by measurements of Cl concentration and discharge in 19 tributaries to Skiatook Lake. Dissolved Cl concentrations measured in October, 2004 provide a snapshot of conditions assumed to be reasonably representative of typical inputs to the lake. Chloride concentrations ranged from 5.8 to 2300 mg/L and compare to a value of 34 mg/L in the lake. At the time of sampling, Hominy Creek provided 63% of the surface water entering the lake and 80% of the Cl load. The Cl load from the other tributaries is relatively small (<600 kg/day) compared to Hominy Creek (11 900 kg/day) because their discharges are relatively small (<0.44 m³/s) relative to Hominy Creek (3.1 m³/s). Examination of chemical components other than Cl in stream and lake waters indicates that many species, such as SO₄, cannot be used to assess contamination potential because they participate in a number of common biogeochemical processes that alter their concentrations.     

Processes that can disturb the chronostratigraphy of laminated sediments and pollen deposition

The sediment trap technique was used to study the sedimentation processes in two parts of Lake Goci, central Poland, the deep of the main basin and the shallow bay area. From field and lab data was noted that seasonal and annual deposition of pollen grains on the lake bottom was disturbed in the main basin by an increase in water mass dynamics and by resuspension and focusing. Greater concordance between pollen sedimentation and the flowering periods of plants was found in the bay area, where sediment resuspension took place sporadically and with less intensity, compared to the main basin. Futhermore, it is suggested that resuspension of pollen can occur even if laminated sediments are formed, a process which therby diminishes the chronostratigraphic value of sediments and pollen analyses.