Determination par activation neutronique des rapports Cl/Br des inclusions fluides de divers gypses. Correlation avec les donnees de la microcryoscopie et interpretations genetiques

Gypsum contains liquid inclusions which fill mainly primary cavities. Analysis of inclusions may give some information about the mineral formation process. In places, diagenetic solutions have filled secondary cavities along cleavage planes or replaced initial liquid inclusions in primary cavities; the presence of such secondary inclusions must, therefore, be taken into consideration. This study presents our results on the Cl/Br ratio of liquid inclusions in gypsum. The Cl/Br ratio is practically constant in present sea water, and has been measured in many different types of waters. The Br content of halite has also been extensively studied to trace the compositional changes of a salt-depositing brine. In gypsum Br is present only in microscopic fluid inclusions. For this reason we used the neutron-activation method. We adopted the technique in order to prevent any contamination and obtain directly Cl/Br ratio within 10% accuracy. In order to ascertain that liquid inclusions reside mainly in primary cavities of gypsum, we selected our samples only after microscopic observation. Fifty-eight samples from different types of gypsum were analysed. The salinities of the inclusions, obtained through the data on freezing, and the Cl/Br ratio, obtained through activation-analysis, give us clues as to the nature of the fluids depositing the gypsum. Recent gypsum deposits from French salt-pans of Mediterranean and Atlantic coasts were sampled. The latter has apparently been diagenetically altered by meteoric water; the salinity of many inclusions having been changed while the Cl/Br ratio (315 and 350) in both remains close to the value of present sea water (#300). Liquid inclusions of Recent crystals from New Caledonia, deposited in mangrove swamps are enriched in Br (Cl/Br = 150 and 200). The enrichment might be related to the presence of abundant organic materials. Inclusions in crystals from Sebkha el Melah (Tunisia) also show high Br content (Cl/Br = 194). In this case, the brine was highly concentrated and was saturated with NaCl. The Upper Miocene gypsum from Sicily was studied to test the various models for the genesis of this important evaporite formation of the Mediterranean. Freezing data show some decrease of salinities, probably by groundwater diagenesis, but the Br content is high. The Cl/Br ratio is 175, and this value is similar to that of Sebkha el Melah. Samples from three thick Eocene and Oligocene sequences near Paris and in the South of France were studied. Freezing data and Cl/Br ratio of their inclusions indicate that those gypsum deposits have crystallized in marine environments receiving considerable influx of river-waters.     

Recent variations in the general circulation as related to glacier retreat in northern Scandinavia

Summary A review is given of the investigations on variations in the general circulation in middle latitudes made byWillett andPetterssen. According toWillett a «high-index» type of circulation pattern with a strong zonal flow has probably caused the recent climatic improvement in the northern latitudes while the «low-index» type with meridional flow would create a cooling off in the same areas. According toPetterssen an other type of «low-index» pattern with a weak zonal flow and strong meridional exchange of air has been the essential cause of the warming up of the northern latitudes in Europe. This implies that the definition of the «low-index» type is not clear and gives rise to misunderstanding. Making use of our experience on glacier retreat in northern Scandinavia it is concluded that thePetterssen type of circulation more probably than the «high-index» type has caused the warming-up in the North Atlantic area from which the retreat of the glaciers has followed.     

Exploring Chile: Identities and Their Relation with the Environment through the Film Football Stories

Cinema can be considered a useful tool for understanding different geographic concepts, showing physical and human factors and the interactions between them. Andres Wood's film Football Stories explores the Chilean territory allowing the observation of the differences between the north and south of the country. Geographic components such as landscapes, architectures, the impact of anthropogenic activities, social inequalities, ways of life, and city and countryside differences are analyzed, as well as the importance of location, the spatial environment, and cinematic narration. The study of geography through films could contribute to understanding of our world and to spatial knowledge.     

The Beach Crowding Index: A Tool for Assessing Social Carrying Capacity of Vulnerable Beaches

The aim of this article is to introduce the Beach Crowding Index (BCI), a procedure to assess the social carrying capacity of vulnerable beaches. The study uses the people at one time (PAOT) approach and data gathered weekly throughout the bathing season regarding the number of beachgoers in 100 m² cells of the beach to assess how many beachgoers it can comfortably hold. The procedure is based on fieldwork, interviews with beachgoers, and geographic information system (GIS) analysis and has been tested on four beaches in protected areas on the Spanish Mediterranean coast. On a scale from 0 to 4, minimum scores throughout the bathing season are 0.7 and maximum 3.7, although results showed wide variation between the beaches, the section of the beach, and the time of day. This study suggests that determining the location of beachgoers and collecting a long-term series of data is fundamental to assessing social carrying capacity and that the BCI procedure can be used for a large number of applications.     

Identifying Groundwater Potential in Crystalline Basement Rocks Using Remote Sensing and Electromagnetic Sounding Techniques in Central Western Mozambique

Exploring for groundwater in crystalline rocks in semiarid areas is a challenge because of their complex hydrogeology and low potential yields. An integrated approach was applied in central western Mozambique, in an area covered by Precambrian crystalline basement rocks. The approach combined a digital elevation model (DEM), remote sensing, and a ground-based geophysical survey. The aim was to identify groundwater zones with high potential and to identify geological structures controlling that potential. Lineaments were extracted from the DEM that had been enhanced using an adaptive-tilt, multi-directional, shading technique and a non-filtering technique to characterize the regional fracture system. The shallowness and amount of stored groundwater in the fracture zones was assessed using vegetation indices derived from Landsat 8 OLI images. Then, 14 transient electromagnetic (TEM) survey profiles were taken in different geological settings across continuous lineaments that were considered to be aligned along inferred faults. In the central lineament zones, the TEM soundings gave resistivity values of less than 300 Ωm at a depth of 20–80 m. The values varied with location. Conversely, values greater than 400 Ωm were observed at the sites away from the central zones. This contrast is probably caused by the differences in permeability and degree of weathering along the fractured zones. These differences could be key factors in determining groundwater occurrence. By integrating five water-related factors (lineament density, slope, geology, vegetation index, and proximity to lineaments), high groundwater potential zones were located in the vicinity of the lineaments. In these zones, vegetation remains active regardless of the season.     

Evaluation of an automated EA-IRMS method for total carbon analysis of atmospheric aerosol at HEKAL

Comprehensive atmospheric studies have demonstrated that carbonaceous particles are one of the main components of atmospheric aerosols over Europe. The aim of our study was to establish an automated elemental analyser interfaced to a stable isotope mass spectrometer (EA-IRMS) method at the Hertelendi Laboratory of Environmental Studies (HEKAL), as a suitable method of quantification of total carbon mass in individual PM_2.5 aerosol samples. Total carbon (TC) mass and simultaneous stable isotopic ratios were determined for both test standard and genuine aerosol samples. Finally, the results were compared to the ones obtained independently by an alternative sealed tube combustion method developed previously at HEKAL. The TC recovery tests of standard material prepared by the sealed tube method confirmed at least a carbon recovery yield of 92% for a broad range of carbon mass (100–2000 μg). The stable isotopic results confirmed that sealed tube method is reproducible and suitable to be used as a reference to verify our new EA-IRMS method. The EA-IRMS TC measurements of genuine aerosols gave on average 3% higher carbon recovery yield, relative to the uncorrected results of the sealed tube method. The comparison of the stable isotopic results by the two methods for aerosols also showed minimal differences. Consequently, the possibility of simultaneous TC and stable isotopic analyses makes the EA-IRMS method a very attractive alternative for continuous measurement of aerosols, with an accuracy and reliability similar to other commercial devices.     

Impacts of climate change on building energy demands in the intra-Americas region

It was recently reported a regional warming in the intra-Americas region where sea surface temperature exhibited increases exceeding 0.15 °C/decade and an accelerated air temperature rise that could impact building energy demands per capita (EDC). Reanalysis data is used herein to quantify the impacts of these warming trends on EDC. Results of the analysis depict a Southern Greater Antilles and inland South America with a positive annual EDC rate of 1–5 kWh per year. The Intergovernmental Panel on Climate Change (IPCC) Representative Concentration Pathways (RCP) 2.6 and 4.5 scenarios were selected to analyze energy demand changes in the twenty-first century. A multi-model ensemble forecasts an EDC increase of 9.6 and 23 kWh/month in the RCP2.6 and RCP4.5 at the end of the twenty-first century, which may increase average building cooling loads in the region by 7.57 GW (RCP2.6) and 8.15 GW (RCP4.5), respectively. Furthermore, 4 of 9 (RCP2.6) and 7 of 9 (RCP4.5) of the major countries in this region have EDCs ranging between 1887 and 2252 kWh/year at the end of this century. Therefore, increased energy production and improved energy infrastructure will be required to maintain ideal indoor building conditions at the end of the twenty-first century in these tropical coastal regions as consequence of a warmer climate.     

Effect of asymmetrical street canyons on pedestrian thermal comfort in warm-humid climate of Cuba

Walkability and livability in cities can be enhanced by creating comfortable environments in the streets. The profile of an urban street canyon has a substantial impact on outdoor thermal conditions at pedestrian level. This paper deals with the effect of asymmetrical street canyon profiles, common in the historical centre of Camagüey, Cuba, on outdoor thermal comfort. Temporal-spatial analyses are conducted using the Heliodon2 and the RayMan model, which enable the generation of accurate predictions about solar radiation and thermal conditions of urban spaces, respectively. On these models, urban settings are represented by asymmetrical street canyons with five different height-to-width ratios and four street axis orientations (N-S, NE-SW, E-W, SE-NW). Results are evaluated for daytime hours across the street canyon, by means of the physiologically equivalent temperature (PET index) which allows the evaluation of the bioclimatic conditions of outdoor environments. Our findings revealed that high profiles (façades) located on the east-facing side of N-S streets, on the southeast-facing side of NE-SW streets, on the south-facing side of E-W street, and on the southwest-facing side of SE-NW streets, are recommended to reduce the total number of hours under thermal stress. E-W street canyons are the most thermally stressed ones, with extreme PET values around 36 °C. Deviating from this orientation ameliorates the heat stress with reductions of up to 4 h in summer. For all analysed E-W orientations, only about one fifth of the street can be comfortable, especially for high aspect ratios (H/W > 3). Optimal subzones in the street are next to the north side of the E-W street, northwest side of the NE-SW street, and southwest side of the SE-NW street. Besides, when the highest profile is located on the east side of N-S streets, then the subzone next to the east-facing façade is recommendable for pedestrians. The proposed urban guidelines enable urban planners to create and renovate urban spaces which are more efficient in diminishing pedestrian thermal stress.