Ground water geochemistry of 228Ra, 226Ra and 222Rn

²²⁸Ra, ²²⁶Ra, and ²²²Rn activities were determined on over 150 ground water samples collected from drilled, public water supply wells throughout South Carolina. A wide range of aquifer lithologies were sampled including the crystalline rocks of the Piedmont and sedimentary deposits of the Coastal Plain. A significant linear relationship between log ²²⁸Ra and log ²²⁶Ra (n = 182, r = 0.83) was indistinguishable between Piedmont and Coastal Plain ground water. Median ${}^{228}\text{Ra}{}^{226}\text{Ra}$ activity ratios for the Piedmont, 1.2, and Coastal Plain, 1.3, ground water are close to estimated average crustal ${}^{232}\text{Th}{}^{238}\text{U}$ activity ratios of 1.2 to 1.5 corresponding to Th/U weight ratios of 3.5 to 4.5. A linear correlation was also found between log ²²²Rn and log ²²⁶Ra for Piedmont (n = 68, r = 0.62) and Coastal Plain (n = 89, r = 0.64) ground water. However, the median ${}^{222}\text{Rn}{}^{226}\text{Ra}$ activity ratio for Piedmont ground water, 6100, was much higher than for Coastal Plain ground water, 230. Higher excess ²²²Rn activities may be due to greater retention of ²²⁶Ra by the chemically active Piedmont aquifers compared to the more inert sand aquifers sampled in the Coastal Plain. The relationship between log ²²⁸Ra and log ²²⁶Ra was used to predict total Ra (${}^{228}\text{Ra +}{}^{226}\text{Ra}$) distributions in Appalachian and Atlantic and Gulf Coastal Plain ground water. Predictions estimate that 2.4% of Appalachian and 5.3% of Atlantic and Gulf Coastal Plain ground water supplies contain total Ra activities in excess of the 5 pCi/l limit established by the U.S. Environmental Protection Agency. These predictions also indicate that 40–50% of these ground water wells may be overlooked using the presently suggested screening activity of 3.0 pCi/l of ²²⁶Ra for ²²⁸Ra analysis.     

Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano,Hawaii

Eighteen basalts and some volcanic gases from the submarine and subaerial parts of Kilauea volcano were analyzed for the concentration and isotope ratios of sulfur. By means of a newly developed technique, sulfide and sulfate sulfur in the basalts were separately but simultaneously determined. The submarine basalt has 700 ± 100 ppm total sulfur with δ³⁴S_Σs of $\text{0.7 ± 0.1 ‰}$. The sulfate/sulfide molar ratio ranges from 0.15 to 0.56 and the fractionation factor between sulfate and sulfide is $\text{+7.5 ± 1.5‰}$. On the other hand, the concentration and δ³⁴S_Σs values of the total sulfur in the subaerial basalt are reduced to 150 ± 50 ppm and $\text{?0.8 ± 0.2‰}$, respectively. The sulfate to sulfide ratio and the fractionation factor between them are also smaller, 0.01 to 0.25 and +3.0‰, respectively. Chemical and isotopic evidence strongly suggests that sulfate and sulfide in the submarine basalt are in chemical and isotopic equilibria with each other at magmatic conditions. Their relative abundance and the isotope fractionation factors may be used to estimate the $\text{?o}{}_2$ and temperature of these basalts at the time of their extrusion onto the sea floor. The observed change in sulfur chemistry and isotopic ratios from the submarine to subaerial basalts can be interpreted as degassing of the SO₂ from basalt thereby depleting sulfate and ³⁴S in basalt.The volcanic sulfur gases, predominantly SO₂, from the 1971 and 1974 fissures in Kilauea Crater have δ³⁴S values of 0.8 to 0.9%., slightly heavier than the total sulfur in the submarine basalts and definitely heavier than the subaerial basalts, in accord with the above model. However, the δ³⁴S value of sulfur gases (largely SO₂) from Sulfur Bank is 8.0%., implying a secondary origin of the sulfur. The δ³⁴S values of native sulfur deposits at various sites of Kilauea and Mauna Loa volcanos, sulfate ions of four deep wells and hydrogen sulfide from a geothermal well along the east rift zone are also reported. The high δ³⁴S values (+5 to +6%._o) found for the hydrogen sulfide might be an indication of hot basaltseawater reaction beneath the east rift zone.     

The Tantalite Valley shear zone — a major locus for igneous activity in Southern Namibia (South West Africa)?

The Tantalite Valley Shear Zone is a major Precambrian, southeast-trending tectonic lineament extending for some 500 km (possibly as much as 800 km) along strike in southern Namibia (South West Africa) and the northern Cape Province of South Africa. A minimum right-lateral displacement of 85 km has been estimated for this shear zone, which is one of a number with similar orientations found in southwestern Africa. The shear zones may represent slip-lines produced during continental collision about 1000–1300 m.y. B.P.The shear zones have acted as the locus for the intrusion of high-alumina tholeiitic magmas which have led to the development of a number of mafic to ultramafic complexes situated in or near the zones, and particularly the Tantalite Valley Shear Zone. Igneous activity and tectonism took place over an extended period of time and some bodies have been partly or completely metamorphosed to metagabbro or amphibolite.Three complexes have been studied in detail and they are geochemically distinct from each other, such that they cannot be related to one another by simple processes of fractionation although the rock types within any one complex may be so related. All show broad similarities in that they are depleted in lithophile elements (Ba, Rb, Sr, Nb, Zr) and enriched in nickel relative to similar basalts found elsewhere.     

Tectonic complexities in the bonin arc system

The Bonin arc system is anomalous in that it does not appear to fit the tectonic pattern observed in most arc systems. Re-examination of this arc system, with a new bathymetric chart and against a background of recent studies in other arcs, leads to reasonable explanations for its anomalous characteristics. The frontal-arc volcanics on the Bonin Islands, which now form part of the trench slope break, can best be explained by the northward rifting of the Bonin Islands block from a position along the frontal arc under the influence of oblique subduction. The very large positive gravity anomaly over the islands results from the greater than normal density and volume of the volcanics compared to most trench slope breaks. The dominant northeast—southwest ridge and trough topography, into which the Iwo Jima Ridge (frontal arc) is broken may have resulted from compressions of the arc along its trend. This compression would be attributed to the southward movement of Japan as the Yamato Basin of the Sea of Japan opened in the Late Oligocene and Early Miocene. Recent extension is occurring in the Bonin arc system, as earlier suggested, but in an east—west direction. Features associated with extension can best be identified at the south end of the arc, but may persist for its entire length. This extension is either more rapid, or began first at the south end.     

Estimates of integral time scales from a 100-M meteorological tower at a plains site

Four distinct types of autocorrelograms were observed using high-frequency vertical velocity data measured at 100 m above a flat terrain. Several types of nonstationary atmospheric motions due to low frequency fluctuations were examined. Under nighttime stable conditions, these phenomena were found to lead to abnormally slow exponential decay of the autocorrelation function. Several different techniques for estimating Eulerian integral time scales were compared in order to select an appropriate method of estimation. When grouped by stability classes, the Eulerian integral time scales decrease slightly with increasing stability, but generally exhibit no significant correlation with other meteorological parameters. Using a postulated relation, estimates of the Lagrangian to Eulerian integral time scale ratio range from 3 to 5 under unstable conditions and 15 to 25 under stable conditions. Under unstable conditions the average Lagrangian integral time scale is on the order of 40 s and exhibits no significant correlation with several pertinent meteorological parameters. Under stable conditions, the Lagrangian integral time scale correlates well with the Monin-Obukhov length and temperature lapse rate.Work conducted while a visiting scholar at Systems Applications, Inc.     

Environmental effects of the use of oil-based drilling muds in the North Sea

The environmental effects of oil-based drilling mud cuttings have been evaluated using all the data available from monitoring around North Sea platforms. Beneath the platforms making extensive use of oil-based drilling muds the natural sediment is buried by cuttings and the hydrocarbon concentration 250 m from the platforms may be 1000 times background, but the concentration gradient is very steep and background levels are usually reached 2000–3000 m from the platform.The extent of the biological effects appear to be greater from the use of oil-based muds than from water-based muds. Beyond the area of physical smothering the effects of oil-based mud cuttings may be due to organic enrichment or to the toxicity of the aromatic fraction of the oil. Despite the large scale of inputs, in all the fields studied the major deleterious biological effects occurred within 500 m of the platform. Surrounding the area of major impact was a transition zone in which subtle biological effects could be detected as community parameters returned to normal, generally within 400–1000 m.The shape and extent of this zone varied and was largely determined by the current regime and scale of the drilling operation. Elevated hydrocarbon concentrations were detected beyond the areas of biological effects.     

Hotine’s conjecture in differential geodesy

In this paper we present a critical examination of a conjecture ofMartin Hotine on the possibility of employing the geopotential function of the Earth’s gravitational field as a member of a triply orthogonal system of surfaces. If such a conjecture were valid, it would provide a natural triply orthogonal system of coordinates which would be of significance in mathematical geodesy. It is shown that Hotine’s arguments are inadequate to prove his conjecture, and finally that his conjecture is false. Dedicated to the memory of Martin Hotine (1898–1968)     

Laser station coordinates and baselines from long-ARC and short-ARC analyses of starlette

Laser ranging to Starlette from April 1983 to April 1984 has been used to determine a coordinate set, UASC.ST1, of laser reference points for 18 tracking stations. The coordinates were derived by application of the least-squares data reduction procedure in a simultaneous solution along with geodynamic parameters for 49 near consecutive 5–6 day arcs. Comparisons with the University of Texas station coordinates,LSC 8112 andLSC 8402, and theRGO, Herstmonceux, coordinates,RGOSC.LG2, reveal consistency to near 30 cm in each coordinate. Furthermore, the translation vectors of the comparisons are not significantly different from zero indicating consistency in the implied origins of the systems. The period of analysis included seven occasions in which STARLETTE was tracked near simultaneously by three or four laser stations in North America. Using the short arcs as reference frameworks, station coordinates were determined by application of two contrasting methods, namely, a multi-arc simultaneous analysis and a weighted mean of the individual pass solutions. The former compared more favourably with baselines from the long-arc solution with anRMS error of near 16 cm. Comparison against theLSC 8402 coordinates confirmed that baselines accurate to within 15 cm can be achieved by satellite laser ranging to Starlette.     

Macrocryst Fe - Ti oxides in olivine melilitites from Namaqualand-Bushmanland South Africa

Ilmenite macrocrysts in olivine melilitites from Namaqualand-Bushmanland, South Africa, have decomposed by subsolidus reduction to form oriented Mg-titanomagnetite along {0001} ilmenite planes. Residual ilmenite contains 10–11 wt% MgO, 1 wt% MnO, and 0.1 wt% Cr₂O₃. This macrocryst assemblage is mantled by an annulus of Mg-titanomagnetite, followed by an overgrowth of radiating magnetite + perovskite. Terminal compositions of these magnetites are similar to groundmass spinels, and to the outermost margins of magnetite macrocrysts that have very high Fe³⁺ core contents. The assemblages are remarkably similar to oxide intergrowths in kimberlites and an upper mantle derivation is proposed for ilmenite macrocrysts in these melilitites. Oxidation states in the source regions are also very similar, whether on-or off-craton, being slightly above FMQ (NNO), but reduced to FMQWM with the onset of decompression, volatile loss, and carbonate immiscibility. In the case of the melilitites, late stage, low pressure crystallization above NNO precipated abundant magnetite + perovskite. The oxide fO₂ data are consistent with, and refine the fO₂ estimates obtained previously for the behavior of Fe/Mg and Ni contents in olivine from the same suite of samples.