The radiolysis of SO2 and H2S in water ice: Implications for the icy jovian satellites

Spectra of Europa, Ganymede, and Callisto reveal surfaces dominated by frozen water, hydrated materials, and minor amounts of SO₂, CO₂, and H₂O₂. These icy moons undergo significant bombardment by jovian magnetospheric radiation (protons, electrons, and sulfur and oxygen ions) which alters their surface compositions. In order to understand radiation-induced changes on icy moons, we have measured the mid-infrared spectra of 0.8 MeV proton-irradiated SO₂, H₂S, and H₂O-ice mixtures containing either SO₂ or H₂S. Samples with H₂O/SO₂ or H₂O/H₂S ratios in the 3-30 range have been irradiated at 86, 110, and 132 K, and the radiation half-lives of SO₂ and H₂S have been determined. New radiation products include the H₂S₂ molecule and HSO⁻₃, HSO⁻₄, and SO²⁻₄ ions, all with spectral features that make them candidates for future laboratory work and, perhaps, astronomical observations. Spectra of both unirradiated and irradiated ices have been recorded as a function of temperature, to examine thermal stability and phase changes. The formation of hydrated sulfuric acid in irradiated ice mixtures has been observed, along with the thermal evolution of hydrates to form pure sulfuric acid. These laboratory studies provide fundamental information on likely processes affecting the outer icy shells of Europa, Ganymede, and Callisto.     

Adaptive Relative Motion Representation of Space–Time Trajectories

Abstract

In this article the author explains how military geography information is being exploited by modern Armed Forces. In doing so he highlights some of the underlying principles of surveying and cartographic that define paper mapping, and that are still applicable in the digital era.

This article reflects the personal views of Lieutenant Colonel Prain who is currently serving in the Headquarters of the Defence Geographic and Imagery Intelligence Agency.     

Integrity monitoring of fixed ambiguity Precise Point Positioning (PPP) solutions

Traditional positioning methods, such as conventional Real Time Kinematic (cRTK) rely upon local reference networks to enable users to achieve high-accuracy positioning. The need for such relatively dense networks has significant cost implications. Precise Point Positioning (PPP) on the other hand is a positioning method capable of centimeter-level positioning without the need for such local networks, hence providing significant cost benefits especially in remote areas. This paper presents the state-of-the-art PPP method using both GPS and GLONASS measurements to estimate the float position solution before attempting to resolve GPS integer ambiguities. Integrity monitoring is carried out using the Imperial College Carrier-phase Receiver Autonomous Integrity Monitoring method. A new method to detect and exclude GPS base-satellite failures is developed. A base-satellite is a satellite whose measurements are differenced from other satellite’s measurements when using between-satellite-differenced measurements to estimate position. The failure detection and exclusion methods are tested using static GNSS data recorded by International GNSS Service stations both in static and dynamic processing modes. The results show that failure detection can be achieved in all cases tested and failure exclusion can be achieved for static cases. In the kinematic processing cases, failure exclusion is more difficult because the higher noise in the measurement residuals increases the difficulty to distinguish between failures associated with the base-satellite and other satellites.     

Evaluating DEM source and resolution uncertainties in the Soil and Water Assessment Tool

DEMs as important input parameters of environmental risk assessment models are notable sources of uncertainties. To illustrate the effect of DEM grid size and source on model outputs, a widely used watershed management model, the Soil and Water Assessment Tool (SWAT), was applied with two newly available DEMs as inputs (i.e. ASTER GDEM Version 1, and SRTM Version 4.1). A DEM derived from 1:10,000 high resolution digital line graph (DLG) was used as a baseline for comparisons. Eleven resample resolutions, from 5 to 140?m, were considered to evaluate the impact of DEM resolution on SWAT outputs. Results from a case study in South-eastern China indicate that the SWAT predictions of total phosphorus and total nitrogen decreased substantially with coarser resample resolution. A slightly decreasing trend was found in the SWAT predicted sediment when DEMs were resampled to coarser resolutions. The SWAT predicted runoff was not sensitive to resample resolution. For different data sources, ASTER GDEM did not perform better than SRTM in SWAT simulations even it was provided with a smaller grid size and higher vertical accuracy. The predicted outputs based on ASTER GDEM and SRTM were similar, and much lower than the ones based on DLG. This study presents potential uncertainties introduced by DEM resolutions and data sources, and recommends strategies choosing DEMs based on research objects and maximum acceptable errors.     

Tropical cyclone-tornado casualties

Landfalling tropical cyclones often produce tornadoes. This study investigates how hazardous these tornadoes are to human life by analyzing the resultant casualties, which includes fatalities and injuries. From 1995 to 2009, 63 tropical cyclones made landfall in the United States producing a reported 1,139 tornadoes. Most tornadoes resulted in no casualties but a few extreme cases indicate that the potential exists for a substantial number of casualties. Temporal and spatial analyses indicate that most casualties occur when and where the physical risk of tornadoes is elevated.     

Porphyry copper potential mapping using the weights of evidence model in a GIS,northern Shahr e Babak,Iran

A variety of spatial geological data were compiled, evaluated and integrated to produce a potential map for porphyry copper deposits in the northern Shahr e Babak, Iran, within a total area of approximately 408 km². Remotely sensed data including LANDSAT Thematic Mapper were used to create the hydrothermal alteration haloes around intrusive bodies. Geological data, such as exposed granitic to intermediate intrusions, and part of the lineaments were extracted from available geological maps. Aeromagnetic data were also used to extract magnetic anomalies and extra lineaments. The Conditional Independence test was carried out on five binary maps representing diagnostic deposit recognition criteria, and four of them were then integrated using a weights of evidence model. The procedure generated a posterior probability map identifying favourable areas for porphyry copper deposits. The final map highlights the most important known copper deposits in high favourability domains. Some new target areas are also located in the favourability map and warrant further investigation.     

Natural attenuation of septic system nitrogen by anammox

On-site disposal of sewage in septic systems can lead to groundwater plumes with NO(3)(-)-N concentrations exceeding the common drinking water limit of 10 mg/L. Currently, denitrification is considered as the principal natural attenuation process. However, at a large seasonal-use septic system in Ontario (256 campsites), a suboxic zone exists where nitrogen removal of up to 80% occurs including removal of NH(4)(+)-N. This zone has both NO(3)(-)-N and NH(4)(+)-N at >5 mg/L each. In the distal NH(4)(+)-rich zone, NH(4)(+)-N concentrations (8.1 ± 8.0 mg/L) are lower than in the proximal zone (48 ± 36 mg/L) and NH(4)(+)-N is isotopically enriched (concentration-weighted mean δ(15)N of +15.7‰) compared to the proximal zone (+7.8‰). Furthermore, δ(15)N-NH(4)(+) isotopic enrichment increases with depth in the distal zone, which is opposite to what would result if nitrification along the water table zone was the mechanism causing NH(4)(+) depletion. Bacterial community composition was assessed with molecular (DNA-based) analysis and demonstrated that groundwater bacterial populations were predominantly composed of bacteria from two Candidatus genera of the Planctomycetales (Brocadia and Jettenia). Together, these data provide strong evidence that anaerobic ammonium oxidation (anammox) plays an important role in nitrogen attenuation at this site.     

Absolute Calibration of the TOPEX/POSEIDON Altimeters using UK Tide Gauges,GPS, and Precise,Local Geoid-Differences

This article describes an "absolute" calibration of TOPEX/POSEIDON (T/P) altimeter bias using UK tide gauges equipped with Global Positioning System (GPS) receivers. The method is an extension of earlier work using the Newhaven tide gauge in the English Channel. However, the present analysis extends the research to a number of gauges around the UK and incorporates several improvements. The time-averaged TOPEX and POSEIDON biases are obtained with a precision of approximately 2 and 3 cm, respectively. The research complements work on bias determination by other groups in the T/P Science Working Team and can, in principle, be applied at other locations for which precise, local geoid-differences are available. The relatively sparse POSEIDON data set has been used as a test of our ability to perform an absolute calibration of upcoming Jason-1 altimetry as soon as possible after launch.     

Geotechnical Investigation of the Titanic Wreck Site

Abstract

Recent marine forensic investigations have largely unravelled the sequence of events concerning the sinking of the R.M.S. Titanic and its descent through nearly 3800 m of water to the seafloor on the morning of 15 April 1912. In particular, the velocity and attitude of the Titanic's bow section (at present lying upright, reasonably intact, and embedded by ～12 m at the prow) as it hit the bottom are of general interest to marine accident investigators. During the 1998 Titanic Science Expedition, a single sediment sample was retrieved from the seafloor (depth 20–30 cm) near the wreck by the deep water submersible, Nautile. Published geological studies suggest the seafloor in this area has remained largely undisturbed since 1912. Geotechnical analysis of the sediment sample reveals that the impact was probably a substantially undrained event and that the characteristic undrained shear strength of the sediment is ～25kPa within 10–16 m below the seafloor. A simple analytical model was used to calculate the embedment of a cuboid with dimensions and mass of the water-filled bow as a function of impact velocity, impact angle, and the undrained shear strength of the sediment. The results indicate the impossibility of a steep angle of impact and fast velocity. The most likely scenario is an impact velocity of 5–10 m/s at a fairly shallow angle (<40°), which corroborates the results of hydrodynamic investigations.     

The sandhopper Talitrus saltator (Crustacea: Amphipoda) as a biomonitor of trace metal bioavailabilities in European coastal waters

The amphipod crustacean Talitrus saltator is an established, easily accessible, biomonitor of trace metal bioavailabilities in coastal waters. We have carried out a geographically widespread collection of T. saltator from European shores, stretching from the north-west Atlantic through the Baltic to the Mediterranean. A primary aim of the work was to establish a database of accumulated trace metal concentrations (Cd, Cr, Cu, Fe, Mn and Zn) in this biomonitor. Statistical analysis has shown significant geographical differences in the bioavailabilities of all the metals, the most distinct being copper, iron and manganese. It has proved possible to identify unusually high accumulated concentrations of Cd, Cr, Cu, Fe, Mn and Zn in this biomonitor, indicative of high metal bioavailability at a particular site. These may serve as reference points for future biomonitoring programmes seeking to identify metal contamination in coastal waters.