Unmanned Underwater Vehicle Fuel Cell Energy/Power System Technology Assessment

This paper provides a technology assessment for an unmanned underwater vehicle (UUV) fuel cell energy/power system (FCEPS), including design methodology and design concepts. The design concepts are based on the polymer electrolyte membrane fuel cell (FC) operating on hydrogen and oxygen. The technology assessment method presented is a holistic approach which combines alternative hydrogen and oxygen storage [and fuel cell system (FCS)] options to provide the highest specific energy and energy density-within the constraints of the UUV application. Using this method, some surprising combinations appear as the theoretical ldquowinnersrdquo for maximum energy storage within the application constraints of the UUV.     

How soil moisture mediates the influence of transpiration on streamflow at hourly to interannual scales in a forested catchment

The water balance equation dictates that streamflow may be reduced by transpiration. Yet temporal disequilibrium weakens the relationship between transpiration and streamflow in many cases where inputs and outputs are unbalanced. We address two critical knowledge barriers in ecohydrology with respect to time, scale dependence and lags. Study objectives were to correlate components of the water balance equation at hourly to annual scales, quantify time lags, and simplify critical components of the water budget during wet and dry conditions. We tested interrelationships among precipitation, vapour pressure deficit, transpiration, soil moisture, and streamflow within the confines of a 60‐hectare forested watershed in the western Cascades of Oregon. The Pacific Northwest is an ideal location to compare wet and dry seasons because of its Mediterranean climate. Soil moisture explained more than 80% of the variation in streamflow at all temporal scales investigated. Streamflow was most strongly coupled to soil moisture in the wet season because of gravitational drainage patterns; strong coupling of transpiration to vapour pressure deficit was dominant in the dry season and driven by low humidity. We observed progressively longer hourly time lags between soil moisture and streamflow in the dry season, which relates to an increasing soil moisture deficit that took an average of 48 days to refill after the onset of winter rains. We propose that transpiration drives seasonal patterns in soil moisture that relate to patterns in streamflow only after long time lags. In other words, soil moisture mediates the influence of transpiration on streamflow. Copyright © 2011 John Wiley & Sons, Ltd.     

Influences of upstream reservoir stratification and downstream tidal fluctuations on the summer thermal regime of a regulated coastal river

This study focused on the effects of upstream reservoir thermal dynamics and downstream tidal influences on temperatures in a 25-km reach of Alouette River (coastal British Columbia, Canada) below a control dam and upstream of its confluence with Pitt River. Temperature was monitored during summer 2013 using 25 sensors. Water was released from the reservoir through a low level outlet at approximately 2.7 m³ s⁻¹, except during late spring when a higher flow was released over the dam spillway. Temperature variations in the lowest section of Alouette River, and in the lower portion of a tributary, were distinct from those further upstream due to backwatering effects associated with a semi-diurnal tide, which can cause flow reversals in Pitt River. An internal seiche was identified in the reservoir during mid-summer that resulted in oscillating releases of warmer and cooler water with an amplitude of up to 6°C and a period of approximately 12 hr. Wavelet analysis and band-pass filtering indicated that the 12-hr signal declined in strength with downstream distance, but remained detectable about 15 km below the dam. In contrast, the 24-hr diel signal increased in strength with distance below the dam. Travel times computed via cross-correlation of the 12-hr signals with that at the low level outlet were within ±10% of those estimated from measured mean velocities. Lagrangian tracking of water parcels using the derived travel times indicated that the cooling effect of periodic releases of cold water during the seiching period persisted to the lower extent of the non-tidal reach. The tidally influenced locations experienced higher temperatures than those recorded in the non-tidal portion of Alouette River, although the relative roles of heating in the upstream tidal reach versus upstream advection of water associated with tide-driven flow reversals in Pitt River require further study.     

Copper isotope fractionation in the Meiduk porphyry copper deposit,Northwest of Kerman Cenozoic magmatic arc,Iran

The Meiduk deposit possesses three different Cu reservoirs each with a unique Cu isotope signature. δ⁶⁵Cu for the leached cap minerals ranges from ?2.5 to +0.49‰ to ?0.45 to +0.3‰ for hypogene minerals and from +1.3 to +4.4‰ for supergene enrichment minerals. Oxidation of hypogene sulphides and effective trapping of copper (from solutions derived from the leached cap) in the supergene enrichment zone caused this relationship. A systematic pattern of low Cu isotope values close to the surface and higher isotope values with depth reveals a palaeo‐fluid pathway in the northwest–southeast direction over the deposit. Thus, the copper isotope data from leached cap and enrichment minerals can be used to monitor copper migration during supergene weathering at the Meiduk deposit.     

Crowdsourcing The National Map

Using crowdsourcing techniques, the US Geological Survey’s (USGS) Volunteered Geographic Information (VGI) project known as “The National Map Corps (TNMCorps)” encourages citizen scientists to collect and edit data about man-made structures in an effort to provide accurate and authoritative map data for the USGS National Geospatial Program’s web-based The National Map. VGI is not new to the USGS, but past efforts have been hampered by available technologies. Building on lessons learned, TNMCorps volunteers are successfully editing 10 different structure types in all 50 states as well as Puerto Rico and the US Virgin Islands.     

Sublethal impact of short term exposure to the organophosphate pesticide azamethiphos in the marine mollusc Mytilus edulis

Concern has been raised that the increased use of pesticides in intensive aquaculture practices may cause adverse sublethal effects to non-target aquatic species. Azamethiphos is an organophosphate (OP) pesticide used to combat sea lice infestations in farmed salmonids. Here, the sublethal impact on the blue mussel, Mytilus edulis, of short term exposure to azamethiphos was determined. The testing regime included biomarkers of exposure (acetylcholinesterase activity), cytotoxicity (neutral red retention), immune function (phagocytic index) and physiological condition (feeding rate). The distribution and sensitivity of M. edulis acetylcholinesterase to inhibition by azamethiphos was first determined, yielding IC(50) values of 0.736 and 1.30 mg l(-1) for gill and haemolymph, respectively. Exposure of mussels to 0.1 mg l(-1) azamethiphos for periods of up to 24h caused a significant reduction in acetylcholinesterase activity in both the haemolymph (P<0.0002) and the gill (P<0.002), alteration in cell viability (P<0.02) and decrease in phagocytic index (P<0.03). The feeding rate remained unaffected. The results support the hypothesis that, in addition to its neurotoxic effects, azamethiphos can modulate haemocyte function and immune defence in M. edulis at environmentally relevant concentrations after only a few hours.     

Persistent organic pollutants carried by synthetic polymers in the ocean environment

Thermoplastic resin pellets are melted and formed into an enormous number of inexpensive consumer goods, many of which are discarded after a relatively short period of use, dropped haphazardly onto watersheds and then make their way to the ocean where some get ingested by marine life. In 2003 and 2004 pre-production thermoplastic resin pellets and post-consumer plastic fragments were collected and analyzed for contamination for persistent organic pollutants (POPs). Samples were taken from the North Pacific Gyre, and selected sites in California, Hawaii, and from Guadalupe Island, Mexico. The total concentration of PCBs ranged from 27 to 980 ng/g; DDTs from 22 to 7100 ng/g and PAHs from 39 to 1200 ng/g, and aliphatic hydrocarbons from 1.1 to 8600 microg/g. Analytical methods were developed to extract, concentrate and identify POPs that may have accumulated on plastic fragments and plastic pellets. The results of this study confirm that plastic debris is a trap for POPs.     

A comprehensive numerical simulation of Io’s sublimation-driven atmosphere

Io’s sublimation-driven atmosphere is modeled using the direct simulation Monte Carlo (DSMC) method. These rarefied gas dynamics simulations improve upon earlier models by using a three-dimensional domain encompassing the entire planet computed in parallel. The effects of plasma heating, planetary rotation, inhomogeneous surface frost, molecular residence time of SO₂ on the exposed (non-volatile) rocky surface, and surface temperature distribution are investigated. Circumplanetary flow is predicted to develop from the warm dayside toward the cooler nightside. Io’s rotation leads to a highly asymmetric frost surface temperature distribution (due to the frost’s high thermal inertia) which results in circumplanetary flow that is not axi-symmetric about the subsolar point. The non-equilibrium thermal structure of the atmosphere, specifically vibrational and rotational temperatures, is also examined. Plasma heating is found to significantly inflate the atmosphere on both the dayside and nightside. The plasma energy flux causes high temperatures at high altitudes but plasma energy depletion through the dense gas column above the warmest frost permits gas temperatures cooler than the surface at low altitudes. A frost map (Douté, S., Schmitt, B., Lopes-Gautier, R., Carlson, R., Soderblom, L., Shirley, J., and the Galileo NIMS Team [2001]. Icarus 149, 107-132) is used to control the sublimated flux of SO₂ which can result in inhomogeneous column densities that vary by nearly a factor of four for the same surface temperature. A short residence time for SO₂ molecules on the “rock” component is found to smooth lateral atmospheric inhomogeneities caused by variations in the surface frost distribution, creating an atmosphere that looks nearly identical to one with uniform frost coverage. A longer residence time is found to agree better with mid-infrared observations (Spencer, J.R., Lellouch, E., Richter, M.J., López-Valverde, M.A., Jessup, K.L, Greathouse, T.K., Flaud, J. [2005]. Icarus 176, 283-304) and reproduce the observed anti-jovian/sub-jovian column density asymmetry. The computed peak dayside column density for Io assuming a surface frost temperature of 115 K agrees with those suggested by Lyman-α observations (Feaga, L.M., McGrath, M., Feldman, P.D. [2009]. Icarus 201, 570-584). On the other hand, the peak dayside column density at 120 K is a factor of five larger and is higher than the upper range of observations (Jessup, K.L., Spencer, J.R., Ballester, G.E., Howell, R.R., Roesler, F., Vigel, M., Yelle, R. [2004]. Icarus 169, 197-215; Spencer et al., 2005).