Modulation and symmetry changes in stellar dynamos

Stellar dynamos are governed by non-linear partial differential equations (PDEs) which admit solutions with dipole, quadrupole or mixed symmetry (i.e. with different parities). These PDEs possess periodic solutions that describe magnetic cycles, and numerical studies reveal two different types of modulation. For modulations of Type 1 there are parity changes without significant changes of amplitude, while for Type 2 there are amplitude changes without significant changes in parity. In stars like the Sun, cyclic magnetic activity is interrupted by grand minima that correspond to Type 2 modulation. Although the Sun's magnetic field has maintained dipole symmetry for almost 300 yr, there was a significant parity change at the end of the Maunder Minimum. We infer that the solar field may have flipped from dipole to quadrupole polarity (and back) after deep minima in the past and may do so again in the future. Other stars, with different masses or rotation rates, may exhibit cyclic activity with dipole, quadrupole or mixed parity. The origins of such behaviour can be understood by relating the PDE results to solutions of appropriate low-order systems of ordinary differential equations (ODEs). Type 1 modulation is reproduced in a fourth-order system while Type 2 modulation occurs in a third-order system. Here we construct a new sixth-order system that describes both types of modulation and clarifies the interactions between symmetry-breaking and modulation of activity. Solutions of these non-linear ODEs reproduce the qualitative behaviour found for the PDEs, including flipping of polarity after a prolonged grand minimum. Thus we can be confident that these patterns of behaviour are robust, and will apply to stars that are similar to the Sun.     

Abundances of isotopes in planetary atmospheres

Carbon and oxygen isotopes show no large anomalies on Venus (10–15%) or Mars (<5%); the high value of¹⁵N/¹⁴N found on Mars is explained by non-thermal escape of nitrogen. The isotopes of non-radiogenic noble gases in the atmosphere of Mars exhibit abundance patterns similar to those in the primordial component of meteoritic gases and in the Earth's atmosphere. This implies that gas fractionation took place in the inner solar nebula prior to planet formation. The relatively high value of¹²⁹Xe on Mars emphasizes its deficiency on Earth, implying a difference in accretion histories of volatiles for the two planets. In the outer solar system, we find normal isotope ratios for nitrogen and carbon on Jupiter, and for carbon on Saturn, but precision is low (±15% at best). Controversy exists about the correct value of D/H, with current estimates ranging from 2.3±1.1 to 5.1±0.7×10^–5. Planetary missions planned for the next few years should add considerably to the quantity and quality of these data.Paper presented at the Conference on Protostars and Planets, held at the Planetary Science Institute, University of Arizona, Tucson, Arizona, between January 3 and 7, 1978.     

The Martian paleoclimate and enhanced atmospheric carbon dioxide

Current evidence indicates that the Martian surface is abundant with water presently in the form of ice, while the atmosphere was at one time more massive with a past surface pressure of as much as 1 atm of CO₂. In an attempt to understand the Martian paleoclimate, we have modeled a past CO₂H₂O greenhouse and find global temperatures which are consistent with an earlier presence of liquid surface water, a finding which agrees with the extensive evidence for past fluvial erosion. An important aspect of the CO₂H₂O greenhouse model is the detailed inclusion of CO₂ hot bands. For a surface pressure of 1 atm of CO₂, the present greenhouse model predicts a global mean surface temperature of 294°K, but if the hot bands are excluded, a surface temperature of only 250°K is achieved.     

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.     

The abundances of ammonia in the atmospheres of Jupiter,Saturn, and Titan

An investigation of low-resolution ratio spectra of Jupiter, Saturn, and Titan in the region 5400–6500 Å has permitted new evaluations of ammonia absorption bands. The distribution of ammonia over the disk of Jupiter is very inhomogeneous. The carbon-to-nitrogen ratio is distinctly different from the solar value, but this is probably a result of uneven mixing of methane and ammonia, as suggested previously by Kuiper, rather than a compositional anomaly. The abundance of ammonia on Saturn also shows spatial variations, but appears constant in time over a 3-yr period. Two weak, unidentified absorptions were discovered in the red region of Titan's spectrum, in the absence of any detectable ammonia. The new upper limit is ηN < 120 cm-am.     

Mineralization of vestimentiferan tubes at methane seeps on the Congo deep-sea fan

Vestimentiferan tube worms are prominent members of modern methane seep communities and are totally reliant as adults on symbiotic sulphide-oxidizing bacteria for their nutrition. The sulphide is produced in the sediment by a biochemical reaction called the anaerobic oxidation of methane (AOM). A well-studied species from the Gulf of Mexico shows that seep vestimentiferans ‘mine’ sulphide from the sediment using root-like, thin walled, permeable posterior tube extensions, which can also be used to pump sulphate and possibly hydrogen ions from the soft tissue back into the sediment to increase the local rate of AOM. The ‘root-balls’ of exhumed seep vestimentiferans are intimately associated with carbonate nodules, which are a result of AOM. We have studied vestimentiferan specimens and associated carbonates from seeps at the Kouilou pockmark field on the Congo deep-sea fan and find that some of the posterior ‘root’ tubes of living specimens are enclosed with carbonate indurated sediment and other, empty examples are partially or completely replaced by the carbonate mineral aragonite. This replacement occurs from the outside of the tube wall inwards and leaves fine-scale relict textures of the original organic tube wall. The process of mineralization is unknown, but is likely a result of post-mortem microbial decay of the tube wall proteins by microorganisms or the precipitation from locally high flux of AOM derived carbonate ions. The aragonite-replaced tubes from the Kouilou pockmarks show similar features to carbonate tubes in ancient seep deposits and make it more likely that many of these fossil tubes are those of vestimentiferans. These observations have implications for the supposed origination of this group, based on molecular divergence estimates.