Abundances of isotopes in planetary atmospheres

Carbon and oxygen isotopes show no large anomalies on Venus (10–15%) or Mars (<5%); the high value of¹⁵N/¹⁴N found on Mars is explained by non-thermal escape of nitrogen. The isotopes of non-radiogenic noble gases in the atmosphere of Mars exhibit abundance patterns similar to those in the primordial component of meteoritic gases and in the Earth's atmosphere. This implies that gas fractionation took place in the inner solar nebula prior to planet formation. The relatively high value of¹²⁹Xe on Mars emphasizes its deficiency on Earth, implying a difference in accretion histories of volatiles for the two planets. In the outer solar system, we find normal isotope ratios for nitrogen and carbon on Jupiter, and for carbon on Saturn, but precision is low (±15% at best). Controversy exists about the correct value of D/H, with current estimates ranging from 2.3±1.1 to 5.1±0.7×10^–5. Planetary missions planned for the next few years should add considerably to the quantity and quality of these data.Paper presented at the Conference on Protostars and Planets, held at the Planetary Science Institute, University of Arizona, Tucson, Arizona, between January 3 and 7, 1978.     

Will climate change exacerbate water stress in Central Asia?

Millions of people in the geopolitically important region of Central Asia depend on water from snow- and glacier-melt driven international rivers, most of all the Syr Darya and Amu Darya. The riparian countries of these rivers have experienced recurring water allocation conflicts ever since the Soviet Union collapsed. Will climate change exacerbate water stress and thus conflicts? We have developed a coupled climate, land-ice and rainfall-runoff model for the Syr Darya to quantify impacts and show that climatic changes are likely to have consequences on runoff seasonality due to earlier snow-melt. This will increase water stress in unregulated catchments because less water will be available for irrigation in the summer months. Threats from geohazards, above all glacier lake outbursts, are likely to increase as well. The area at highest risk is the densely populated, agriculturally productive, and politically unstable Fergana Valley. Targeted infrastructural developments will be required in the region. If the current mismanagement of water and energy resources can be replaced with more effective resource allocation mechanisms through the strengthening of transboundary institutions, Central Asia will be able to successfully address these future climate-related challenges.     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Revising the paradigm of tidal analysis – the uses of non-stationary data

Surface elevation and current records contain non-tidal variance, often dismissed as noise. The processes responsible for the non-tidal component may also modulate the tidal signal, altering its strength and frequency structure. Because of their manner of generation and propagation, internal tides are inherently irregular. The non-stationary character of these and other tidal processes provides an integral and useful property of tidal records, because it provides an opportunity to obtain insights into tidal dynamics and the interaction of tidal and non-tidal processes. It is, moreover, productive to use multiple approaches in analyzing coastal and estuarine tidal processes so that both the time-varying and average frequency content are determined. Only by confronting the causes of non-stationary behaviour in this way can some of the remaining challenges in tidal analysis and prediction be overcome, e.g. shelf and estuarine currents, river tides, internal tides, tide-surge interactions and tidally influenced ecological processes. Several examples illustrate the utility of non-stationary tidal analysis methods.Responsible Editor: Jens Kappenberg     

Travel time based approach for the assessment of vulnerability of karst groundwater: the Transit Time Method

Karst aquifers represent important water resources in many parts of the world. Unfortunately, karst aquifers are characterised by high contamination risks. This paper presents a travel time based method for the estimation of karst groundwater vulnerability. It considers (1) physics-based lateral flow within the uppermost weathered zone (epikarst) in a limestone-dominated region and (2) high velocities of vertical infiltration at discrete infiltration points (e.g. sinkholes) or lines (e.g. dry valleys, faults). Consequently, the Transit Time Method honours the actual flow path within the unsaturated zone of a karst aquifer system. A test site in Northern Jordan was chosen for the demonstration of the assessment technique, i.e. the catchment area of the Qunayyah Spring north of the capital Amman. The results demonstrate that zones of highest vulnerability lie within valleys and nearby main fault zones. It also reveals that regions, categorised as protected areas by other methods due to thick unsaturated zones, contribute to a major degree to the total risk.     

Experimental impact cratering: A summary of the major results of the MEMIN research unit

This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.     

Benchmarking observational uncertainties for hydrology: rainfall,river discharge and water quality

This review and commentary sets out the need for authoritative and concise information on the expected error distributions and magnitudes in observational data. We discuss the necessary components of a benchmark of dominant data uncertainties and the recent developments in hydrology which increase the need for such guidance. We initiate the creation of a catalogue of accessible information on characteristics of data uncertainty for the key hydrological variables of rainfall, river discharge and water quality (suspended solids, phosphorus and nitrogen). This includes demonstration of how uncertainties can be quantified, summarizing current knowledge and the standard quantitative results available. In particular, synthesis of results from multiple studies allows conclusions to be drawn on factors which control the magnitude of data uncertainty and hence improves provision of prior guidance on those uncertainties. Rainfall uncertainties were found to be driven by spatial scale, whereas river discharge uncertainty was dominated by flow condition and gauging method. Water quality variables presented a more complex picture with many component errors. For all variables, it was easy to find examples where relative error magnitudes exceeded 40%. We consider how data uncertainties impact on the interpretation of catchment dynamics, model regionalization and model evaluation. In closing the review, we make recommendations for future research priorities in quantifying data uncertainty and highlight the need for an improved ‘culture of engagement’ with observational uncertainties. Copyright © 2012 John Wiley & Sons, Ltd.     

Comparison of P‐wave attenuation models of wave‐induced flow

Wave‐induced oscillatory fluid flow in the vicinity of inclusions embedded in porous rocks is one of the main causes for P‐wave dispersion and attenuation at seismic frequencies. Hence, the P‐wave velocity depends on wave frequency, porosity, saturation, and other rock parameters. Several analytical models quantify this wave‐induced flow attenuation and result in characteristic velocity–saturation relations. Here, we compare some of these models by analyzing their low‐ and high‐frequency asymptotic behaviours and by applying them to measured velocity–saturation relations. Specifically, the Biot–Rayleigh model considering spherical inclusions embedded in an isotropic rock matrix is compared with White's and Johnson's models of patchy saturation. The modeling of laboratory data for tight sandstone and limestone indicates that, by selecting appropriate inclusion size, the Biot‐Rayleigh predictions are close to the measured values, particularly for intermediate and high water saturations.     

Effect of rod friction on vane shear tests in very soft organic harbour mud

Very soft organic harbour mud is increasingly used as a filling and construction material in harbour construction and reorganization. The undrained shear strength of such soft sediments is the critical geotechnical soil parameter with regard to any specific construction design. Field and laboratory vane shear testing is a standard method to quickly determine this important parameter. So far, the effect of rod friction on vane shear tests in very soft organic soils is unclear. In this study we present results from laboratory experiments on harbour mud from a construction site in northern Germany. Relations among vane and rod geometry, penetration depth, water content, rod friction and undrained shear strength are derived. Based on these relations the influence of rod friction on vane shear test results is investigated. The results indicate that field and laboratory vane shear test measurements may be significantly influenced by rod friction. Methods are proposed to correct for the rod influence, which is shown to increase with rising water contents.