Investigation of hydrochemical characteristics of groundwater from the Cretaceous-Eocene limestone aquifer in southern Ghana and southern Togo using hierarchical cluster analysis

The most relevant controls on the water quality within the Cretaceous-Eocene limestone aquifer of the Keta Basin, Ghana, and the coastal sedimentary basin of Togo were assessed using Q-mode hierarchical cluster analysis (HCA) and mass-balance modelling. The pattern recognition technique of HCA was employed for partitioning hydrochemical data from a total of 65 surface and borehole samples from the study area into water groups. A spatial plot of the water groups consisting of samples from the limestone aquifer shows that the vast majority of samples belonging to the same group are located in close proximity to one another, suggesting the same processes and/or flow paths in the limestone aquifer system. Geochemical reaction models of selected water groups were constructed using PHREEQC-2. The hydrochemical compositions of the water groups and the mass-balance calculations indicate that the dominant processes and reactions responsible for the hydrochemical evolution in the system are: (1) carbonate equilibria, (2) silicate weathering reactions, (3) limited mixing with saline water, and (4) ion exchange. The combined use of HCA and mass-balance modelling has shown to be a useful approach in interpreting groundwater hydrochemistry in an area where large uncertainties exist in the understanding of the groundwater flow system.     

Methodology for the Process Based Acquisition and Assessment of Non-Intended Outputs in the Mining Industry

For the activities of the mining industry land, equipment, material, and energy are used. During operation material and energy flows such as overburden, dead rock, tailings, wastewater, exhaust air, dust, energy, abrasion, coolant and lubricant losses, are released. These released material and energy flows are nearly always without value for the raw material supply chain as they are not production targets. Instead, they have negative effects on the economy and ecology and are, therefore, referred to as ‘non-intended’. The knowledge of the quantities and qualities of these non-intended outputs as a function of the processes and their parameters is the basis for technical and economical measures. A methodology for the acquisition and assessment of the material and energy flows in the mining industry was developed and tested at the Technical University Berlin, Germany. For that purpose and based on a system analysis in different mines, all relevant material and energy flows were assigned to individual processes. Causal relationships, possible interactions, quantities, and qualities were examined as functions of system parameters. Finally, a technical and economic evaluation was performed.     

One-phase-low-pH enzyme induced carbonate precipitation (EICP) method for soil improvement

Enzyme induced carbonate precipitation (EICP) is an emerging soil improvement method using free urease enzyme for urea hydrolysis. This method has advantages over the commonly used microbially induced carbonate precipitation (MICP) process as it does not involve issues related to bio-safety. However, in terms of efficiency of calcium carbonate production, EICP is considered lower than that of MICP. In this paper, a high efficiency EICP method is proposed. The key of this new method is to adopt a one-phase injection of low pH solution strategy. In this so-called one-phase-low-pH method, EICP solution consisting of a mixture of urease solution of pH?=?6.5, urea and calcium chloride is injected into soil. The test results have shown that the one-phase-low-pH method can improve significantly the calcium conversion efficiency and the uniformity of calcium carbonate distribution in the sand samples as compared with the conventional two-phase EICP method. Furthermore, the unconfined compressive strength of sand treated using the one-phase-low-pH method is much higher than that using the two-phase method and the one-phase-low-pH method is also simpler and more efficient as it involves less number of injections.

     

Using Geomorphological Indicators to Predict Earthquake Magnitude (MOb‒Max): A Case Study from Cao Bang Province and Adjasent Areas (Vietnam)

Geotectonics - This paper presents analysis of geomorphological indices for predicting the maximum observed earthquake (MOb?Max) in research region, conducted in three steps: (i)...     

Description of a complex,rainfall-induced landslide within a multi-stage three-dimensional model

Natural Hazards - The mechanical processes involved in movements of earth or rock masses under the effect of gravity—a landslide—may include several phases where the failure of one...     

Methodology for evaluation of potential sites for large-scale riverbank filtration

Despite being a simple and inexpensive pretreatment technology, the cost-effectiveness of riverbank filtration (RBF) depends on complex hydrogeological and hydrogeochemical variables. One of the most important issues for decision makers regarding RBF is optimal site selection. Therefore, a methodology for multicriteria site evaluation for large-scale RBF schemes is offered. The methodology is primarily designed as a prescreening method, applied over a wide area, but can also serve as a guide for evaluating individual RBF sites. To facilitate further discussion about improvements on the methodology, the reasoning behind each relevant factor and its weight in the evaluation is presented. The methodology is divided into three sequential steps through which a site can be assessed. The first step is to establish the existence of connectivity between the river and aquifer. This is termed the essential criterion, and is a binary determination of site suitability. If the site is determined to be suitable, it is then assessed via a set of quantity criteria, which measure the aquifer capacity and amount of bank filtrate that can be effectively abstracted. Lastly, water quality criteria are assessed by means of surface-water and groundwater quality. The quantity and quality criteria form a result expressed as the site suitability index (SSI), which ranges from 0 to 1, where higher scores represent increased suitability. Finally, the methodology is applied to evaluate existing sites of large-scale RBF application as a demonstration of its applicability. The success of these existing sites is compared to the calculated SSI value and discussed.

     

Continental Scale Hydrostratigraphy: Comparing Geologically Informed Data Products to Analytical Solutions

This study synthesizes two different methods for estimating hydraulic conductivity (K) at large scales. We derive analytical approaches that estimate K and apply them to the contiguous United States. We then compare these analytical approaches to three-dimensional, national gridded K data products and three transmissivity (T) data products developed from publicly available sources. We evaluate these data products using multiple approaches: comparing their statistics qualitatively and quantitatively and with hydrologic model simulations. Some of these datasets were used as inputs for an integrated hydrologic model of the Upper Colorado River Basin and the comparison of the results with observations was used to further evaluate the K data products. Simulated average daily streamflow was compared to daily flow data from 10 USGS stream gages in the domain, and annually averaged simulated groundwater depths are compared to observations from nearly 2000 monitoring wells. We find streamflow predictions from analytically informed simulations to be similar in relative bias and Spearman's rho to the geologically informed simulations. R-squared values for groundwater depth predictions are close between the best performing analytically and geologically informed simulations at 0.68 and 0.70 respectively, with RMSE values under 10 m. We also show that the analytical approach derived by this study produces estimates of K that are similar in spatial distribution, standard deviation, mean value, and modeling performance to geologically-informed estimates. The results of this work are used to inform a follow-on study that tests additional data-driven approaches in multiple basins within the contiguous United States.     

Sediment delivery,resuspension, and transport in two contrasting canyon environments in the southwest Gulf of Lions

Multiple canyons incise the continental slope at the seaward edge of the continental shelf in the Gulf of Lions and are actively involved in the transfer of sediment from shelf to deep sea. Two canyons in the southwest region of the Gulf of Lions, Lacaze-Duthiers Canyon and Cap de Creus Canyon, were instrumented with bottom-boundary-layer tripods in their heads to evaluate the processes involved in sediment delivery, resuspension and transport. In both canyons, intense cold, dense-water flows carry sediment across the slope. In the Lacaze-Duthiers canyon head (located ∼35 km from the shoreline), dense-water cascading into the canyon was episodic. Currents were highly variable in the canyon head, and responded to interactions between the along-slope Northern Current and the sharp walls of the canyon. Inertial and other high-frequency fluctuations were associated with suspended-sediment concentrations of ∼5 mg/l. In Cap de Creus canyon head (located ∼14 km from the shoreline), downslope currents were higher in magnitude and more persistent than in Lacaze-Duthiers canyon head. Greater suspended-sediment concentrations (peaks up to 20 mg/l) were observed in Cap de Creus Canyon due to resuspension of the canyon seabed during dense-water cascading events. The similarities and contrasts between processes in these two canyon heads emphasize the importance of the interaction of currents with sharp canyon bathymetry. The data also suggest that cold, dense-water flows have more potential to carry sediment to the slope on narrow shelves, and may more efficiently transfer that sediment to the deep sea where a smooth transition between shelf and slope exists.     

Simultaneous Organic Matter and Nitrogen Removal from Piggery Slaughterhouse Wastewater Using Bioaugmented Gaslift Membrane Bioreactor

A single bioaugmentation reactor and a side-stream gaslift membrane bioreactor combined with bioaugmentation are conducted to treat real wastewater from a centralized piggery slaughterhouse in Vietnam. The bioaugmented reactor is inoculated with heterotrophic microorganisms (Bacillus sp.) isolated from piggery slaughterhouse wastewater. The results of a single bioaugmentation experiment show high removal efficiency of chemical oxygen demand (COD) (84.8%–97.5%) and total nitrogen (TN) (69.9%–87.2%) at loading rates of 1.28–3.89 and 0.14–0.37 kg m⁻³ d⁻¹, respectively. The combined system demonstrates a significantly higher TN removal efficiency (89.0%–96.1%) (p < 0.001), more stable flux (36.0–38.4 L m⁻² h⁻¹), and transmembrane pressure (0.95–1.05 bar), and better capacity of separation of solid–liquid phases compared to the single bioaugmentation. High COD and TN removal efficiency is possibly due to assimilation and simultaneous nitrification and denitrification processes. The results of this study also indicate the feasibility and propitious efficiency of the bioaugmented gaslift membrane bioreactor for piggery slaughterhouse wastewater treatment.     

Geochemical and geochronological studies of the Muong Hum alkaline granitic pluton from the Phan Si Pan Zone,northwest Vietnam: Implications for petrogenesis and tectonic setting

The Phan Si Pan zone in northwest Vietnam is an important tectonic unit for understanding the geological evolution of the southeast Asian Block. Numerous late Permian A‐type granites outcrop in this zone. In this study, new geochemical and geochronological data derived from the Muong Hum alkaline granitic pluton in the Phan Si Pan zone were investigated for its petrogenesis and tectonic setting. Zircon U–Pb analyses of three samples yielded ²⁰⁶Pb/²³⁸U ages of (251.1 ±3.5) Ma, (251.2 ±3.8) Ma, and (253.9 ±1.5) Ma, respectively, coinciding with the ages of the acid member of magma from Emeishan large igneous province, southwest China. The Muong Hum granite has 10 000 × Ga/Al and A/CNK values of 4.70–4.93 and 0.87–0.90, respectively, as well as negative Eu anomalies. It shows significant depletion of Ba, Sr, Ti, and P, similar to features of A‐type granite. Zircons have positive ε_Hf(t) values (+1.9 to +8.6) and Hf model ages (T_DM1) of 595–846 Ma, originating a mantle source. Compared with the Panzhihua A‐type granite of the southwest China domain and other A‐type plutons of the Phan Si Pan zone, including Ye Yen Sun, Phu Sa Phin, Nam Xe, Tam Duong Phan Si Pan, and Taihe, the geochemical characteristics and zircon Hf isotopic compositions of the Muong Hum granite demonstrate an affinity of mantle magma. It is believed that the Phan Si Pan zone is an important part of Emeishan large igneous province. It was reworked by the Cenozoic Aillaoshan‐Red River shear fault to its present location.