Roughness length in the turbulent Ekman layer above the sea bed

Roughness lengths were determined from average current profiles in the logarithmic boundary layer at a site in the southern North Sea. Grab samples indicated that the bed configuration controlling the bed roughness was unlikely to change even at maximum spring tides, but the measured roughness lengths were found to decrease as the speed of the flow 10 m above the bed increased. This has been qualitatively interpreted in terms of the size of the turbulent eddies within the flow and their effectiveness at “feeling” the size of the elements forming the bed roughness. It is also shown that the dependence of the observed drag coefficient on the Rossby number follows closely the theoretical form when the roughness length decreases with increasing flow speed.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

Preservation conditions and the use of sediment pigments as a tool for recent ecological reconstruction in four Northern European estuaries

Down-core sediment pigment concentrations from four Northern European estuaries were measured using high-performance liquid chromatography (HPLC) to investigate phytoplankton community structure and preservation conditions over the last ca. 100 years where all sites have experienced different levels of eutrophication. Phytoplankton pigments have been shown to be useful biomarkers for phytoplankton community structure and abundance due to their taxonomic specificity. The pigment concentrations and sediment pigment inventory showed large variation between the four sites. Concentrations ranged from more than 6000 nmol/g OC to less than 100 nmol/g OC and the inventory integrated over the top 10 cm from more than 300 nmol/cm² to less than 30 nmol/cm² for total identified pigments. Good pigment preservation in Mariager Fjord (Denmark) reflected the almost permanently anoxic conditions. Pigments in Laajalahti (Finland) showed peak concentrations around the time of highest nitrogen loading events known from historical and modelled records over the past 100 years. In contrast, poor down-core preservation of pigments (especially carotenoids) was observed in the Ems-Dollard (The Netherlands) and Himmerfjärden (Sweden) estuaries. The Ems-Dollard site is an intertidal mudflat that experiences daily exposure to light and air, which enhances pigment degradation. In Himmerfjärden, resuspension is an important process affecting both the sedimentation rate and degradation properties. The different preservation conditions at the four sites were supported by the differences in two degradation indicators; the ratio of pheopigment-a to chlorophyll-a and total carotenoids to total pigments. Class-specific carotenoid pigments represented the dominant algal groups reported from each site, however, no distinct down-core changes in the pigment composition were observed at any of the four sites. This indicated that changes in plankton community structure on the group level have been limited over this time period or masked by low preservation of pigments.     

Dissolved nutrient balance and net ecosystem metabolism in a Mediterranean-climate coastal lagoon: San Diego Bay

The temporal and spatial variability of dissolved inorganic phosphate (DIP), nitrogen (DIN), carbon (DIC) and dissolved organic carbon (DOC) were studied in order to determine the net ecosystem metabolism (NEM) of San Diego Bay (SDB), a Mediterranean-climate lagoon. A series of four sampling campaigns were carried out during the rainy (January 2000) and the dry (August 2000 and May and September 2001) seasons. During the dry season, temperature, salinity and DIP, DIC and DOC concentrations increased from oceanic values in the outer bay to higher values at the innermost end of the bay. DIP, DIC and DOC concentrations showed a clear offset from conservative mixing implying production of these dissolved materials inside the bay. During the rainy season, DIP and DOC increased to the head, whereas salinity decreased toward the mouth due to land runoff and river discharges. The distributions of DIP and DOC also showed a deviation from conservative mixing in this season, implying a net addition of these dissolved materials during estuarine mixing within the bay. Mass balance calculations showed that SDB consistently exported DIP (2.8–9.8 × 10³ mol P d⁻¹), DIC (263–352 × 10³ mol C d⁻¹) and DOC (198–1233 × 10³ mol C d⁻¹), whereas DIN (5.5–18.2 × 10³ mol N d⁻¹) was exported in all samplings except in May 2001 when it was imported (8.6 × 10³ mol N d⁻¹). The DIP, DIC and DOC export rates along with the strong relationship between DIP, DIC or DOC and salinity suggest that intense tidal mixing plays an important role in controlling their distributions and that SDB is a source of nutrients and DOC to the Southern California Bight. Furthermore, NEM ranged from −8.1 ± 1.8 mmol C m⁻² d⁻¹ in September to −13.5 ± 5.8 mmol C m⁻² d⁻¹ in January, highlighting the heterotrophic character of SDB. In order to explain the net heterotrophy of this system, we postulate that phytoplankton-derived particulate organic matter, stimulated by upwelling processes in the adjacent coastal waters, is transported into the bay, retained and then remineralized within the system. Our results were compared with those reported for the heterotrophic hypersaline coastal lagoons located in the semi-arid coast of California–Baja California, and with those autotrophic hypersaline systems found in the semi-arid areas of Australia. We point out that the balance between autotrophy and heterotrophy in inverse estuaries is dependent on net external inputs of either inorganic nutrients or organic matter as it has been indicated for positive estuaries.     

Performance efficiency of swim fins

Design improvements on swim fins are most difficult, if not impossible, to assess quantitatively by swimmers alone. In order to make reliable measurements of swim fin performance, an instrumented mechanical swimming device was developed and operated in a water tank. Using this facility, the performance of the more popular conventional fins and that of a new design concept were evaluated. The comparative performance of the various fins was correlated with their physical characteristics.     

Physiography of the Exmouth and Scott Plateaus,Western Australia,and adjacent northeast Wharton Basin

The continental margin of Western Australia is a rifted or “Atlantic”-type margin, with a complex physiography. The margin comprises a shelf, an upper and lower continental slope, marginal plateaus, a continental rise, and rise or lower slope foothills. Notches or terraces on the shelf reflect pre-Holocene deposition of prograded sediment, whose seaward limit was determined by variations in relative sea level, wave energy, and sediment size and volume. The upper continental slope has four physiographic forms: convex, due to sediment outbuilding (progradation) over a subsiding marginal plateau; scarped, due to erosion of convex slopes; stepped, due to deposition at the base of a scarped slope; and smooth, due to progradation of an upper slope in the absence of a marginal plateau. Lying at the same level as the upper/lower slope boundary are two extensive marginal plateaus: Exmouth and Scott. They represent continental crust which subsided after continental rupture by sea-floor spreading. Differential subsidence, probably along faults, gave rise to the various physiographic features of the plateaus. The deep lower continental slope is broken into straight northeasterly-trending segments, that parallel the Upper Jurassic/Lower Cretaceous rift axis, and northwesterly-trending segments that parallel the transform direction. The trends of the slope foothills are subparallel to the rift direction. The four abyssal plains of the region (Perth, Cuvier, Gascoyne and Argo) indicate a long history of subsidence and sedimentation on Upper Jurassic/Lower Cretaceous oceanic crust.     

Facies distribution and dissolution depths of surface sediment components from the Vema channel and the Rio Grande rise (southwest Atlantic Ocean)

Surface sediments from the Vema channel and from the Rio Grande rise (western extremity) contain less calcareous fossils with increasing water depth. The pteropodal (aragonite) lysocline corresponds to the 3200-m isobath. The pteropodal compensation depth is found above the lower boundary of the North Atlantic Deep Water: 3500 m. The planktonic foraminiferal lysocline (4050 m) seems to be very close to the abyssal thermocline and is therefore here the upper limit of the Antarctic Bottom Water. The foraminiferal and the coccolith compensation depths seem to coincide: 4500 m. Distribution and dissolution of calcareous sediment components are the same all around the western extremity of the Rio Grande rise (southern, western and northern flanks).     

A free air gravity anomaly contour map of the Irish continental margin

Compilation of currently-available gravity data permits the construction of a free-air anomaly contour map of the continental margin west of Ireland (51–54 N). Major elements in the structure of the margin, previously delineated on the basis of seismic reflection and magnetic surveys, are clearly seen on the FAA contour map, notably the Porcupine Seabight Trough, and Porcupine Ridge. However, contrary to earlier ideas, the gravity data imply that the Seabight Trough extends northwards onto the Slyne Ridge; and the Slyne Trough, formerly regarded as northeasterly prolongation of the Seabight Trough, appears to be a discrete, fault-bounded, feature separated from the latter by a basement ridge. East-west gravity profiles are modelled in terms of thinned crust with the Moho at a minimum depth of 15 km beneath the axis of the Seabight Trough. The models tend to support hypotheses invoking formation of the Seabight Trough by simple westward translation of Porcupine Ridge with respect to the Irish Mainland.     

Improved in situ gamma-ray transmission densitometer for marine sediments

The first-generation University of Illinois gamma-ray transmission densitometer, designed for the in situ measurement of sediment bulk density, was modified by incorporating in the detector probe (1) an Americium-241 alpha particle pulser and an anti-walk gain stabilization control to maintain better temperature stability and (2) a small power supply and a IC preamplifier to eliminate the need for a high-voltage coaxial cable between the detector and external signal conditioning electronics package. This second-generation Lehigh University system has been successfully deployed since 1971 in routine use from ships and submersibles in the Atlantic and Pacific Oceans and the Gulf of Mexico. Results are presented of system operations to (1) measure bulk density over the range of 1.2–1.8 Mg/m³ in the Hudson Canyon, (2) penetrate 1.9 m into the seafloor in the San Diego trough and, (3) be lowered to a water depth of 3.6 km in the Gulf of Mexico.