Experimental constraints on ureilite petrogenesis

This experimental study explores the petrogenesis of ureilites by a partial melting/smelting process. Experiments have been performed over temperature (1150-1280 °C), pressure (5-12.5 MPa), and low oxygen fugacity (graphite-CO gas) conditions appropriate for a hypothetical ureilite parent body ∼200 km in size. Experimental and modeling results indicate that a partial melting/smelting model of ureilite petrogenesis can explain many of the unique characteristics displayed by this meteorite group. Compositional information preserved in the pigeonite-olivine ureilites was used to estimate the composition of melts in equilibrium with the ureilites. The results of 20 experiments saturated with olivine, pyroxene, metal, and liquid with appropriate ureilite compositions are used to calibrate the phase coefficients and pressure-temperature dependence of the smelting reaction. The calibrated coefficients are used to model the behavior of a hypothetical residue that is experiencing fractional smelting. The residue is initially olivine-rich and smelting progressively depletes the olivine content and enriches the pyroxene and metal contents of the residues. The modeled residue composition at 1260 °C best reproduces the trend of ureilite bulk compositions. The model results also indicate that as a ureilite residue undergoes isothermal decompression smelting over a range of temperatures, Ca/Al values and Cr₂O₃ contents are enriched at lower temperatures (below ∼1240 °C) and tend to decrease at higher temperatures. Therefore, fractional smelting can account for the high Ca/Al and Cr₂O₃ wt% values observed in ureilites. We propose that ureilites were generated from an olivine-rich, cpx-bearing residue. Smelting began when the residue was partially melted and contained liquid, olivine, and carbon. These residues experienced varying degrees of fractional smelting to produce the compositional variability observed within the pigeonite-bearing ureilites. Variations in mineral composition, modal proportions, and isotopic signatures are best described by heterogeneous accretion of the ureilite parent body followed by minimal and variable degrees of igneous processing.     

A regional and global analysis of carbon dioxide physiological forcing and its impact on climate

An increase in atmospheric carbon dioxide concentration has both a radiative (greenhouse) effect and a physiological effect on climate. The physiological effect forces climate as plant stomata do not open as wide under enhanced CO₂ levels and this alters the surface energy balance by reducing the evapotranspiration flux to the atmosphere, a process referred to as ‘carbon dioxide physiological forcing’. Here the climate impact of the carbon dioxide physiological forcing is isolated using an ensemble of twelve 5-year experiments with the Met Office Hadley Centre HadCM3LC fully coupled atmosphere–ocean model where atmospheric carbon dioxide levels are instantaneously quadrupled and thereafter held constant. Fast responses (within a few months) to carbon dioxide physiological forcing are analyzed at a global and regional scale. Results show a strong influence of the physiological forcing on the land surface energy budget, hydrological cycle and near surface climate. For example, global precipitation rate reduces by ~3% with significant decreases over most land-regions, mainly from reductions to convective rainfall. This fast hydrological response is still evident after 5 years of model integration. Decreased evapotranspiration over land also leads to land surface warming and a drying of near surface air, both of which lead to significant reductions in near surface relative humidity (~6%) and cloud fraction (~3%). Patterns of fast responses consistently show that results are largest in the Amazon and central African forest, and to a lesser extent in the boreal and temperate forest. Carbon dioxide physiological forcing could be a source of uncertainty in many model predicted quantities, such as climate sensitivity, transient climate response and the hydrological sensitivity. These results highlight the importance of including biological components of the Earth system in climate change studies.     

Interaction-induced star formation in a complete sample of 105 nearby star-forming galaxies

We investigate the clustering properties of a complete sample of 10⁵ star-forming galaxies drawn from the data release 4 (DR4) of the Sloan Digital Sky Survey. On scales less than 100 kpc, the amplitude of the correlation function exhibits a strong dependence on the specific star formation rate (SSFR) of the galaxy. We interpret this as the signature of enhanced star formation induced by tidal interactions. We then explore how the average star formation rate (SFR) in a galaxy is enhanced as the projected separation r _p between the galaxy and its companions decreases. We find that the enhancement strongly depends on r _p, but very weakly on the relative luminosity of the companions. The enhancement is also stronger in low-mass galaxies than in high-mass galaxies. In order to explore whether a tidal interaction is not only sufficient, but also necessary to trigger enhanced star formation in a galaxy, we compute background subtracted neighbour counts for the galaxies in our sample. The average number of close neighbours around galaxies with low to average values of SFR/ M _* is close to zero. At the highest SSFRs, however, more than 40 per cent of the galaxies in our sample have a companion within a projected radius of 100 kpc. Visual inspection of the highest SFR/ M _* galaxies without companions reveals that more than 50 per cent of these are clear interacting or merging systems. We conclude that tidal interactions are the dominant trigger of enhanced star formation in the most strongly star-forming systems. Finally, we find clear evidence that tidal interactions not only lead to enhanced star formation in galaxies, but also cause structural changes such as an increase in concentration.     

Mid-infrared reflectance spectra and optical constants of six iron oxide/oxyhydroxide phases

We have determined the real and imaginary indices of refraction (n and k) for six iron oxide/oxyhydroxide phases—magnetite, maghemite, goethite, lepidocrocite, akaganéite, and ferrihydrite. A single crystal of magnetite was used to derive bulk n and k values from 100-2000 cm⁻¹ (5-100 μm). Synthetic nanocrystalline samples of maghemite, goethite, lepidocrocite, akaganéite, and ferrihydrite were pressed into compact pellets used to determine bulk n and k values from 100-1200 cm⁻¹ (8.33-100 μm). All values of n and k (the optical constants) were determined from specular reflectance spectra acquired at 2 cm⁻¹ spectral sampling using classical Lorentz-Lorenz dispersion theory. In this paper, we present the optical constants of all six minerals and the oscillator parameters with which they were modeled. Use of these optical constants could aid in radiative transfer models of terrestrial dust as well as Mars, the Moon, and airless bodies in the Solar System.     

Constraining provenance,thickness and erosion of nappes using low‐temperature thermochronology: the Northland Allochthon,New Zealand

The Northland Allochthon, an assemblage of Cretaceous–Oligocene sedimentary rocks, was emplaced during the Late Oligocene–earliest Miocene, onto the in situ Mesozoic and early Cenozoic rocks (predominantly Late Eocene–earliest Miocene) in northwestern New Zealand. Using low‐temperature thermochronology, we investigate the sedimentary provenance, burial and erosion histories of the rocks from both the hanging and footwalls of the allochthon. In central Northland (Parua Bay), both the overlying allochthon and underlying Early Miocene autochthon yield detrital zircon and partially reset apatite fission‐track ages that were sourced from the local Jurassic terrane and perhaps Late Cretaceous volcanics; the autochthon contains, additionally, material sourced from Oligocene volcanics. Thermal history modelling indicates that the lower part of the allochthon together with the autochthon was heated to ca. 55–100°C during the Late Oligocene and Early Miocene, most likely due to the burial beneath the overlying nappe sequences. From the Mesozoic basement exposed in eastern Northland, we obtained zircon fission‐track ages tightly bracketed between 153 and 149 Ma; the apatite fission‐track ages on the other hand, generally young towards the northwest, from 129 to 20.9 Ma. Basement thermochronological ages are inverted to simulate the emplacement and later erosion of the Northland Allochthon, using a thermo‐kinematic model coupled with an inversion algorithm. The results suggest that during the Late Oligocene, the nappes in eastern Northland ranged from ca. 4–6‐km thick in the north to zero in the Auckland region (over a distance >200 km). Following the allochthon emplacement, eastern Northland was uplifted and unroofed during the Early Miocene for a period of ca. 1–6 Myr at the rate of 0.1–0.8 km/Myr, leading to rapid erosion of the nappes. Since Middle Miocene, the basement uplift ceased and the erosion of the nappes and the region as a whole slowed down (ca. 0–0.2 km/Myr), implying a decay in the tectonic activity in this region.     

Trace/minor element:calcium ratios in cultured benthic foraminifera. Part I: Inter-species and inter-individual variability

Trace/minor element signatures (D_Cd, D_Ba, D_Mg, and D_Sr) were measured in the tests (shells) of benthic foraminifera cultured in a trace-metal-concentration-controlled system. The culture system was constructed of inert materials and designed to limit microhabitat effects. This system ensured that variation observed in cultured foraminiferal element:calcium (TE/Ca) signatures was due to biologically mediated (vital) effects only. Two species, Bulimina aculeata and Rosalina vilardeboana, reproduced prolifically during two 4-to-8-month culture periods. In every case (i.e., for both species and each element), the inter-individual variability was larger than the analytical precision. Mean (±1 standard deviation) D_E signatures for B. aculeata were: D_Cd: 1.5 ± 0.4, D_Ba × 10: 2.1 ± 0.7, D_Mg × 1000: 0.62 ± 0.15, and D_Sr × 10: 1.5 ± 0.1. Cultured B. aculeata D_Mg, calibrated from culture and core-top (live) field specimens, predicted temperatures within ±2.0 °C. The observed inter-individual variability from culture specimens was as large or larger than comparable results from core-top investigations. R. vilardeboana D_Cd signatures were significantly lower, while D_Ba, D_Mg, and D_Sr signatures were significantly higher than B. aculeata values. Since our culture system minimizes microhabitat variability, the variation in measured TE/Ca ratios suggests that biological processes are a significant factor in inter-individual and inter-species variability. Comparison of cultured and field-collected foraminiferal D_Ba signatures supports previous findings that pore-water chemistry is a major environmental influence on foraminiferal test chemistry.     

Radiometric dating of the Middle Palaeolithic tool industry and associated fauna of Pin Hole Cave,Creswell Crags,England

Uranium-series dating of derived speleothem suggests that the sediments enclosing a Middle Palaeolithic stone artefact assemblage in Pin Hole Cave probably accumulated after about 64 ka, and ¹⁴C dates indicate a likely age of > 40 ka for the large mammal fauna associated with it. Electron spin resonance data from the fauna conform with these age constraints and are consistent with accumulation between 38 and 50 ka. This evidence supports the view that Britain was recolonised by hominids during Oxygen Isotope Stage 3. Stratigraphically higher stone tool industries demonstrate the local presence of both early Upper and late Upper Palaeolithic cultures. © 1998 John Wiley & Sons, Ltd.     

Discriminating sources of PCB contamination in fish on the coastal shelf off San Diego, California (USA)

Management of coastal ecosystems necessitates the evaluation of pollutant loading based on adequate source discrimination. Monitoring of sediments and fish on the shelf off San Diego has shown that some areas on the shelf are contaminated with polychlorinated biphenyls (PCBs). Here, we present an analysis of PCB contamination in fish on the shelf off San Diego designed to discriminate possible sources. The analysis was complicated by the variability of species available for analysis across the shelf, variable affinities of PCBs among species, and non-detects in the data. We utilized survival regression analysis to account for these complications. We also examined spatial patterns of PCBs in bay and offshore sediments and reviewed more than 20 years of influent and effluent data for local wastewater treatment facilities. We conclude that most PCB contamination in shelf sediments and fish is due to the ongoing practice of dumping contaminated sediments dredged from San Diego Bay.     

The interplay between extrinsic and intrinsic controls in determining floodplain wetland characteristics in the South African drylands

Controls on the characteristics of floodplain wetlands in drylands are diverse and may include extrinsic factors such as tectonic activity, lithology and climate, and intrinsic thresholds of channel change. Correct analysis of the interplay between these controls is important for assessing possible channel–floodplain responses to changing environmental conditions. Using analysis of aerial imagery, geological maps and field data, this paper investigates floodplain wetland characteristics in the Tshwane and Pienaars catchments, northern South Africa, and combines the findings with previous research to develop a new conceptual model highlighting the influence of variations in aridity on flow, sediment transport, and channel–floodplain morphology. The Tshwane–Pienaars floodplain wetlands have formed in response to a complex interplay between climatic, lithological, and intrinsic controls. In this semi‐arid setting, net aggradation (alluvium >7 m thick) in the wetlands is promoted by marked downstream declines in discharge and stream power that are related to transmission losses and declining downstream gradients. Consideration of the Tshwane–Pienaars wetlands in their broader catchment and regional context highlights the key influence of climate, and demonstrates how floodplain wetland characteristics vary along a subhumid to semi‐arid climatic gradient. Increasing aridity tends to be associated with a reduction in the ability of rivers to maintain through‐going channels and an increase in the propensity for channel breakdown and floodout formation. Understanding the interplay between climate, hydrology and geomorphology may help to anticipate and manage pathways of floodplain wetland development under future drier, more variable climates, both in South African and other drylands. Copyright © 2016 John Wiley & Sons, Ltd.