Influence of urban expansion on the urban heat island effect in Shanghai

The urban heat island (UHI) effect resulting from rapid urbanization is attracting increasing attention among the global scientific community. This research analyzed the relationship between urban expansion and the UHI effect utilizing an integrated approach, including urban land interpretation and retrieving land surface temperature based on remote sensing, and spatial overlay analysis for revealing the relationship for different time periods between 1984 and 2014 in Shanghai, China. The results show that (1) the spatiotemporal changes in UHI are consistent with the expansion of urban land, and rapid urban expansion leads to an expansion of the UHI, in particular along roadways. (2) The mode of urban expansion is an important factor influencing the UHI effect. Urban sprawl (urban expansion in the edge-expansion way) is a form of typical expansion that leads to the rapid increase in the UHI. When the urban compactness ratio is less than 0.15, a compact design can effectively control the expansion rate of the UHI and mitigate its range of influence and intensity. However, when the urban compactness ratio is greater than 0.15, the urban design has a marked influence on the UHI ratio index: a more compact form produces a stronger UHI effect. So, finding an equilibrium between urban compactness ratio and urban expansion rate is good for effective urban management and planning.     

Effects of experimental warming on soil microbial communities in two contrasting subalpine forest ecosystems,eastern Tibetan Plateau,China

Soil microbial communities are primarily regulated by environmental temperature. Our study investigated the effects of global warming on soil microbial community composition as measured via phospholipid fatty acid (PLFA) analysis and soil chemical characteristics in relation to soil depth in a dragon spruce plantation and a spruce-fir-dominated natural forestin the Eastern Tibetan Plateau. Open-top chambers were utilized to increase the soil and air temperature. Soil samples were collected from the 0-10 cm, 10-20 cm, and 20-30 cm layers after a 4-year warming. Our results showed that the soil microbial community and the contents of TC (Total carbon), TN (Total nitrogen), NO ₃ ^- , and NH ₄ ⁺ responded differently to warming in the two contrasting forests, especially at the 0-10 cm soil depth. Warming increased soil microbial biomass at the 0-20 cm depth of soil in natural forest but reduced it at the 0-10 cm depth ofsoil in the plantation. In contrast, the TC and TN contents were reduced in most soil layers of a natural forest but increased in all of the soil layers of the plantation under warming conditions. This result suggested that the effects of warming on soil microbial community and soil C and N pools would differ according to soil depth and forest types; thus, the two contrasting forests would under go differing changes following the future climate warming in this region.     

Mass-front velocity of dry granular flows influenced by the angle of the slope to the runout plane and particle size gradation

The mass-front velocities of granular flows results from the joint action of particle size gradations and the underlying surfaces.However,because of the complexity of friction during flow movement,details such as the slope-toe impedance effects and momentum-transfer mechanisms have not been completely explained by theoretical analyses,numerical simulations,or field investigations.To study the mass-front velocity of dry granular flows influenced by the angle of the slope to the runout plane and particle size gradations we conducted model experiments that recorded the motion of rapid and long-runout rockslides or avalanches.Flume tests were conducted using slope angles of 25°,35°,45°,and 55° and three particle size gradations.The resulting mass-front motions consisted of three stages:acceleration,velocity maintenance,and deceleration.The existing methods of velocity prediction could not explain the slowing effect of the slope toe or the momentum-transfer steady velocity stage.When the slope angle increased from 25° to 55°,the mass-front velocities dropped significantly to between 44.4% and59.6% of the peak velocities and energy lossesincreased from 69.1% to 83.7% of the initial,respectively.The velocity maintenance stages occurred after the slope-toe and mass-front velocity fluctuations.During this stage,travel distances increased as the angles increased,but the average velocity was greatest at 45°.At a slope angle of 45°,as the median particle size increased,energy loss around the slope toe decreased,the efficiency of momentum transfer increased,and the distance of the velocity maintenance stage increased.We presented an improved average velocity formula for granular flow and a geometrical model of the energy along the flow line.     

Characteristics of viscous debris flow in a drainage channel with an energy dissipation structure

A new type of drainage channel with an energy dissipation structure has been proposed based on previous engineering experiences and practical requirements for hazard mitigation in earthquakeaffected areas. Experimental studies were performed to determine the characteristics of viscous debris flow in a drainage channel of this type with a slope of 15%. The velocity and depth of the viscous debris flow were measured, processed, and subsequently used to characterize the viscous debris flow in the drainage channel. Observations of this experiment showed that the surface of the viscous debris flow in a smooth drainage channel was smoother than that of a similar debris flow passing through the energy dissipation section in a channel of the new type studied here. However, the flow patterns in the two types of channels were similar at other points. These experimental results show that the depth of the viscous debris flow downstream of the energy dissipation structure increased gradually with the length of the energy dissipation structure. In addition, in the smooth channel, the viscous debris-flow velocity downstream of the energy dissipation structure decreased gradually with the length of the energy dissipation structure. Furthermore, the viscous debris-flow depth and velocity were slightly affected by variations in the width of the energy dissipation structure when the channel slope was 15%. Finally, the energy dissipation ratio increased gradually as the length and width of the energy dissipation structure increased; the maximum energy dissipation ratio observed was 62.9% (where B = 0.6 m and L/w = 6.0).     

Livelihood changes and evolution of upland ethnic communities driven by tourism: a case study in Guizhou Province,southwest China

As an effective livelihood approach to alleviate poverty without rural population migration, ethnic tourism has become the primary choice of economic development in ethnic areas worldwide in addition to traditional livelihood approaches. This article applies the theories of livelihood to study the community evolution driven by tourism livelihood and examine three mountainous tourism communities in different stages of tourist area life cycle. Drawing on the methods of GIS spatial analysis, semi-structured interviews and questionnaires, this article proposes a sustainable livelihood framework for ethnic tourism to explore the evolution of ethnic tourism communities by identifying changes in livelihood assets (natural, financial, social, cultural and human capitals) in the process of tourism development. The results show that the development of ethnic tourism has led to changes in the increase of building land, and the diversification of land use functions with a trend of shifting from meeting local villagers' living needs to satisfying tourists, income composition and uneven distribution of tourism income spatially. Ethnic tourism also led to the deterioration of traditional social management structure, collapse of neighboring relationship, the over- commercialization and staged authenticity of ethnic culture, as well as the gradual vanish of agricultural knowledge with a trend of increasing modern business knowledge and higher education. In addition, these changes, involving livelihood assets from natural, economic, human, social and cultural aspects are interrelated and interactive, which form new evolution characters of ethnic community. This study reveals the conflicts over livelihood approaches which have formed new vulnerabilities to impact on sustainable evolution of ethnic communities. This research provides implications for achieving the sustainable development of ethnic communities with the driving force of tourism livelihood.     

Size distributions and source function of sea spray aerosol over the South China Sea

The number concentrations in the radius range of 0.06 – 5 μm of aerosol particles and meteorological parameters were measured on board during a cruise in the South China Sea from August 25 to October 12, 2012. Effective fluxes in the reference height of 10 m were estimated by steady state dry deposition method based on the observed data, and the influences of different air masses on flux were discussed in this paper. The number size distribution was characterized by a bimodal mode, with the average total number concentration of(1.50 ± 0.76)×10~3 cm~(-3). The two mode radii were 0.099 μm and 0.886 μm, both of which were within the scope of accumulation mode. A typical daily average size distribution was compared with that measured in the Bay of Bengal. In the whole radius range, the number concentrations were in agreement with each other; the modes were more distinct in this study than that abtained in the Bay of Bengal. The size distribution of the fluxes was fitted with the sum of log-normal and power-law distribution. The impact of different air masses was mainly on flux magnitude, rather than the shape of spectral distribution. A semiempirical source function that is applicable in the radius range of 0.06 μmr_(80)0.3 μm with the wind speed varying from 1.00 m s~(-1) to 10.00 m s~(-1) was derived.     

Study on biogenic amines in various dry salted fish consumed in China

This study was carried out to investigate the biogenic amines（BAs）, physicochemical property and microorganisms in dry salted fish, a traditional aquatic food consumed in China. Forty three samples of dry salted fish were gathered from retail and wholesale markets and manufacturers, which had been produced in various regions in China. Cadaverine（CAD） and putrescine（PUT） were quantitatively the most common biogenic amines. About 14% of the samples exceeded the histamine content standards established by the FDA and/or EU. The highest histamine content was found in Silver pomfret（Pampus argenteus）(347.79 mg kg^-1). Five of forty three samples exceeded the acceptable content of TYR(100 mg kg^-1), and 23.26% of dried-salted fish contained high contents of biogenic amines(above 600 mg kg^-1). In addition, species, regions, pickling processes and drying methods made the physicochemical property, microorganisms and biogenic amines in dry salted fish to be different to some extents. The total plate count（TPC） was much higher than that of total halophilic bacteria in all samples. The biogenic amines, physicochemical property and microbiological counts exhibited large variations among samples. Furthermore, no significant correlation between biogenic amines and physicochemical property and TPC was observed. This study indicated that dry salted fish may still present healthy risk for BAs, depending on the processing methods, storage conditions among others.     

Preparation of iron phosphate from sludge sourced from the electrocoagulation treatment of source-separated urine

In order to prepare iron phosphate by waste sludge, we report a method for effective utilization of the sludge obtained from the electrocoagulation treatment of source-separated urine. The sludge was dissolved with hydrochloric acid and pretreated with H₂O₂ and Na₃PO₄; finally, NaOH was added to precipitate iron phosphate from the solution. Thermal treatment of the precipitate at 750 °C in air yielded crystalline quartz-like anhydrous FePO₄. The precipitate was characterized by a number of thermal techniques such as thermogravimetry/differential thermal analysis, scanning electron microscopy, and X-ray powder diffraction.     

Impacts of mineralogical compositions on different trapping mechanisms during long-term CO<Subscript>2</Subscript> storage in deep saline aquifers

Deep saline aquifers in sedimentary basins are considered to have the greatest potential for CO₂ geological storage in order to reduce carbon emissions. CO₂ injected into a saline sandstone aquifer tends to migrate upwards toward the caprock because the density of the supercritical CO₂ phase is lower than that of formation water. The accumulated CO₂ in the upper portions of the reservoir gradually dissolves into brine, lowers pH and changes the aqueous complexation, whereby induces mineral alteration. In turn, the mineralogical composition could impose significant effects on the evolution of solution, further on the mineralized CO₂. The high density of aqueous phase will then move downward due to gravity, give rise to “convective mixing,” which facilitate the transformation of CO₂ from the supercritical phase to the aqueous phase and then to the solid phase. In order to determine the impacts of mineralogical compositions on trapping amounts in different mechanisms for CO₂ geological storage, a 2D radial model was developed. The mineralogical composition for the base case was taken from a deep saline formation of the Ordos Basin, China. Three additional models with varying mineralogical compositions were carried out. Results indicate that the mineralogical composition had very obvious effects on different CO₂ trapping mechanisms. Specific to our cases, the dissolution of chlorite provided Mg²⁺ and Fe²⁺ for the formation of secondary carbonate minerals (ankerite, siderite and magnesite). When chlorite was absent in the saline aquifer, the dominant secondary carbon sequestration mineral was dawsonite, and the amount of CO₂ mineral trapping increased with an increase in the concentration of chlorite. After 3000 years, 69.08, 76.93, 83.52 and 87.24 % of the injected CO₂ can be trapped in the solid (mineral) phase, 16.05, 11.86, 8.82 and 6.99 % in the aqueous phase, and 14.87, 11.21, 7.66 and 5.77 % in the gas phase for Case 1 through 4, respectively.