Carbon cycling in a shallow turbid estuary of southeast Texas: The use of plant pigment biomarkers and water quality parameters

Particulate organic carbon (POC), dissolved organic carbon (DOC), and plant pigments (chlorophylls and carotenoids) were measured approximately bimonthly from March 1992 to October 1993 in the Sabine-Neches estuary (Sabine Lake region), located on the Texas-Louisiana border. High freshwater inflow into this shallow turbid estuary results in the shortest hydraulic residence time (ca. 7 d) of all Texas estuaries (Baskaran et al. in press). Annual averages of chlorophyll-a (3.0 μg l^?1) and particulate organic carbon (1.1 mg l^?1) in the water column were extremely low in comparison to other shallow estuaries. The highest chlorophyll-a concentrations were observed in October 1993, in the mid and lower regions of the estuary, during the lowest river discharge. Zeaxanthin and fucoxanthin concentrations suggested that much of the chlorophyll-a during this low flow period was represented by cyanobacteria and diatoms that entered from the Gulf of Mexico. The range of DOC concentrations was generally high (4.4–20.9 mg l^?1) and were significantly correlated with POC, but not with chlorophyll-a concentrations. When total suspended particulate (TSP) concentrations were below 20 to 30 mg l^?1, there were significant increases in %POC and %PON of the TSP. The unusually high POC: chlorophyll-a ratios (highest value of 1423) suggested that much of the POC contained low concentrations of chlorophyll-a that had degraded during transport from wetlands in the Sabine and Neches rivers. Based on these data, this estuary can be characterized as a predominantly heterotrophic system, with low light penetrance, short particle-residence times, high DOC, and low inputs from autochthonous carbon sources.     

Short contribution: Buried Canopic channel identified near Egypt's Nile delta coast with radar (SRTM) imagery

Shuttle Radar Topography Mission (SRTM) data, with ground‐based geologic investigations, define the geographic position of the relict Canopic channel in Egypt's NW Nile delta. Two sinuous channel segments south of Abu Qir Bay are observed on a radar image: a more sinuous trace (36 km in length) west of Idku lagoon, and an eastern one (˜20 km), reaching the lagoon's southeast corner. Sediment cores recovered along channel traces show sand‐rich deposits (to > 4 m thick) beneath the surface, in contrast with silty muds in areas away from channels. Historic and archaeological findings indicate that the Ptolemaic Roman city of Schedia once lay directly along the Canopic that channeled water from the 3rd to 2nd centuries B.C. until ˜5th century A.D., after which Nile water was displaced to the east via Bolbitic and, later, Rosetta branches. Identification of buried, but well‐defined, Canopic channels provides baselines for renewed archaeological exploration in this delta sector. © 2006 Wiley Periodicals, Inc.     

Cryogenic Core Collection (C3) from Unconsolidated Subsurface Media

We evaluated tools and methods for in situ freezing of cores in unconsolidated subsurface media. Our approach, referred to as cryogenic core collection (C₃), has key aspects that include downhole circulation of liquid nitrogen (LN) via a cooling system, strategic use of thermal insulation to focus cooling into the core, and controlling LN back pressure to optimize cooling. Two cooling systems (copper coil and dual‐wall cylinder) are described. For both systems, the time to freeze a single 2.5‐foot (76‐cm) long by 2.5‐inch (63‐mm) diameter core is 5 to 7 min. Frozen core collection rates of about 30 feet/day (10 m/day) were achieved at two field sites, one impacted by petroleum‐based light nonaqueous phase liquids (LNAPLs) and the other by chlorinated solvents. Merits of C₃ include (1) improved core recovery, (2) potential control of flowing sand, and (3) improved preservation of critical sediment attributes. Development of the C₃ method creates novel opportunities to characterize sediment with respect to physical, chemical, and biological properties. For example, we were able to resolve water, LNAPL, and gas saturations above and below the water table. By eliminating drainage of water, gas and LNAPL saturations in the range of 6 to 23% and 1 to 3% of pore space, respectively, were measured in LNAPL‐impacted intervals below the water table.     

B and Li isotopes as intrinsic tracers for injection tests in aquifer storage and recovery systems

Boron and Li isotopes have been tested as environmental tracers of treated sewage injected into a sandy aquifer (Shafdan reclamation project, Israel). During a 38 days injection test in a newly dug injection well, a conservative artificial tracer (Br⁻) was monitored together with δ¹¹B and δ⁷Li in the injectate, in the unsaturated soil zone (porous cup) and an observation well in the aquifer. In spite of B and Li concentrations in the injectate close to background values, significant shifts of the isotope signatures could be observed over the duration of the injection test. Boron isotope ratios show a breakthrough curve delayed with respect to Br⁻ breakthrough due to some reversible sorption on the aquifer material. No isotope fractionation was observed in the unsaturated or the saturated zone so that B isotopes can be considered as conservative in the investigated part of the aquifer system. Lithium isotopes are strongly fractionated, probably due to sorption processes. Lithium concentrations point to a Li sink in the system, δ⁷Li values vary strongly with a tendency of ⁷Li depletion in the liquid phase over the duration of the experiment. This is opposite to the expected preferential sorption of ⁶Li onto clay minerals. Boron isotopes reveals a valuable tracer of artificial recharge of freshwaters derived from treated sewage, both for short term tracer tests and for long-term monitoring of artificial recharge, even if in aquifers with higher clay contents, sorption-linked isotope fractionation cannot be excluded. More data are needed on Li isotope fractionation in natural groundwater systems to assess the potential of this tracer as monitoring tool.     

COUNTERURBANIZATION IN THE FEDERAL REPUBLIC OF GERMANY*

Since Berry argued in 1976 that counterurbanization had replaced urbanization in the U.S., a debate has ensued as to whether the phenomenon also exists in Western Europe. Proponents of a developmental theory of counterurbanization contend that the phenomenon should be evident in countries which have achieved a very high level of socioeconomic development, including the Federal Republic of Germany (FRG). Most of the German and English language literature on the topic suggests the contrary for the FRG. Here urbanization and counterurbanization are restricted to specific geographic meanings, i.e., spatial agglomeration and deglomeration. Results from four interrelated tests show a trend toward counterurbanization evident as early as the 1960s in the post-war regional demographic data of the FRG.     

The influence of floodplain geohydrology on the distribution of Sarcocornia pillansii in the Olifants Estuary on the West Coast, South Africa

The distribution of Sarcocornia pillansii (Moss) A.J. Scott was determined by water-table depth and electrical conductivity (EC) of the groundwater. Where the groundwater was accessible (<1.5 m) and had a low EC (<80 mS cm⁻¹), S. pillansii extended its roots down to the water-table where a suitable water potential gradient was shown to exist between the soil and roots. In areas where the groundwater was too deep and/or hypersaline, the plants grew on hummocks. The unconfined aquifer below the floodplain is linked to the estuary and although diurnal tidal waves were dampened, water-table level fluctuations were recorded between tidal events. The complex geomorphology of the floodplain influences groundwater flow, in turn affecting the distribution of the salt marsh vegetation.     

Hydrodynamics and sediment dynamics in the German Bight. A focus on observations and numerical modelling in the East Frisian Wadden Sea

This work deals with analysis of hydrographic observations and results of numerical simulations. The data base includes acoustic Doppler current profilers (ADCP) observations, continuous measurements on data stations and satellite data originating from the medium resolution imaging spectrometer (MERIS) onboard the European Space Agency (ESA) satellite ENVISAT with a spatial resolution of 300 m. Numerical simulations use nested models with horizontal resolutions ranging from 1 km in the German Bight to 200 m in the East Frisian Wadden Sea coupled with a suspended matter transport model. Modern satellite observations have now a comparable horizontal resolution with high-resolution numerical model of the entire area of the East Frisian Wadden Sea allowing to describe and validate new and so far unknown patterns of sediment distribution. The two data sets are consistent and reveal an oscillatory behaviour of sediment pools to the north of the back-barrier basins and clear propagation patterns of tidally driven suspended particulate matter outflow into the North Sea. The good agreement between observations and simulations is convincing evidence that the model simulates the basic dynamics and sediment transport processes, which motivates its further use in hindcasting, as well as in the initial steps towards forecasting circulation and sediment dynamics in the coastal zone.     

Upscaling permeability for three-dimensional fractured porous rocks with the multiple boundary method

Upscaling permeability of grid blocks is crucial for groundwater models. A novel upscaling method for three-dimensional fractured porous rocks is presented. The objective of the study was to compare this method with the commonly used Oda upscaling method and the volume averaging method. First, the multiple boundary method and its computational framework were defined for three-dimensional stochastic fracture networks. Then, the different upscaling methods were compared for a set of rotated fractures, for tortuous fractures, and for two discrete fracture networks. The results computed by the multiple boundary method are comparable with those of the other two methods and fit best the analytical solution for a set of rotated fractures. The errors in flow rate of the equivalent fracture model decrease when using the multiple boundary method. Furthermore, the errors of the equivalent fracture models increase from well-connected fracture networks to poorly connected ones. Finally, the diagonal components of the equivalent permeability tensors tend to follow a normal or log-normal distribution for the well-connected fracture network model with infinite fracture size. By contrast, they exhibit a power-law distribution for the poorly connected fracture network with multiple scale fractures. The study demonstrates the accuracy and the flexibility of the multiple boundary upscaling concept. This makes it attractive for being incorporated into any existing flow-based upscaling procedures, which helps in reducing the uncertainty of groundwater models.