T-XCO2 stability relations and phase equilibria of a calcic carbonate scapolite

At a total pressure of 5 kb, calcic, Cl-free scapolite (Me₈₃) is stable relative to plagioclase-bearing assemblages at $\text{T ≧ 625°C}$, . With decreasing temperature, scapolite breaks down to plagioclase + calcite. Scapolite is replaced by plagioclase + grossular + cancrinite + CO₂ in the presence of H₂O-rich fluids. The stable coexistence of scapolite and calcite, an assemblage typical of most natural occurrences of calcic scapolite, is limited by the reaction: scapolite + calcite → grossular + cancrinite + CO₂, which occurs at 750°C, X_CO2 = 0.46; 700°C, X_CO2 = 0.33; 650°C, X_CO2 = 0.18, for the chosen bulk composition.Generalization of the experimental results to encompass the complete range of fully carbonated scapolite compositions indicates that mizzonite (Me₇₅) has the largest T-X_CO2 stability field. For scapolite more calcic than mizzonite, stable growth is restricted to conditions of increasingly higher temperature and X_CO2.The experimental results are consistent with various petrologic features of scapolite-bearing rocks, particularly scapolite-clinopyroxene granulites, and indicate that such rocks were formed in the presence of CO₂-rich fluids.     

Na2O solubility in CaO-MgO-SiO2 melts

The sodium solubility in silicate melts in the CaO-MgO-SiO₂ (CMS) system at 1400 °C has been measured by using a closed thermochemical reactor designed to control alkali metal activity. In this reactor, Na_(g) evaporation from a Na₂O-xSiO₂ melt imposes an alkali metal vapor pressure in equilibrium with the molten silicate samples. Because of equilibrium conditions in the reactor, the activity of sodium-metal oxide in the molten samples is the same as that of the source, i.e., aNa₂O_(sample) = aNa₂O_(source). This design also allows to determine the sodium oxide activity coefficient in the samples. Thirty-three different CMS compositions were studied. The results show that the amount of sodium entering from the gas phase (i.e., Na₂O solubility) is strongly sensitive to silica content of the melt and, to a lesser extent, the relative amounts of CaO and MgO. Despite the large range of tested melt compositions (0 < CaO and MgO < 40; 40 < SiO₂ < 100; in wt%), we found that Na₂O solubility is conveniently modeled as a linear function of the optical basicity (Λ) calculated on a Na-free basis melt composition. In our experiments, γNa₂O_(sample) ranges from 7 × 10⁻⁷ to 5 × 10⁻⁶, indicating a strongly non-ideal behavior of Na₂O solubility in the studied CMS melts (γNa₂O_(sample) ? 1). In addition to showing the effect of sodium on phase relationships in the CMS system, this Na₂O solubility study brings valuable new constraints on how melt structure controls the solubility of Na in the CMS silicate melts. Our results suggest that Na₂O addition causes depolymerization of the melt by preferential breaking of Si-O-Si bonds of the most polymerized tetrahedral sites, mainly Q⁴.     

MINI-MACtm—A new generation dual—Band surveyor

Summary Litton Divisions presently produce both high accuracy GPS surveyors and low—cost GPS navigation sets. Aero Service'sMACROMETER ^R Interferometric Surveyors, have become the standard against which GPS surveying equipment is measured. Litton Aero Products has developed a highly digitized, low costL ₁,C/A code GPS card set. The integration of these technologies had led to the development of a low-cost, high-precision, GPS survey system which can be configured with or without a codelessL ₂ capability. TheMINI-MAC surveying system is the first member of the new generation of GPS survey systems resulting from this joint development. The system design is described in this paper, and initial survey test results using a prototypeMINI-MAC surveying system are presented.     

Longshore variations in nearshore wave processes at magilligan point,northern ireland

Magilligan Point is a recurved cuspate foreland at the mouth of Lough Foyle. Two wave regimes intersect in the estuary mouth and the manner of their interplay controls shoreline changes. Ocean swell waves from the N and NE are refracted around the recurve, losing both height and energy longshore. Width of the surf zone decreases and waves tend to steepen, although both these changes and wave refraction owe something to nearshore geometry. Angle of wave approach becomes more acute and a westerly flowing longshore current moves sand S and SW along the beach. Estuary waves from the S and SW are wind-driven with high-frequencies and steepnesses. They generate a northeasterly current which returns material N, but dies out as the waves become obliterated by nearshore attenuation and breaking of swell. It is possible to identify a time-averaged null-point where shoreline wave power is balanced, although this tends to shift over short periods causing rapid morphological changes. The existence of two independent, but counteractive cells ensures the long-term maintenance of the foreland, without requiring major or continuous supplies of fresh sediment.     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Digital Image Based Approach for Three-Dimensional Mechanical Analysis of Heterogeneous Rocks

Summary This paper presents a digital image based approach for three-dimensional (3-D) numerical simulation and failure analysis of rocks by taking into account the actual 3-D heterogeneity. Digital image techniques are adopted to extract two-dimensional (2-D) material heterogeneity from material surface images. The 2-D image mesostructures are further extrapolated to 3-D cuboid mesostructures by assuming the material surface as a representation of the inner material heterogeneity within a very small depth. The iterative milling and scanning system is set up to generate the 3-D rock mesostructures. A Hong Kong granite specimen is used as an example to demonstrate the procedure of 3-D mesostructure establishment. The mechanical responses and failure process under the conventional Brazilian tensile test condition are examined through numerical analyses. The stress distribution, crack propagation process and failure model of heterogeneous material cases are simulated with a finite difference software. The numerical results indicate that material heterogeneity plays an important role in determining the failure behavior of rocks under external loading.     

Nowcasting with INCA During SNOW-V10

A Central-European nowcasting system which has been developed for use in mountainous terrain is tested in the Whistler/Vancouver area as part of the SNOW-V10 experiment. The integrated nowcasting through comprehensive analysis system provides hourly updated gridded forecasts of temperature, humidity, and wind, as well as precipitation forecasts which are updated every 15 min. It is based on numerical weather prediction (NWP) output and real-time surface weather station and radar data. Verification of temperature, relative humidity, and wind against surface stations shows that forecast errors are significantly reduced in the nowcasting range compared to those of the driving NWP model. The main contribution to the improvement comes from the implicit bias correction due to use of the latest observations. Relative humidity shows the longest lasting effect, with >50 % reduction of mean absolute error up to +4 h. For temperature and wind speed this percentage is reached after +2 and +3 h, respectively. Two cases of precipitation nowcasting are discussed and verified qualitatively.