Benthic indicators: analysis of the threshold values of ecological quality classifications for transitional waters

The effect of the modifications of the threshold values generally adopted for the five EcoQ (Ecological Quality) classes recognized by the European Water Framework Directive (WFD) for the most used benthic indicators and diversity indicators (AMBI, BENTIX, BOPA, BQI, H', ITI and M-AMBI) were studied to test whether it is possible to obtain the same or similar ecological classifications for transitional waters using these different indicators, and determine whether the current classifications can be improved. The analysis included: (i) the use of indicator equations, (ii) the use of reference indicators, and (iii) the use of indicator distribution laws. These investigations demonstrated that it was impossible to obtain an exact intercalibration of the ecological classifications with the selected indicators. However, some propositions to improve the actual classification were suggested.     

Geodynamic and climate controls in the formation of Mio–Pliocene world-class oxidized cobalt and manganese ores in the Katanga province, DR Congo

The Katanga province, Democratic Republic of Congo, hosts world-class cobalt deposits accounting for ~50% of the world reserves. They originated from sediment-hosted stratiform copper and cobalt sulfide deposits within Neoproterozoic metasedimentary rocks. Heterogenite, the main oxidized cobalt mineral, is concentrated as “cobalt caps” along the top of silicified dolomite inselbergs. The supergene cobalt enrichment process is part of a regional process of residual ore formation that also forms world-class “manganese cap” deposits in western Katanga, i.e., the “black earths” that are exploited by both industrial and artisanal mining. Here, we provide constraints on the genesis and the timing of these deposits. Ar–Ar analyses of oxidized Mn ore and in situ U–Pb SIMS measurements of heterogenite yield Mio–Pliocene ages. The Ar–Ar ages suggest a multi-phase process, starting in the Late Miocene (10–5 Ma), when the metal-rich substratum was exposed to the action of meteoric fluids, due to major regional uplift. Further oxidation took place in the Pliocene (3.7–2.3 Ma) and formed most of the observed deposits under humid conditions: Co- and Mn-caps on metal-rich substrata, and coeval Fe laterites on barren areas. These deposits formed prior to the regional shift toward more arid conditions in Central Africa. Arid conditions still prevailed during the Quaternary and resulted in erosion and valley incision, which dismantled the metal-bearing caps and led to ore accumulation in valleys and along foot slopes.     

Burgundy regional climate change and its potential impact on grapevines

ARPEGE general circulation model simulations were dynamically downscaled by The Weather Research and Forecasting Model (WRF) for the study of climate change and its impact on grapevine growth in Burgundy region in France by the mid twenty-first century. Two time periods were selected: 1970–1979 and 2031–2040. The WRF model driven by ERA-INTERIM reanalysis data was validated against in situ surface temperature observations. The daily maximum and minimum surface temperature (T_max and T_min) were simulated by the WRF model at 8?×?8?km horizontal resolution. The averaged daily T_max for each month during 1970–1979 have good agreement with observations, the averaged daily T_min have a warm bias about 1–2?K. The daily T_max and T_min for each month (domain averaged) during 2031–2040 show a general increase. The largest increment (~3?K) was found in summer. The smallest increments (<1?K) were found in spring and fall. The spatial distribution of temperature increment shows a strong meridional gradient, high in south in summer, reversing in winter. The resulting potential warming rate in summer is equivalent to 4.7?K/century under the IPCC A2 emission scenario. The dynamically downscaled T_max and T_min were used to simulate the grape (Pinot noir grape variety) flowering and véraison dates. For 2031–2040, the projected dates are 8 and 12?days earlier than those during 1970–1979, respectively. The simulated hot days increase more than 50% in the two principal grapevine regions. They show strong impact on Pinot noir development.     

Bounding the time delay between high-energy neutrinos and gravitational-wave transients from gamma-ray bursts

We derive a conservative coincidence time window for joint searches of gravitational-wave (GW) transients and high-energy neutrinos (HENs, with energies ?100 GeV), emitted by gamma-ray bursts (GRBs). The last are among the most interesting astrophysical sources for coincident detections with current and near-future detectors. We take into account a broad range of emission mechanisms. We take the upper limit of GRB durations as the 95% quantile of the T₉₀’s of GRBs observed by BATSE, obtaining a GRB duration upper limit of ∼150 s. Using published results on high-energy (>100 MeV) photon light curves for 8 GRBs detected by Fermi LAT, we verify that most high-energy photons are expected to be observed within the first ∼150 s of the GRB. Taking into account the breakout-time of the relativistic jet produced by the central engine, we allow GW and HEN emission to begin up to 100 s before the onset of observable gamma photon production. Using published precursor time differences, we calculate a time upper bound for precursor activity, obtaining that 95% of precursors occur within ∼250 s prior to the onset of the GRB. Taking the above different processes into account, we arrive at a time window of t_HEN − t_GW ∈ [−500 s, +500 s]. Considering the above processes, an upper bound can also be determined for the expected time window of GW and/or HEN signals coincident with a detected GRB, t_GW − t_GRB ≈ t_HEN − t_GRB ∈ [−350 s, +150 s]. These upper bounds can be used to limit the coincidence time window in multimessenger searches, as well as aiding the interpretation of the times of arrival of measured signals.     

Vertical and meridional distribution of ethane, acetylene and propane in Saturn’s stratosphere from CIRS/Cassini limb observations

Measuring the spatial distribution of chemical compounds in Saturn’s stratosphere is critical to better understand the planet’s photochemistry and dynamics. Here we present an analysis of infrared spectra in the range 600-1400 cm⁻¹ acquired in limb geometry by the Cassini spacecraft between March 2005 and January 2008. We first determine the vertical temperature profiles from 3 to 0.01 hPa, at latitudes ranging from 70°N to 80°S. We infer a similar meridional temperature gradient at 1-2 hPa as in recent previous studies [Fletcher, L.N., Irwin, P.G.J., Teanby, N.A., Orton, G.S., Parrish, P.D., de Kok, R., Howett, C., Calcutt, S.B., Bowles, N., Taylor, F.W., 2007. Icarus 189, 457-478; Howett, C.J.A., Irwin, P.G.J., Teanby, N.A., Simon-Miller, A., Calcutt, S.B., Fletcher, L.N., de Kok, R., 2007. Icarus 190, 556-572]. We then retrieve the vertical profiles of C₂H₆ and C₂H₂ from 3 to 0.01 hPa and of C₃H₈ around 1 hPa. At 1 hPa, the meridional variation of C₂H₂ is found to follow the yearly averaged solar insolation, except for a strong equatorial mole fraction of 8×10^-7, nearly two times higher than expected. This enhancement in abundance can be explained by the descent of hydrocarbon-rich air, with a vertical wind speed at the equator of 0.25±0.1 mm/s at 1 hPa and 0.4±0.15 mm/s at 0.1 hPa. The ethane distribution is relatively uniform at 1 hPa, with only a moderate 25% increase from 35°S to 80°S. Propane is found to increase from north to south by a factor of 1.9, suggesting that its lifetime may be shorter than Saturn’s year at 1 hPa. At high altitudes (1 Pa), C₂H₂ and C₂H₆ abundances depart significantly from the photochemical model predictions of Moses and Greathouse [Moses, J.I., Greathouse, T.K., 2005. J. Geophys. Res. 110, 9007], except at high southern latitudes (62, 70 and 80°S) and near the equator. The observed abundances are found strongly depleted in the 20-40°S region and enhanced in the 20-30°N region, the latter coinciding with the ring’s shadow. We favor a dynamical explanation for these anomalies.     

Fracture in a heterogeneous medium: a network approach

Fracture in a heterogeneous medium is simulated by a network model. Heterogeneity is introduced by randomly distributing an initial population of cracks on a triangular network of bonds. Each ruptured bond represents a crack. External stresses are applied onto the network and the evolution of the crack population is analysed when the stresses are increased. A crack will propagate to an intact bond if the critical crack extension force is reached. This propagation leads to the coalescence of bonds: crack clusters are formed. When their shapes are complex we approximate them by simpler ones to compute a crack extension force. Crack interactions are introduced by adding for a given bond the contributions of all adjacent dusters. By using this kind of approach combining fracture mechanics and network modelling, we are able to simulate the rupture of a rock specimen under compression/ traction or shear stresses and to give some characteristics of the macroscopic fracture.     

Mn-oxide: a major source of easily mobilisable Co and Ni under reducing conditions in New Caledonia FerralsolsLes oxydes de Mn : une source majeure de Co et Ni facilement mobilisables en conditions réductrices dans les Ferralsols de Nouvelle-Calédonie

Chemical and bacterial reduction and dissolution of Fe and Mn-oxide and the concomitant solubilisation of Co and Ni were studied in a surface horizon of a New-Caledonia Ferralsol. Chemical extractions showed that Mn and Co were in a large part associated in Mn-oxides. The main part of Ni was associated with goethite, but a very small fraction was also associated with Mn-oxides. Anaerobic reducing bacterial activity was responsible for Fe solubilisation at a smaller extent than for Mn solubilisation and consequently for associated metal release. Submicroscopic investigations revealed the presence of a Mn-oxide containing Co, Ni and Al, close to a lithiophorite–asbolane mixed-layers Mn-oxide, which can be considered as a main source of easily available metals in this soil. To cite this article: C. Quantin et al., C. R. Geoscience 334 (2002) 273–278.     

Surface-rupturing history of the Bree fault scarp, Roer Valley graben: Evidence for six events since the late Pleistocene

Since 1996 paleoseismological investigations have been used to develop the surface- rupturing history of the Bree fault scarp, the morphologically best-defined segment of the southwestern border fault of the Roer Valley graben in northeastern Belgium. The first studies determined that the escarpment is associated with a surface fault, and they exposed evidence for three surface displacements since about 40 ka BP. The most recent eventprobably occurred between 1000 and 1350 yr cal BP. Geophysical and trenching studies at a new site near the southeastern end of the fault scarp reconfirmed the coincidence of the frontal escarpment with a shallow normal fault, which displaces the Middle Pleistocene `Main Terrace' of the Maas River, as well as overlying coversands of Saalian to late Weichselian age. Different amounts of displacement shown by the two youngest coversand units indicate two discrete faulting events, but primary evidence for the coseismic nature of these events is sparse. Radiocarbon and optically stimulated luminescence dating constrainthe age of these events to the Holocene and between 14.0 ± 2.3 ka BP and 15.8 ± 2.9 ka BP, respectively. In addition, four older surface-rupturing events are inferred from the presence of four wedge-shaped units of reworked Main Terrace deposits that are interbedded with coversand units in the hanging wall of the trench and in shallow boreholes. These wedges are interpreted as colluvial wedges, produced by accelerated slope processes in response torejuvenation of the fault scarp, most probably in a periglacial environment. Luminescence dating indicates that five out of a total of six identified faulting events are younger than 136.6 ± 17.6 ka. The antepenultimate event was the largest faulting event, associated with a total fault displacement in excess of 1 m. Thus, the newly investigated trench site represents the longest and most complete record of surface rupturing recovered so far along the Bree fault scarp. This study also demonstrates the viability of the paleoseismological approach to identify past large earthquakes in areas of present-day moderate to low seismic activity.