The Nucleus Deposit: Superposed Au–Ag–Bi–Cu Mineralization Systems at Freegold Mountain,Yukon, Canada

In this paper we present titanite U–Pb (both single crystal CA ID‐TIMS and in situ LA ICP‐MS) data, coupled with ore and gangue mineralogy and geochemical (both lithogeochemistry and microanalysis) data from the Nucleus Au–Ag–Bi–Cu deposit, in the Yukon (Canada) portion of the Tintina Au province. Arsenic‐bearing Au–Ag–Bi–Cu mineralization at Nucleus consists of two distinct styles of mineralization including: (i) reduced Au skarn and sulfide replacement; and (ii) a relatively shallow‐emplaced (as supported by textures and temperature of formation), vein‐controlled mineralization occurring mainly as veins and veinlets of various shapes (sheeted, single, stockworks, and crustiform), breccias, and disseminations. Whereas Au, Bi, and Cu mineralization from skarn is associated with hydrous retrograde alteration phases (actinolite, ferro‐actinolite, hastingsite, cannilloite, and hornblende), numerous alteration types are associated with the vein‐controlled style of mineralization and these include: biotite, phyllic, argillic, propylitic, carbonate, and quartz (silicification) alterations. The mineralization–alteration processes took place over a wide temperature range that is bracketed between 340 and 568°C, as indicated by chlorite and arsenopyrite geothermometers. The Au‐rich Nucleus deposit is characterized by anomalously high content of As and Bi (as much as 1 %), and whereas Au moderately correlates with Bi (r = 0.40) in the skarn mineralization style (where native Au is spatially associated with native Bi and Bi‐bearing sulfides), the two elements correlate poorly (r = 0.14) in the vein‐controlled type, in which native Bi‐ and Bi‐sulfide‐bearing veins are locally observed. Sphalerite from the vein‐controlled mineralized type is Fe‐rich (9.92–10.54 mol % FeS) indicative of low sulfidation conditions, as well as high temperature, with the latter further supported by arsenopyrite geothermometry (up to 491°C), low Ag content (3–7 wt.%) in Au, and the high gold fineness (926–964). Whereas molybdenite Re–Os ages from quartz‐molybdenite veins range from 75.8 to 76.2 ± 0.3 Ma, titanite from the skarn type mineralization recorded CA ID‐TIMS and LA ICP‐MS U–Pb ages of 182.6 ± 2.4 Ma and 191.0 ± 1.5 Ma, respectively, thus precluding any genetic link between the two spatially associated styles of mineralization from the Nucleus deposit area. The Au–Ag–Bi–Cu Nucleus deposit is therefore regarded as a superposed system in which two mineralization types, without any petrogenetic relationship, overlapped, possibly with remobilization of early‐formed mineralization.     

Review: Impact of underground structures on the flow of urban groundwater

Property economics favours the vertical development of cities but flow of groundwater can be affected by the use of underground space in them. This review article presents the state of the art regarding the impact of disturbances caused by underground structures (tunnels, basements of buildings, deep foundations, etc.) on the groundwater flow in urban aquifers. The structures built in the underground levels of urban areas are presented and organised in terms of their impact on flow: obstacle to the flow or disturbance of the groundwater budget of the flow system. These two types of disturbance are described in relation to the structure area and the urban area. The work reviewed shows, on one hand, the individual impacts of different urban underground structures, and on the other, their cumulative impacts on flow, using real case studies. Lastly, the works are placed in perspective regarding the integration of underground structures with the aim of operational management of an urban aquifer. The literature presents deterministic numerical modelling as a tool capable of contributing to this aim, in that it helps to quantify the effect of an underground infrastructure project on groundwater flow, which is crucial for decision-making processes. It can also be an operational decision-aid tool for choosing construction techniques or for formulating strategies to manage the water resource.     

VIRGO: Experiment for helioseismology and solar irradiance monitoring

The scientific objective of the VIRGO experiment (Variability of solar IRradiance and Gravity Oscillations) is to determine the characteristics of pressure and internal gravity oscillations by observing irradiance and radiance variations, to measure the solar total and spectral irradiance and to quantify their variability over periods of days to the duration of the mission. With these data helioseismological methods can be used to probe the solar interior. Certain characteristics of convection and its interaction with magnetic fields, related to, for example, activity, will be studied from the results of the irradiance monitoring and from the comparison of amplitudes and phases of the oscillations as manifest in brightness from VIRGO, in velocity from GOLF, and in both velocity and continuum intensity from SOI/MDI. The VIRGO experiment contains two different active-cavity radiometers for monitoring the solar constant, two three-channel sunphotometers (SPM) for the measurement of the spectral irradiance at 402, 500 and 862 nm, and a low-resolution imager (LOI) with 12 pixels, for the measurement of the radiance distribution over the solar disk at 500 um. In this paper the scientific objectives of VIRGO are presented, the instruments and the data acquisition and control system are described in detail, and their measured performance is given.died 13 October 1994     

Enrichment of redox-sensitive trace metals (U,V, Mo,As) associated with the late Hauterivian Faraoni oceanic anoxic event

The Faraoni Level is a short-lived oxygen-deficient event that took place during the latest Hauterivian. In order to improve our understanding of the palaeoenvironmental conditions that occurred during this event, we have analysed the contents of several redox-sensitive trace elements (U, V, Mo, As, Co, Cd, Cu, Zn, Ni, Pb, Cr) from bulk limestone samples of late Hauterivian–early Barremian age from three reference sections. U, V, Mo and As show consistent and significant enrichments during the Faraoni event whereas the other redox-sensitive trace elements analysed here are not systematically enriched. In order to explain this discrepant behaviour, we propose that the Faraoni Level was deposited during a period of anoxic conditions near the sediment–water interface. The distinctive peaks in U, V, Mo and As contents are traceable throughout the three studied sections and represent a good correlation tool which helps to identify the Faraoni Level and its equivalents in the western Tethyan realm and outside of the Tethys. For example, a peak in U contents in upper Hauterivian sediments of the northwestern Pacific realm (ODP leg 185, site 1149) may well be an expression of the Faraoni event in this particular basin.     

A spatial analysis of structural controls on Karst groundwater geochemistry at a regional scale

The coupled spatial investigation of the geometrical and geochemical properties of a chalk karstic aquifer provides information on the degree to which geologic structure controls aquifer functioning and groundwater quality. Major ion concentrations in the chalk aquifer of the Haute-Normandie region (France) were measured at a high spatial resolution (more than 100 sampling sites over a 6000 km² area) and mapped. The first observation is a continuity of the geochemical properties, in spite of the karstic properties of the aquifer principal components analysis of geochemical maps revealed two types of spatial distributions: ions with an autochthonous origin (Ca²⁺, HCO₃), and ions with a principally allochthonous origin (Cl⁻, Na⁺, , ). Mg²⁺ was categorised as both autochthonous (chalk dissolution) and allochthonous (brought in by infiltration of Tertiary deposits). To better understand the spatial distribution of the geochemistry, the aquifer geochemistry was compared to the physical properties of the aquifer, in particular aquifer thickness (representing aquifer geometry) and piezometric level (representing aquifer flow). Use of spatial correlation between the geochemical and the geometrical properties provided insight regarding the directional structure of the data and give evidence of directional relations between geochemical and geometrical properties. The degree of mineralisation (principally composed of Ca²⁺ and ions) increased along the direction of flow, corresponding to an increase in chalk dissolution rate along the flowpath. The steepest mineralisation gradients were related to an increase in the Mg/Ca ratio, evidence of longer residence times and corresponding to zones where aquifer flow capacity is limited because of a decrease of the thickness of the flow section (anticlines or faults). These results highlight the dominant role played by the geometry and the structural context in controlling aquifer geochemistry.     

Quality Assessment of the Cobel-Isba Numerical Forecast System of Fog and Low Clouds

Short-term forecasting of fog is a difficult issue which can have a large societal impact. Fog appears in the surface boundary layer and is driven by the interactions between land surface and the lower layers of the atmosphere. These interactions are still not well parameterized in current operational NWP models, and a new methodology based on local observations, an adaptive assimilation scheme and a local numerical model is tested. The proposed numerical forecast method of foggy conditions has been run during three years at Paris-CdG international airport. This test over a long-time period allows an in-depth evaluation of the forecast quality. This study demonstrates that detailed 1-D models, including detailed physical parameterizations and high vertical resolution, can reasonably represent the major features of the life cycle of fog (onset, development and dissipation) up to +6 h. The error on the forecast onset and burn-off time is typically 1 h. The major weakness of the methodology is related to the evolution of low clouds (stratus lowering). Even if the occurrence of fog is well forecasted, the value of the horizontal visibility is only crudely forecasted. Improvements in the microphysical parameterization and in the translation algorithm converting NWP prognostic variables into a corresponding horizontal visibility seems necessary to accurately forecast the value of the visibility.     

The East Caledonian Current: A Case Example for the Intercomparison between AltiKa and In Situ Measurements in a Boundary Current

This paper presents an assessment of SARAL/AltiKa satellite altimeter for the monitoring of a tropical western boundary current in the south-western Pacific Ocean: the East Caledonian Current. We compare surface geostrophic current estimates obtained from two versions of AltiKa along-track sea level height (AVISO 1 Hz and PEACHI 40 Hz) with two kinds of dedicated in situ datasets harvested along the satellite ground tracks: one deep-ocean current-meter mooring deployed in the core of the boundary current and five glider transects. It is concluded that the AltiKa-derived current successfully captures the velocity of the boundary current, with a standard error of 11 cm/s with respect to the in situ data. It also appears important to reference AltiKa sea level anomaly to the latest mean dynamic topography available in our area. Doing so, Ka-band altimetry provides a satisfactory representation of the western boundary current. Thereby, it usefully contributes to observing its variability in such a remote and under-observed ocean region. However, the rather long repeat period of SARAL (35 days) in comparison to the high frequency variability seen in the flow velocity of the boundary current calls for a combined use of SARAL with the other satellite altimetry missions.     

Effect of decompression and suction on macroscopic and microscopic behavior of a clay rock

The goal in this research was to analyze the effects of decompression and suction on the formation of cracks in a clay rock from the Andra (French National Radioactive Waste Management Agency) site at Bure (Meuse–Haute-Marne, France). The article investigates the relationship between the changes in the hydromechanical properties and the changes in microstructure and porosity. Concerning the effect of decompression, at the macroscopic scale, the study highlighted an important effect on the elastic modulus and permeability, but little effect at the microscopic scale except an evolution of mineralogy related to the oxidation of pyrite often present in layers where cracks develop. Concerning the effect of suction, at the macroscopic level, the results showed that, on drying path, the change in the properties of the material was very small, whereas, on wetting path, a large decrease in tensile strength and gas permeability was observed. At the microscopic level, observations with SEM and ESEM, and measurements with MIP, highlighted the evolution of microstructural organization as a function of suction, and the propagation and enlargement of cracks on wetting path, rather than on drying path.