Comparison of statistical algorithms for detecting homogeneous river reaches along a longitudinal continuum

Seven methods designed to delineate homogeneous river segments, belonging to four families, namely — tests of homogeneity, contrast enhancing, spatially constrained classification, and hidden Markov models — are compared, firstly on their principles, then on a case study, and on theoretical templates. These templates contain patterns found in the case study but not considered in the standard assumptions of statistical methods, such as gradients and curvilinear structures. The influence of data resolution, noise and weak satisfaction of the assumptions underlying the methods is investigated. The control of the number of reaches obtained in order to achieve meaningful comparisons is discussed. No method is found that outperforms all the others on all trials. However, the methods with sequential algorithms (keeping at order n + 1 all breakpoints found at order n) fail more often than those running complete optimisation at any order. The Hubert-Kehagias method and Hidden Markov Models are the most successful at identifying subpatterns encapsulated within the templates. Ergodic Hidden Markov Models are, moreover, liable to exhibit transition areas.     

Solar EUV/FUV irradiance variations: analysis and observational strategy

The knowledge of solar extreme and far ultraviolet (EUV) irradiance variations is essential for the characterization of the Earth’s upper atmosphere. For a long time, this knowledge has been based on empirical models, which are themselves based on proxies of the solar activity. However, the accurate modeling and prediction of the Earth’s upper atmosphere necessitate to improve the precision on the irradiance and its variations below about 200 nm. Here, we present a review of recent works made by the authors that aim at quantifying the irradiance variability at these wavelengths, and that lead to new way of monitoring the solar EUV/FUV irradiance spectrum. In more details, it is shown that the quantification of the high level of redundancy in the solar spectrum variability allows to envisage measuring only a small portion of the spectrum without losing essential knowledge. Finally, we discuss what should and could be measured in order to retrieve the solar extreme and far ultraviolet spectrum.     

Assessment of faecal contamination and the relationship between pathogens and faecal bacterial indicators in an estuarine environment (Seine, France)

The Seine estuary, one of the largest estuaries of the European northwest continental shelf, is subjected to numerous anthropogenic influences. Here we present an assessment of the microbial faecal contamination of the estuary water. The most vulnerable areas were defined on the basis of the fluxes of indicator organisms and the occurrence of Salmonella and Cryptosporidium sp. and Giardia sp. (oo)cysts. The microbial quality of the water changes from upstream to downstream: in the upstream area, contamination by faecal-indicator bacteria and Salmonella occurs during periods of high flow; in the urbanized area, mid-way between the uppermost areas of the estuary and its mouth, discharge from a wastewater treatment plant and a tributary degrade water quality; at the estuary mouth, the accumulation of microorganisms attached to particles in the maximum turbidity zone, particularly Clostridium perfringens spores and oocysts of Cryptosporidium, is accompanied by inputs of ThC and Escherichia coli from tributaries. In some areas, significant strong relations are observed between Salmonella, (oo)cysts of protozoan, and levels of faecal indicators.     

A report card and quality indicators for the Seine estuary: from scientific approach to operational tool

The scientific teams from the interdisciplinary Seine-Aval (SA) research program and the SA's operational pole, GIPSA (Groupement d'Intérêt Public Seine-Aval) have worked together to create a report card designed to help the Estuary Council (Conseil de l'Estuaire) revitalize its original functions: maintaining functional links between the various estuarine ecosystems, comprehending and managing the estuary's natural habitats and biological populations, and monitoring and improving the physical-chemical quality of the estuarine waters. The report card will be able to synthesize the information obtained from several system performance variables and available operational indicators. This approach, intended to guide the estuary managers, is the oeuvre of several scientific teams; it is particularly important in the context of the Water Framework Directive because it facilitates the elaboration of a group of relevant indicators, which can then be used as operational tools. A report card will provide decision-makers (e.g., political authorities; national, regional and local institutions and industries) with the key indicators for evaluating the system and predicting changes in terms of selected objectives, such as the preservation and restoration of the estuary's environmental functionalities. The final objective of the research is to choose among the available indicators to approximate potential ecological risks. Integrating the socio-economical data will perhaps lead to setting risk acceptability thresholds for the different uses of the Seine estuary. In the end, collaboration between the scientists, the managers, and the GIPSA operational pole will be essential to produce a viable report card about the environmental status of the Seine estuary. To illustrate the research now under way, this article presents the results for three actions undertaken, concerning: (i) physical indicators (i.e., an inventory of the estuary first as a whole, and then section by section); (ii) benthic indicators (i.e., seven indices which show a moderate EcoQ for the lower part of the estuary); and (iii) a eutrophication indicator (i.e., an indicator for coastal eutrophication potential (ICEP), which helps to limit the nutrient fluxes (N or P) that exceed the silica flux delivered by the Seine network, based on the Redfield ratios for algal propagation).     

Gas segregation in dykes and sills

Many basaltic volcanoes emit a substantial amount of gas over long periods of time while erupting relatively little degassed lava, implying that gas segregation must have occurred in the magmatic system. The geometry and degree of connectivity of the plumbing system of a volcano control the movement of magma in that system and could therefore provide an important control on gas segregation in basaltic magmas. We investigate gas segregation by means of analogue experiments and analytical modelling in a simple geometry consisting of a vertical conduit connected to a horizontal intrusion. In the experiments, degassing is simulated by electrolysis, producing micrometric bubbles in viscous mixtures of water and golden syrup. The presence of exsolved bubbles induces a buoyancy-driven exchange flow between the conduit and the intrusion that leads to gas segregation. Bubbles segregate from the fluid by rising and accumulating as foam at the top of the intrusion, coupled with the accumulation of denser degassed fluid at the base of the intrusion. Steady-state influx of bubbly fluid from the conduit into the intrusion is balanced by outward flux of lighter foam and denser degassed fluid. The length and time scales of this gas segregation are controlled by the rise of bubbles in the horizontal intrusion. Comparison of the gas segregation time scale with that of the cooling and solidification of the intrusion suggests that gas segregation is more efficient in sills (intrusions in a horizontal plane with typical width:length aspect ratio 1:100) than in horizontally-propagating dykes (intrusions in a vertical plane with typical aspect ratio 1:1000), and that this process could be efficient in intermediate as well as basaltic magmas. Our investigation shows that non-vertical elements of the plumbing systems act as strong gas segregators. Gas segregation has also implications for the generation of gas-rich and gas-poor magmas at persistently active basaltic volcanoes. For low magma supply rates, very efficient gas segregation is expected, which induces episodic degassing activity that erupts relatively gas-poor magmas. For higher magma supply rates, gas segregation is expected to be less effective, which leads to stronger explosions that erupt gas-rich as well as gas-poor magmas. These general physical principles can be applied to Stromboli volcano and are shown to be consistent with independent field data. Gas segregation at Stromboli is thought likely to occur in a shallow reservoir of sill-like geometry at 3.5 km depth with exsolved gas bubbles 0.1–1 mm in diameter. Transition between eruptions of gas-poor, high crystallinity magmas and violent explosions that erupt gas-rich, low crystallinity magmas are calculated to occur at a critical magma supply rate of 0.1–1 m³ s^− 1.     

Evidence of methylmercury production and modification of the microbial community structure in estuary sediments contaminated with wastewater treatment plant effluents

The Seine’s estuary (France) waters are the receptacle of effluents originating from wastewater treatment plants (WWTP). In this estuary, mudflats are deposition zones for sediments and their associated contaminants, and play an essential role in the mercury (Hg) biogeochemical cycle mainly due to indigenous microorganisms. Microcosms were used to assess the impact of WWTP-effluents on mercury methylation by monitoring Hg species (total dissolved Hg in porewater, methylmercury and total mercury) and on microbial communities in sediments. After effluent amendment, methylmercury (MeHg) concentrations increased in relation with the total Hg and organic matter content of the WWTP-effluents. A correlation was observed between MeHg and acid-volatile-sulfides concentrations. Quantification of sulfate-reducing microorganisms involved in Hg methylation showed no increase of their abundance but their activity was probably enhanced by the organic matter supplied with the effluents. WWTP-effluent spiking modified the bacterial community fingerprint, mainly influenced by Hg contamination and the organic matter amendment.