Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

Critical notch depths for failure of coastal limestone cliffs: case study at Kuro‐shima Island,Okinawa, Japan

Development of a notch at the base of a cliff reduces cliff stability and often induces a collapse. Pleistocene limestone coastal cliffs of elevation 5?m in Kuro‐shima, Ryukyu Islands, have a prominent notch with a depth of 3–4?m at their bases. Around these coastal cliffs, collapses different from previous studies of cliff collapses in the Ryukyu Islands were found; collapses in Kuro‐shima have a horizontal failure surface. The horizontal failure surface, situated at the height of the failure surface corresponding to the retreat point of the notch, is bounded by vertical joints cutting the whole cliff and the reef flat in front of the cliff. Two types of horizontal failure surface were found, triangular and quadrangular; the distinction appears to depend on the angle between the vertical joints and the front face of the cliff. Prior to collapse, these cliffs appear to have been separated from the adjacent cliffs by the development of vertical joints. Consequently, a cliff that will collapse can be identified in advance; cliff instability is strongly dependent on the development of a notch. To study the effect of notch development on cliff collapse, the notch depth at which collapse occurs was calculated using stability analysis. Instability of a cliff increases with notch depth; collapse occurs at the horizontal failure surface when the ratio of the notch depth to the seaward length of the cliff is approximately 0·5–0·7 for a triangular failure surface, and 0·7–0·9 for a quadrangular failure surface. Copyright © 2010 John Wiley & Sons, Ltd.     

Instability of coral limestone cliffs due to extreme waves

Many boulders are located around the coastal cliffs with height of below 5 m made of coral limestone at Kuro‐shima, Okinawa, Japan. The origin of the boulders appears to be coral limestone cliffs which show developed notches. We undertook stability analysis, involving the wave pressure due to tsunamis, of wave‐induced collapse of the cliffs. We find that extreme waves are capable of inducing cliff collapse, as observed in circumstances where gravity is insufficient. Copyright © 2010 John Wiley and Sons, Ltd.     

Effects of plant roots on the soil erosion rate under simulated rainfall with high kinetic energy

ABSTRACT

This study examined the effects of herbaceous plant roots on interrill erosion using two herbaceous species: clover (Trifolium repens) and oats (Avena sativa). We developed a simple rainfall simulator with relatively high normalized kinetic energy (KE; 23.2 J m^?2 mm^?1). Under simulated rainfall, we measured eroded soil for 42 boxes with various amounts of aboveground and belowground biomass. Aboveground vegetation had a significant effect on the soil erosion rate (SER). We found a clear negative relationship between the percent vegetation cover (c) and the SER. In contrast, plant roots showed no effects on the SER. The SER was not significantly different between the boxes with and without plant roots under similar c conditions. Thus, plant roots could have less of an effect on the SER under higher KE conditions.

Editor M.C. Acreman Associate editor N. Verhoest     

Sediment transport in high‐speed flows over a fixed bed: 2. Particle impacts and abrasion prediction

Single bed load particle impacts were experimentally investigated in supercritical open channel flow over a fixed planar bed of low relative roughness height simulating high‐gradient non‐alluvial mountain streams as well as hydraulic structures. Particle impact characteristics (impact velocity, impact angle, Stokes number, restitution and dynamic friction coefficients) were determined for a wide range of hydraulic parameters and particle properties. Particle impact velocity scaled with the particle velocity, and the vertical particle impact velocity increased with excess transport stage. Particle impact and rebound angles were low and decreased with transport stage. Analysis of the particle impacts with the bed revealed almost no viscous damping effects with high normal restitution coefficients exceeding unity. The normal and resultant Stokes numbers were high and above critical thresholds for viscous damping. These results are attributed to the coherent turbulent structures near the wall region, i.e. bursting motion with ejection and sweep events responsible for turbulence generation and particle transport. The tangential restitution coefficients were slightly below unity and the dynamic friction coefficients were lower than for alluvial bed data, revealing that only a small amount of horizontal energy was transferred to the bed. The abrasion prediction model formed by Sklar and Dietrich in 2004 was revised based on the new equations on vertical impact velocity and hop length covering various bed configurations. The abrasion coefficient k_v was found to be vary around k_v ~ 10⁵ for hard materials (tensile strength f_t > 1 MPa), one order of magnitude lower than the value assumed so far for Sklar and Dietrich's model. Copyright © 2017 John Wiley & Sons, Ltd.     

3-D internal architecture of methane hydrate-bearing turbidite channels in the eastern Nankai Trough, Japan

The reservoir architecture of methane hydrate (MH) bearing turbidite channels in the eastern Nankai Trough, offshore Japan is evaluated using a combination of 3-D seismic and well data. On the 3-D seismic section, the MH-bearing turbidite channels correspond to complex patterns of strong seismic reflectors, which show the 3-D internal architecture of the channel complex. A seismic-sequence stratigraphic analysis reveals that the channel complex can be roughly classified into three different stages of depositional sequence (upper, middle, and lower). Each depositional sequence results in a different depositional system that primarily controls the reservoir architecture of the turbidite channels. To construct a 3-D facies model, the stacking patterns of the turbidite channels are interpreted, and the reservoir heterogeneities of MH-bearing sediments are discussed. The identified channels at the upper sequence around the β1 well exhibit low-sinuosity channels consisting of various channel widths that range from tens to several hundreds of meters. Paleo-current flow directions of the turbidite channels are typically oriented along the north-northeast-to-south-southwest direction. High-amplitude patterns were identified above the channels along the north-to-south and north-northeast-to-south-southeast directions. These roughly coincide with the paleo-current flow of the turbidite channels. An interval velocity using high-density velocity analysis shows that velocity anomalies (>2000 m/s) are found on the northeastern side of the turbidite channels. The depositional stage of the northeastern side of the turbidite channels exhibits slightly older sediment stages than the depositional stages of the remaining channels. Hence, the velocity anomalies of the northeastern side of the channels are related to the different stages of sediment supply, and this may lead to the different reservoir architectures of the turbidite channels.     

Holocene calcrete crust deposits on the moraine of Batura Glacier, northern Pakistan

Abstract   Calcretes can be observed on the surface of old moraines around Batura Glacier in the upper Hunza Valley, Karakoram Mountains, Pakistan. They develop as a calcareous crust cementing small gravels under boulders. In order to understand the genesis of the calcrete crust, a variety of methods were employed: (i) study of mineralogy and geochemistry of a calcrete crust precipitated on the lateral moraine using X-ray diffractometer and electron probe microanalysis; (ii) analysis of solute chemistry of surface water and ice bodies around the Batura Glacier; and (iii) accelerator mass spectrometry ¹⁴C dating of the crust itself. The results indicate that the calcrete crust has definite laminated layers composed of a fine-grain and compact calcite layer, and a mineral fragment layer. The chemical composition of the calcite layer is approximately 60% CaO and 1% MgO. The mineral fragment layer consists of rounded grain materials up to 0.2 mm in diameter. It shows a graded bedding structure with fine grains of quartz, albite and muscovite. Meanwhile, as the Paleozoic Pasu limestone is distributed around the terminal of Batura Glacier, Ca cations dissolve in the melt water of the glacier. Accordingly, the calcrete crust is precipitated by decreases in CO₂ partial pressure from glacier ice and evaporation of the melt water, including high concentration of Ca²⁺ at ephemeral streams and small ponds stagnating between the moraine and glacial ice. On the basis of the AMS ¹⁴C age, the calcrete is considered to have formed approximately 8200 calibrated years bp under the Batura glacial stage.     

Geochemical evolution of historical lavas from Askja Volcano, Iceland: Implications for mechanisms and timescales of magmatic differentiation

The mechanisms and the timescales of magmatic evolution were investigated for historical lavas from the Askja central volcano in the Dyngjufjöll volcanic massif, Iceland, using major and trace element and Sr, Nd, and Pb isotopic data, as well as ²³⁸U-²³⁰Th-²²⁶Ra systematics. Lavas from the volcano show marked compositional variation from magnesian basalt through ferrobasalt to rhyolite. In the magnesian basalt-ferrobasalt suite (5-10 wt% MgO), consisting of lavas older than 1875 A.D., ⁸⁷Sr/⁸⁶Sr increases systematically with increasing SiO₂ content; this suite is suggested to have evolved in a magma chamber located at ∼600 MPa through assimilation and fractional crystallization. On the other hand, in the ferrobasalt-rhyolite suite (1-5 wt% MgO), including 1875 A.D. basalt and rhyolite and 20th century lavas, ⁸⁷Sr/⁸⁶Sr tends to decrease slightly with increasing SiO₂ content. It is suggested that a relatively large magma chamber occupied by ferrobasalt magma was present at ∼100 MPa beneath the Öskjuvatn caldera, and that icelandite and rhyolite magmas were produced by extraction of the less and more evolved interstitial melt, respectively, from the mushy boundary layer along the margin of the ferrobasalt magma chamber, followed by accumulation of the melt to form separate magma bodies. Ferrobasalt and icelandite lavas in the ferrobasalt-rhyolite suite have a significant radioactive disequilibrium in terms of (²²⁶Ra/²³⁰Th), and its systematic decrease with magmatic evolution is considered to reflect aging, along with assimilation and fractional crystallization processes. Using a mass-balance model in which simultaneous fractional crystallization, crustal assimilation, and radioactive decay are taken into account, the timescale for the generation of icelandite magma from ferrobasalt was constrained to be <∼3 kyr which is largely dependent on Ra crystal-melt partition coefficients we used.