Chromium solubility in anhydrous Phase B

The crystal structure and chemical composition of a crystal of (Mg_14?x Cr _x )(Si_5?x Cr _x )O₂₄ (x ≈ 0.30) anhydrous Phase B (Anh-B) synthesized in the model system MgCr₂O₄–Mg₂SiO₄ at 12 GPa and 1600 °C have been investigated. The compound was found to be orthorhombic, space group Pmcb, with lattice parameters a = 5.900(1), b = 14.218(2), c = 10.029(2) Å, V = 841.3(2) Å³ and Z = 2. The structure was refined to R ₁ = 0.065 using 1492 independent reflections. Chromium was found to substitute for both Mg at the M3 site (with a mean bond distance of 2.145 Å) and Si at the octahedral Si1 site (mean bond distance: 1.856 Å), according to the reaction Mg²⁺ + Si⁴⁺ = 2Cr³⁺. Such substitutions cause a reduction in the volume of the M3 site and an increase in the volume of the Si-dominant octahedron with respect to the values typically observed for pure Anh-B and Fe²⁺-bearing Anh-B. Taking into account that Cr³⁺ is not expected to be Jahn–Teller active, it appears that both the Cr³⁺–for–Mg and Cr³⁺–for–Si substitutions in the Anh-B structure decrease the distortion of the octahedra. Electron microprobe analysis gave the Mg_13.66(8)Si_4.70(6)Cr_0.62(4)O₂₄ stoichiometry for the studied phase. The successful synthesis of this phase provides new information for the possible mineral assemblages occurring in the Earth’s deep upper mantle and shed new light on the so-called X discontinuity that has been observed at 275–345 km depth in several subcontinental and subduction zone environments.     

Eddy Field in the Japan Sea Derived from Satellite Altimetric Data

The Japan Sea is one of the eddy-rich areas in the world. Many researchers have described the variability of the eddy field and its structure in the Tsushima Warm Current region. On the other hand, since there are few data covering the northern part of the Japan Sea, we are not able to understand the detailed variability of the eddy field there. The variation of the eddy field in the Japan Sea is investigated using the temporal fluctuations of sea surface height measured by altimetric data from TOPEX/POSEIDON and ERS-2. Tidal signals are eliminated from the altimetric data on the basis of the results of Morimoto et al. (2000). Distributions of sea surface dynamic height are produced by using the optimal interpolation method every month. The distributions warm and cold eddies that we obtained coincide well with the observed isotherms at 100 m depth measured by the Japan Sea National Fisheries Research Institute and the sea surface temperature measured by satellite. There are areas with high RMS variability of temporal fluctuation of sea surface dynamic height in the Yamato Basin, the Ulleung Basin, east of North Korea, the eastern part of the Yamato Rise, the Tsushima Strait and west of Hokkaido. The characteristics of eddy propagation in the high RMS variability regions are examined using a lag correlation analysis. Seasonal variations in the number of warm and cold eddies are also examined.     

Characteristics of crustal structures in the Yamato Basin,sea of Japan,deduced from seismic explorations

Crustal structures around the Yamato Basin in the southeastern Sea of Japan, inferred from recent ocean bottom seismography (OBS) and active-source seismological studies, are reviewed to elucidate various stages of crustal modification involved from rifting in the crust of the surrounding continental arc to the production of oceanic crust in the Yamato Basin of the back-arc basin. The northern, central, and southern areas of the Yamato Basin have crustal thicknesses of approximately 12–16 km, and lowermost crusts with P-wave velocities greater than 7.2 km/s. Very few units have P-wave velocities in the range 5.4–6.0 km/s, which corresponds to the continental upper crust. These findings, combined with previous geochemical analysis of basalt samples, are interpreted to indicate that a thick oceanic crust has been formed in these areas of the basin, and that this oceanic crust has been underplated by mantle-derived magma. In the central Yamato Basin, the original continental crust has been fully breached and oceanic crust has been formed. Conversely, the presence of a unit corresponding to the continental upper crust and the absence of a high-velocity part in the lower crust implies that the southwestern edge of the Yamato Basin has a rifted crust without significant intrusion. The Oki Trough has a crust that is 17–19 km thick with a high-velocity lower crust and a unit corresponding to the continental upper crust. The formation of the Oki Trough resulted from rifting with magmatic intrusion and/or underplating. We interpret these variations in the crustal characteristics of the Yamato Basin area as reflecting various instances of crustal modification by thinning and magmatic intrusion due to back-arc extension, resulting in the production of a thick oceanic crust in the basin.     

Analysis of satellite and model datasets for variability and trends in Arctic snow extent and depth, 1948–2006

This study aims to investigate the spatiotemporal trends in snow depth (SD) and snow cover extent (SCE) for Arctic lands, excluding Greenland, for the period 1948–2006. The investigation not only delineates how the Arctic regions are manifesting significant annual trends in both SD and SCE, but also provides a comprehensive understanding of their historical context. To achieve these objectives, the combined resources of the hydrological and biogeochemical model (CHANGE), National Oceanic and Atmospheric Administration (NOAA) weekly SCE data, and in situ observations of SD were used. Most regions in the Arctic exhibited a significant negative trend in SD over the 59 years of study. The magnitude of the negative trend was stronger in North America than in Eurasia, where the decrease became more significant, starting from the late 1980s, coinciding well with the temperature rise during that time. During the same period, the warming temperature caused a prominent decrease in deeper SDs (i.e., >35 cm), so that the corresponding SCEs exhibited negative anomalies, with the greatest declines being observed at SDs > 55 cm. In contrast, the SCEs for SD ≤ 35 cm showed increased anomalies during the most recent two decades. The increased anomalies signify a sequential result induced by the decrease in the SCEs with deeper SDs, rather than the expansion of snow to snow-free regions. These changes resulted in a northward shift of the shallow SD line, which took place to a highly significant degree in North America. These results suggest that the Arctic SCE and SD will undergo more intense changes in response to the future climate warming.     

Petrographic study of the Miocene Mizunami Group,Central Japan: Detection of unrecognized volcanic activity in the Setouchi Province

A petrographic study of sandstones from the Miocene Mizunami Group in Central Japan has been performed on core samples from a single borehole, in order to evaluate the provenance of the sedimentary rock. Evaluation of the provenance is based on bulk mineral, heavy mineral and plagioclase contents and on whole rock chemical compositions. The sandstones studied are divisible into three types; the first type is characterized by the occurrence of biotite and plagioclase ranging from albite to oligoclase, the second type is characterized by the dominance of amphibole and labradorite with pyroxene (clinopyroxene > orthopyroxene), and the third type is characterized by the dominance of pyroxene (orthopyroxene > clinopyroxene) and andesine with lesser labradorite, bytownite and anorthite. The first type is interpreted to be derived from the basement granite, whereas the others were derived mostly from volcanic ash, judging from their mineral compositions. The volcanic activity that supplied the volcanic ash to the Mizunami Basin occurred in two phases, distinguishable by variations in their mineralogical and geochemical compositions, an indication of change in character of the volcanic activity. This petrographic study of the sandstones in the Mizunami Group suggests that unrecognized volcanic activity occurred around the Mizunami Basin, even though potential provenance of the volcanic ash has not yet been identified.     

Evaluation of the non-hydrostatic stress produced in a multi-anvil high pressure apparatus

Olivine single crystals have been deformed under high confining pressure (P=5?GPa) and temperature (T=1400?°C) conditions in a multi-anvil high pressure apparatus. NaCl, diamond and NaCl+diamond (2:1 by volume) powders were encapsulated along with the olivine single crystals in order to produce a range of stress states. The change of the non-hydrostatic stress transmitted to the olivine samples, enclosed within these three different media, during heating has been evaluated by observation of dislocation microstructure and density. A higher differential stress can be generated with diamond powder (0.1?GPa) than with NaCl powder (0.02?GPa). Although an intermediate differential stress between 0.1?GPa and 0.02?GPa had been expected to be generated using NaCl+diamond powder, the generation of non-hydrostatic stress in the olivine sample was unsuccessful. This may be caused by the fact that compaction (or sintering) proceeded in the capsule throughout the experiments. The most important finding of these experiments is that a constant non-hydrostatic stress can be applied to a sample under very high pressure and temperature conditions within the multi-anvil high pressure apparatus for the duration of the experiment. This approach is therefore suitable for investigating the steady-state rheological properties of mantle minerals at near-mantle conditions.     

Phase transformations in the earth's mantle and subducting slabs: Implications for their compositions, seismic velocity and density structures and dynamics

Abstract Phase transformations in model mantle compositions and those in subducting slabs have been reviewed to a depth of 800 km on the basis of recent high-pressure experimental data. Seismic velocity and density profiles in these compositions have also been calculated using these and other mineral physics data. The nature of the seismic velocity and density profiles calculated for a pyrolite composition was found to generally agree with those determined by seismic observations (e.g. PREM). The locations of the seismic discontinuities at 400 and 670 km correspond almost exactly to the depths where the transformations of the olivine component to denser phases take place. Moreover, the steep gradients in the seismic velocity/density profiles observed between these depths are qualitatively consistent with those expected from the successive transformations in the complementary pyroxene-garnet component in the pyrolite composition. Further, the calculated seismic velocity and density values agree well with those observed in the upper mantle and mantle transition region within the uncertainties attached to these calculations and observations. Pyrolite or peridotite compositions are thus most likely to represent the composition of the mantle above 670 km depth, although some degrees of chemical heterogeneity may exist in the transition region. The observed sharp discontinuous increases of seismic velocities and density at this depth may be attributed either to the phase transformation to a perovskite-bearing assemblage in pyrolite or to chemical composition changes. Density profiles in subducted slabs have been calculated along adequate geotherms assuming that the slabs are composed of the former oceanic crust underlain by a thicker harzburgitic layer. It is shown that the former oceanic crust is substantially less dense than the surrounding pyrolite mantle at depths below 670 km, while it is denser than pyrolite in the upper mantle and the transition region. The subducted former oceanic crust may be trapped in this region, forming a geochemically enriched layer at the upper mantle-lower mantle boundary. Thick and cool slabs may penetrate into the lower mantle, but the chemically derived buoyancy may result in strong deformation and formation of megalith structures around the 670 km seismic discontinuity. These structures are consistent with those detected by recent seismic tomography studies for subduction zones.     

Stability and P–V–T equation of state of KAlSi3O8-hollandite determined by in situ X-ray observations and implications for dynamics of subducted continental crust material

In situ X-ray diffraction measurements of KAlSi₃O₈-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K′_300,0=4. The determined parameters are V _300,0=237.6(2) Å³, K _300,0=183(3) GPa, (?K _T,0/?T) _P =?0.033(2) GPa K^?1, a ₀=3.32(5)×10^?5 K^?1, and b ₀=1.09(1)×10^?8 K^?2, where a ₀ and b ₀ are coefficients describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm^?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm^?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.     

The 10 ka multiple vent pyroclastic eruption sequence at Tongariro Volcanic Centre, Taupo Volcanic Zone, New Zealand: Part 2. Petrological insights into magma storage and transport during regional extension

The six eruption episodes of the 10 ka Pahoka–Mangamate (PM) sequence (see companion paper) occurred over a ?200–400-year period from a 15-km-long zone of multiple vents within the Tongariro Volcanic Centre (TgVC), located at the southern end of the Taupo Volcanic Zone (TVZ). Most TgVC eruptives are plagioclase-dominant pyroxene andesites and dacites, with strongly porphyritic textures indicating their derivation from magmas that ascended slowly and stagnated at shallow depths. In contrast, the PM pyroclastic eruptives show petrographic features (presence of phenocrystic and groundmass hornblende, and the coexistence of olivine and augite without plagioclase during crystallisation of phenocrysts and microphenocrysts) which suggest that their crystallisation occurred at depth. Depths exceeding 8 km are indicated for the dacitic magmas, and >20 km for the andesitic and basaltic andesitic magmas. Other petrographic features (aphyric nature, lack of reaction rims around hornblende, and the common occurrence of skeletal microphenocrystic to groundmass olivine in the andesites and basaltic andesites) suggest the PM magmas ascended rapidly immediately prior to their eruption, without any significant stagnation at shallow depths in the crust. The PM eruptives show three distinct linear trends in many oxide–oxide diagrams, suggesting geochemical division of the six episodes into three chronologically-sequential groups, early, middle and late. Disequilibrium features on a variety of scales (banded pumice, heterogeneous glassy matrix and presence of reversely zoned phenocrysts) suggest that each group contains the mixing products of two end-member magmas. Both of these end-member magmas are clearly different in each of the three groups, showing that the PM magma system was completely renewed at least three times during the eruption sequence. Minor compositional diversity within the eruptives of each group also allows the PM magmas to be distinguished in terms of their source vents. Because petrography suggests that the PM magmas did not stagnate at shallow levels during their ascent, the minor diversity in magmas from different vents indicates that magmas ascended from depth through separate conduits/dikes to erupt at different vents either simultaneously or sequentially. These unique modes of magma transport and eruption support the inferred simultaneous or sequential tapping of small separate magma bodies by regional rifting in the southern Taupo Volcanic Zone during the PM eruption sequence (see companion paper).