Sequence stratigraphy of Holocene incised-valley fills and coastal evolution in the Gulf of Cádiz (southern Spain)

This first sedimentary interpretation of two incised-valley fills in the Gulf of Cádiz (southern Spain), which accumulated during the last fourth-order eustatic cycle in response to fluvial incision, changes of sea level, and correlative deposition, relates the filling of the estuarine basins and their barriers with four regional progradation phases, H₁ to H₄. The cases studied are the wave-dominated Guadalete, and the mixed, tide and wave-dominated Odiel-Tinto estuaries. The sequence boundary is a type-1 surface produced during the lowstand of the Last Glacial period ca. 18 000 ¹⁴C yr BP. No fluvial lowstand deposits were found in the area. Due to rapid transgression the valley fills consist of transgressive and highstand sediments. The maximum landward advance of the estuarine barriers occurred ca. 6500–6000 ¹⁴C yr BP during the maximum of the Flandrian transgression, but there is no evidence of sea level rising appreciably above the present. A large part of the estuaries was filled during H₁ (ca. 6500–4400 ¹⁴C yr BP) but ravinement by shifting tidal inlets destroyed most of the coeval barriers. During the H₂ phase (ca. 4200–2550 ¹⁴C yr BP) sedimentation was favoured by arid conditions and concentrated in the axial estuarine zones and the barriers. Between H₂ and H₃ prevailing winds changed from W to WSW, increasing spit growth to the east and south-east. Progradation of bay-head deltas and flood-plains during H₃ (ca. 2300–800 ¹⁴C yr BP) and H₄ (500 yr ago to the present) further reduced the accommodation space in the largely-filled valleys, and sediment by-passed the estuaries and accumulated in the estuarine barriers as fast-growing spits. Arid conditions and increasing human activity have caused rapid coastal modifications.     

A macroscopic damage‐plastic constitutive law for modeling quasi‐brittle fracture and ductile behavior of concrete

A new phenomenological macroscopic constitutive model for the numerical simulation of quasi‐brittle fracture and ductile concrete behavior, under general triaxial stress conditions, is presented. The model is particularly addressed to simulate a wide range of confinement stress states, as also, to capture the strong influence of the mean stress value in the concrete failure mechanisms. The model is based on a two‐surface damage‐plastic formulation. The mechanical behavior in different domains of the stress space is separately described by means of a quasi‐brittle or ductile material response:

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The 2011 submarine volcanic eruption in El Hierro (Canary Islands)

Forty years after the Teneguía Volcano (La Palma, 1971), a submarine eruption took place off the town of La Restinga, south of El Hierro, the smallest and youngest island of the Canarian Archipelago. Precursors allowed an early detection of the event and its approximate location, suggesting it was submarine. Uncertainties derived from insufficient scientific information available to the authorities during the eruption, leading to disproportionate civil protection measures, which had an impact on the island's economy—based primarily on tourism—while residents experienced extra fear and distress.     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.     

Fluid inclusion studies in datolite of low grade metamorphic origin from a Jurassic pillow basalt series in northeastern Hungary

The Jurassic pillow basalt blocks in the Szarvask? Unit in the SW-Bükk Mountains are incorporated into an accretionary mélange of Cretaceous age which had been displaced from the Dinarides to NE-Hungary during the Alpine-Carpathian collision. The pillow basalt series is a part of an incomplete remnant of an ophiolite-like sequence from which ultramafic units and sheeted dikes are almost completely absent. At the studied Egerbakta quarry, closely packed pillow, pillow fragmented hyaloclastite breccia and peperitic facies of submarine basaltic volcanism were recognized. Peperitic facies was formed by local admixture of unconsolidated siliciclastic sediment into the basaltic lava. Basaltic pillows contains short and thin prehnite-chlorite-carbonate-quartz veins formed during the interaction of seawater with the cooling lava, as well as cross-cutting datolite-prehnite-quartzchlorite-albite bearing veins. Calcite in the short cooling cracks crystallised from upheated seawater at around 160°C temperature and 0.5?C0.6 kbar pressure (water depth of about 5?C6 km). Datolite precipitations in veins can be classified into at least three different textural-morphological types but all of them contain methane bearing primary fluid inclusion assemblages, with variable methane/water ratios, suggesting an inhomogeneous entrapment from a heterogeneous aqueous-carbonic fluid. End member primary fluid inclusions contain aqueous liquid with methane rich vapour phase and apparently methane only inclusions characterized by liquid phase on room temperature. A combination of results from fluid inclusion microthermometry, Raman spectroscopy (used not only for phase identification but also for determination of salinities) and temperatures calculated from chlorite compositions, show that the precipitation of datolite had taken place from low salinity (0.2?C2 NaCl equiv. mass%) aqueous-methane fluids under increasing temperature and pressure (from 160 to 210°C, and from 0.6 to 1.1 kbar) conditions. The elevated pressures and temperatures in comparison to the submarine hydrothermal processes suggest that the datolite bearing mineral parageneses had been formed during the progression of Alpine very low grade metamorphic processes.     

Palaeoshoreline for the Late Cretaceous marine platform in the Iberian Trough (Leonese Area, Spain) deduced from outcrop and subsurface analysis

The location of the Late Cretaceous paleoshoreline in the Leonese Area (Iberian Trough, Spain) has been investigated by seismic analysis through isobath and isopach maps. The succession can be divided into two depositional sequences: DS-1 and DS-2. These sequences are composed of fluvial systems at the base, with paleocurrents that flowed eastward and north-eastward. The DS-1 sequence (Late Albian-Middle Turonian) shows intertidal to subtidal and offshore deposits at the top, while the DS-2 sequence (Late Turonian-Campanian) presents intertidal to subtidal, tidal flat and shallow marine and lacustrine deposits at its top. The stratigraphic cyclicity based on systems tracts shows that these two depositional sequences exhibit remarkable eustatic control. Both sequences start at the base with a significant sedimentary supply from fluvial systems, related to eustatic fall episodes, and conclude at the top with transgressive periods. The evolution of the basin reveals the history of base-level changes and associated shifts in depositional trends during successive stages. The deeper sectors of the DS-1 sequence are located towards the northeastern part of the study area while the proximal portion of the basin-margin is located to the southwest. The paleoshoreline is placed in a direction oriented at 120. The variations in thickness are elongated in orientations between 030 and 050 and are mainly related to paleovalleys and tributary fluvial networks that supply sediment through the shoreline. It is possible that these variations may be related to active synsedimentary faults. Depocenters move toward the northeast and east during the DS-2 sequence while the proximal portion of the basin-margin moves to the southwest. The paleoshoreline has an orientation of 155 direction and moves basinward. The isopach maps show a group of corridors oriented at 130?C140 and 165?C170, interpreted as result of accumulation of sandy bodies such as inter and subtidal bars. The fluvial systems are transversal to the paleoshoreline direction.     

Risk of water pollution due to ash–sludge mixtures: column trials

The purpose of this work was to study the risks of water pollution due to the use of mixtures containing wood ash and sewage sludge. Mixtures including sludge and ash may be recycled as fertilizers, and they are economical as they do not integrate commercial limes, but Escherichia coli counts may keep significantly high in such mixtures, because their pH is not alkaline enough. In view of that, it seems interesting to study the E. coli survival in lixiviate from ash?Csludge mixtures including limes rather than from ash?Csludge mixtures alone. Two kinds of experiments were performed using laboratory column trials under saturated flow conditions. The first experiment investigated the chemical leaching behaviour of a mixture of 70% timber-industry wood ashes and 30% urban sewage sludge (% dry weight) at doses equivalent to 10 and 30?Mg/ha. The second experiment studied the survival of E. coli in lixiviates generated from 30?Mg/ha of a mixture consisting in 75% wood ash, 20% sewage sludge and 5% quicklime (% dry weight). In the first experiment, admixture of the ash and sludge achieved a stabilization of elements such as aluminium, iron, magnesium, nickle, carbon monoxide, cadmium, chromium and molybdenum that reduced their solubility compared with that in the ash or sludge alone. Significant solubilisation of heavy metals was not observed, with overall minor risk of chemical water pollution. In the second experiment, although including quicklime E. coli counts were still detected in the lixiviate, indicating risk of water contamination.     

Implications of chloride-enhanced cadmium uptake in saline agriculture: modeling cadmium uptake by maize and tobacco

Chloride salinity has been strongly related to enhanced cadmium (Cd) uptake by plants due to increased solubility in the soil solution, even in agricultural soil with very low levels of cadmium. This finding is relevant because the cadmium content of food crops is an important concern for human health. Therefore, the aim of this study was to predict and discuss the chlorine-enhanced uptake of cadmium by two common crops: maize and tobacco under ??non-saline?? (1?mM) and ??very strongly saline?? (200?mM) scenarios using a modified ??biotic ligand model?? and datasets from a set of soil and hydroponic experiments. Results indicated that predicted cadmium uptake rates (expressed as cadmium in plant ??mol?m^?2 root) by maize and tobacco plants were consistently higher (54 and 15%, respectively) assuming conditions of ??very strong salinity?? soil compared to the simulated ??non-saline?? soil. In the light of the results of the present research, valuable information is given on modeled cadmium phytoavailability as an indication of the potential risk due to increased cadmium uptake by crops under saline conditions, especially as the enhancement of cadmium uptake in the presence of Cl^? salinity may be a general trend that occurs in many edible crops. The biotic ligand model parameterization applied in the present study attempted to simulate conditions commonly found in natural cadmium and salt-affected soils. However, caution is needed to extrapolate results obtained from these models to real soil conditions.     

Pravčice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering

The dominant factors affecting the development of weathering forms on the Prav?ice Rock Arch (PRA) (Bohemian Switzerland National Park, Czech Republic) are discussed, based on the in situ monitoring of weathering forms, as well as on laboratory studies of materials taken from this site. The in situ monitoring shows the progressive development of distinct weathering forms (delamination of case-hardened rock surfaces, cyclic efflorescence, and granular disintegration of exposed weakly cemented rock mass) in specific portions of the PRA, whose location is controlled by lithology, jointing/local hydrodynamics, and exposure to climatic factors. From the analysis of efflorescence, the dominance of sulphates is evident; particularly of gypsum and alums. However, the synergistic effects of the several salt species (that also include minor nitrates and chlorides) upon the mechanical disintegration of sandstone can be expected.     

A geologic study of the Juan del Grijalva landslide,the most important mass movement during the last century in Mexico

On November 4th 2007, along the Grijalva River in the state of Chiapas, Mexico, has occurred one of the largest landslides ever known. This landslide, known as Juan del Grijalva, destroyed the town of the same name, killing 20 people, and moved 55 million cubic meters of rock and debris down slope to completely block the Grijalva River. In order to understand the characteristics and factors that triggered the Juan del Grijalva landslide, geologic studies were conducted at the site. The results indicate that the landslide was composed of a lithologic sequence of thin-bedded shales and thin to medium-thick-bedded sandstones. This was faulted into several blocks dipping in the same sense as the mass movement. The main triggering factor was the increment of the pore pressure into the lithologic unit due to water saturation after 5 days of heavy rain before the incident. According to records from the last century, the Juan del Grijalva mass movement represents one of the largest mass movements recorded all over the world. The risk conditions of the area after the landslide lead to the rapid construction of an artificial channel to drain the accumulating mass of water upstream and therefore prevent a future catastrophic inundation down stream.