Thermal processing and crystallization of amorphous Mg‐Ca silicates

The structural evolution of sol–gel‐produced amorphous Mg_(x)Ca_(1–x)SiO₃ silicates is investigated. Mid‐IR Fourier transform infrared spectroscopy and synchrotron X‐ray diffraction are used to confirm the amorphous nature of the as‐prepared silicates, while subsequent in situ synchrotron X‐ray powder diffraction measurements are used to study the evolution of crystalline mineral phases as a function of annealing temperature. Multiple silicate phases, including diopside, enstatite, forsterite, and SiO₂, are identified, while Rietveld (i.e., structure) refinement of the diffraction data is used to quantify phase change relationships. Investigated as possible analogs for the refractory dust grain materials likely to have been present in the early solar nebula, the likely relevance of these investigations to the observed silicate compositions of chondritic meteorites and cometary bodies and the processing of their precursor materials is discussed.     

Using remote sensing imagery to determine the impact of land cover changes on potential runoff for the Mid-Cibolo Creek watershed,Texas

Land cover changes within watersheds have the potential to produce dramatic changes in surface hydrology, namely runoff, in the event of storms. The Mid-Cibolo Creek watershed in south-central Texas has experienced extensive land-cover change in the past two decades due to mass residential development and land clearing in the wake of urban growth along the I-35 corridor. This study determined land-cover changes within the basin using supervised classification to classify land cover from LANDSAT images for the years 1986 and 1999. Changes in runoff volume were then calculated using the Soil Conservation Service (SCS) runoff equation for a series of rainfall scenarios. The results showed that an overall increase in impervious cover and decrease in natural vegetative cover has occurred leading to larger runoff volumes for all storm scenarios. The findings are important for watershed scale urban expansion and land clearing practices as current methods suggest that flood risk is increased.     

In situ pore‐pressure measurement in Mississippi delta front sediments

Abstract

A differential piezometer was used to monitor excess pore pressure in the soft clayey seafloor sediments of Block 28, South Pass, Mississippi delta, from September 1975 to March 1976. An ambient excess pore pressure of about 32 kPa was measured at a depth of 6.4 m below the mudline in a water depth of 19 m. Storm‐wave‐generated cyclic fluctuations of ± 4 kPa about the ambient were measured during Hurricane Eloise. Irregular, long‐period, small‐amplitude fluctuations in excess pore pressures persisted for 4 days following the storm. An effective stress analysis was made by using excess pore pressures; in situ field vane‐shear strength, t _fv, measurements; and laboratory wet unit weights measured by Lehigh and NOAA. The effective stress of the SEA‐SWAB site soil was calculated to be zero to a depth of about 6 m, below which it increased to 3.5 kPa at a depth of 15 m. Values of c´ = 4.6 kPa, ?´ = 56°, and T _FV/σ_vo(c/p) =0.1–0.2 were calculated, and it was concluded that these data do not represent the in situ condition of the soil because of the probability that the measured soil properties were affected by the presence of gas. However, it is clear that the soil is significantly underconsolidated.     

Imaging Pathways in Fractured Rock Using Three‐Dimensional Electrical Resistivity Tomography

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three‐dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high‐resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time‐lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone.     

The adoption of agroecology and conventional farming techniques varies with socio-demographic characteristics of small-scale farmers in the Fako and Meme divisions of Cameroon

This study verifies how the adoption of agroecology and conventional farming techniques varies among different socio-economic characteristics. Data acquisition involved the administering of 200 questionnaires and the organization of two focus group discussions (FGDs). The data collected were analysed using: frequencies, means, probabilities, odds and odd ratios. The FGDs were analysed using context analysis. The analyses were performed in SPSS version 20 and Wordstat 7. The results reveal that older respondents tend to adopt conventional farming techniques more than other categories due mainly to inertia or the inability to adapt to changes and their limited propensity to adopt agroecology techniques. Farmers with fewer years of farming experience are more open to agroecology related techniques due to higher inertia while those with more years of farming experience converge with older farmers who tend to prefer conventional farming. The higher the level of income, the more frequent the use of agroecology techniques. Families with more members who live and work on the farm are more open to agroecology; however, there is a limit beyond which the more the number of family members who live and work on the farm, the less the probability of adopting agroecology techniques. The higher the level of education, the greater the propensity to adopt and experiment with agroecology.     

Osmium isotope and highly siderophile element systematics of the lunar crust

Coupled ¹⁸⁷Os/¹⁸⁸Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ± 0.3 pg g^? 1 Os, 1.5 ± 0.6 pg g^? 1 Ir, 6.8 ± 2.7 pg g^? 1 Ru, 16 ± 15 pg g^? 1 Pt, 33 ± 30 pg g^? 1 Pd and 0.29 ± 0.10 pg g^? 1 Re (～ 0.00002 × CI) and Re/Os ratios that were modestly elevated (¹⁸⁷Re/¹⁸⁸Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (～ 0.00007 × CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle–crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments.If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust–mantle concentration ratios (D-values) must be ≤ 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust–mantle HSE partitioning for the Earth and Moon are somewhat surprising. Low HSE abundances in the lunar crust, coupled with estimates of HSE concentrations in the lunar mantle implies there may be a ‘missing component’ of late-accreted materials (as much as 95%) to the Moon if the Earth/Moon mass-flux estimates are correct and terrestrial mantle HSE abundances were established by late accretion.     

Sedimentology of the debris-flow-dominated Warm Spring Canyon alluvial fan, Death Valley, California

Facies analysis of widely distributed exposures of the 32·6 km² and 8·1-km-long Warm Spring Canyon fan, central Death Valley, shows that it has been built principally by debris-flow deposits. These deposits were derived from a mature Panamint Range catchment mostly underlain by Precambrian mudrock, quartzite and dolomite. Stacked, clast-rich and matrix-supported debris-flow lobes of slightly bouldery, muddy, pebble–cobble gravel in beds 20–150 cm thick dominate the fan from apex to toe, accounting for 75–98% of most exposures. Interstratified with the debris flows are less abundant (2–25% of cuts), thinner (5–30 cm) and more discontinuous beds of clast-supported and imbricated, pebble–cobble gravel deposited by overland flows and gully flows. This facies formed by the surficial fine-fraction water winnowing of the debris flows primarily during recessional flood stage of the debris-flow events. Two other facies associations make up a small part of the fan. The incised-channel tract consists of a 250-m-wide clast-supported ribbon of irregularly to thickly bedded, boulder, pebble, cobble gravel nested within debris-flow deposits. This channel fill is oriented generally perpendicular to the Panamint range front. It formed by extensive erosion and winnowing of debris flows deposited within the incised channel, into which all water discharge from the catchment is funnelled. The limited presence of this facies only straddling the present incised channel indicates that this channel overall has maintained a consistent position on the fan except for slight lateral shifts, some caused by strike-slip offset. Fault offset temporarily closed the upper incised channel, causing recessional debris-flow mud to be ponded behind the dam. The other local facies assemblage consists of subrounded to rounded, moderately sorted pebble gravel in low-angle cross-beds that slope both basinwards and fanwards. This gravel was deposited in beachface, backshore and shoreface barrier-spit environments that developed where Lake Manly impinged on the Warm Spring fan during late Pleistocene time. These deposits straddle headcuts into, and were derived from, erosion of the debris-flow deposits. Wave energy sorted finer sediment from the shore zone, concentrated coarser sediment and rounded the coarse to very coarse pebble fraction by selective reworking.     

Spurious results from Fourier analysis of data with closely spaced frequencies

It is shown how erroneous results can occur using some period-finding methods, such as Fourier analysis, on data containing closely spaced frequencies. The frequency spacing accurately resolvable with data of lengthT is increased from the standard value of about 1/T quoted in the literature to approximately 1.5/T.     

Palaeoecological investigations towards the reconstruction of the post-glacial environment at Lough Doo,County Mayo,Ireland

Results of palaeoecological studies involving pollen analytical, chemical and palaeomagnetic investigations on a 3 m core from Lough Doo, NE County Mayo, are presented. The record, which commences shortly after 7000 BP, shows a sharp Alnus expansion coinciding with a decline in Pius at 6400 BP, an elm decline taking place in the context of severe soil erosion and the final decline of Pinus occurring as the chemical record indicates onset of severe reducing conditions in the catchment. Pine becomes extinct at or shortly before 3200 BP in the context of increased farming activity and the expansion of blanket bog in the adjacent upland areas. A later feature (c. 1880 BP) is the expansion of Taxus to 7.1% of total pollen. On the basis of the palynological evidence, it is concluded that there were no major Neolithic Landnam phases, which contrasts sharply with the evidence for widespread woodland clearance and the laying out of extensive and regular field systems in the northern coastal part of County Mayo. In the upper part of the core a severe inversion of ¹⁴C dates is recorded. On the basis of the palaeomagnetic and pollen evidence this began at c. 1500 BP and is considered to have been initiated in the context of woodland clearance and a renewal in farming activity.     

Finite element analysis of construction stability of Thika Dam

High pore water pressures were measured in the fill material of the Thika Dam embankment early in its construction. These caused concern about the subsequent short term stability. Therefore construction was stopped. Stability reassessment and drainage design was performed using finite element analyses before construction was allowed to continue. Different methods of modelling the pore water pressure allowed efficient analysis of various drainage options. The analyses highlighted zones of high shear stress and shear strain, and formation of failure surfaces. They established the necessary level of drainage required to ensure stability, control movement and reduce the risk of residual shear surfaces. Large toe movement was predicted immediately after construction recommences. ©