草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

新疆月太阳总辐射气候学计算方法的研究

本文先对现有各种太阳总辐射气候学计算公式进行讨论，并确定Ｑ＝Ｑ２为新疆最佳计算公式，然后根据新疆９个月日射站的资料分南疆，北疆两大区域按月给出区域统一式，最后验证了它们的计算效果。     

颗粒分析用量筒的规格标准和计量标定

文章讨论了国内外用于密度计法颗粒分析用量筒的计量标准的规定，提出了相应的建议和标定方法。     

Typical basin-fill sequences and basin migration in Yanshan, North China--Response to Mesozoic tectonic transition

Basin-fill sequences of Mesozoic typical basins in the Yanshan area, North China may be divided into four phases, reflecting lithosphere tectonic evolution from flexure (T3), flexure with weak rifting (J1+2), tectonic transition (J3), and rifting (K). Except the first phase, the other three phases all start with lava and volcaniclastic rocks, and end with thick coarse clastic rocks and/or conglomerates, showing cyclic basin development rather than simple cyclic rift mechanism and disciplinary basin-stress change from extension to compression in each phase. Prototype basin analysis, based on basin-fill sequences, paleocurrent distribution and depositional systems, shows that single basin-strike and structural-line direction controlling basin development had evidently changed from east-west to northeast in Late Jurassic in the Yanshan area, although basin group still occurred in east-west zonal distribution. Till Early Cretaceous, main structural-line strike controlling basins just turned to northeast by north in the studied area.     

山东省气候变化及其对冬小麦生产潜力的影响

利用全省 2 7个台站 1 96 1～ 1 998年的温度、降水、日照等基本气象要素资料 ,对山东省气候变化特点进行了分析 ,并对冬小麦生产潜力进行了计算、分析。结果表明 ,山东省年、季平均气温呈波动性增暖趋势 ,降水量呈减少趋势。气候变暖有利于生产潜力的提高 ,冬小麦气候生产潜力总的变化趋势是波动性的上升 ,但较光温生产潜力倾向率小 ,反映了小麦生育期内光、温、水的综合影响。     

山西省主要河流流域面雨量预报业务流程

以T213、HLAFS模式、MM5中尺度模式输出的格点资料以及日本降水量格点资料为基础，将影响山西降水的天气动力模型归纳为诊断模型，从中引出多个能够全面反映降水模型特征的综合物理因子；根据各种数值模式输出的降水量预报性能和质量优劣特点，依据数值模式的形势场预报优于要素场预报的现实，构造在不同环流形势背景下，启动不同预报方程的面雨量预报业务流程，有效地遏止了在环流形势调整时预报输出不能快速响应的弱点，提高了点和面雨量预报的准确度。     

用远场辐射场反演云闪放电参数

用地面电磁场遥感闪电放电参数无论是在实际应用还是理论研究中都具有重要意义。文中基于电流传输线模式 ,提出了一种用单站远场VLF/LF辐射场反演云内放电参数的简便方法。当传输线电流从底部传播到顶部的时间只有几微秒时 ,整个传输线的VLF/LF辐射可以近似成偶极子辐射 ,即远场辐射场与电流的时间变化率和传输线长度的乘积成正比。因此 ,对远场辐射场做时间积分就能获得完整的电流矩波形 (上升沿有所加宽 ) ,而且传输线模式中的重要参数 ,电流从底部传播到顶端经历的时间 ,也可以近似地用辐射场时间积分幅度与辐射场幅度之比来估计。这一方法具有估计云闪双极性大脉冲辐射过程的放电参数的潜力。     

从安徽气候变化看2003年洪涝和高温的必然性

利用近 50年温度和降水资料研究了安徽夏季气候变化特征 ,解释了 2 0 0 3年夏季洪涝、高温等极端气候事件出现的必然性。研究结果表明 :(1 )近 50年来安徽夏季温度呈下降趋势 ,降水则呈增加趋势 ,两者变化是相协调的。目前夏季温度处于较低的气候基本态 ,降水处于高基本态。 (2 )无论是温度还是降水 ,其变率都在 2 0世纪80年代中后期开始上升 ,目前均处于高气候变率时期。降水的“两高”(高基本态和高气候变率 )结合决定了 2 0 0 3年夏季洪涝出现的必然性 ;温度的较低基本态决定了“凉夏”背景 ,但由于基本态的回升和变率的加大 ,仍会出现像 2 0 0 3年夏季的若干高温天气。 (3)最大熵谱估计表明 ,安徽夏季降水变化的主周期为 2 5年 ,反映了降水的准两年振荡特征     

碳酸岩Sr、Nd、Pb 同位素地球化学研究评述

碳酸岩是出露相对较少的幔源岩石，其中Sr与Nd是研究地幔物质组成的主要对象之一。本文统计了世界上主要碳酸岩的锶、钕、铅同位素组成特征；研究显示，碳酸岩源区主要是洋岛玄武岩高U／Pb的HIMU端员和富集端员(EM1或EM2)的混合作用；此外大部分碳酸岩的锶、钕同位素落在大洋玄武岩范围内；这些均表明其成因与地慢柱有密切联系。碳酸岩及与之共生的硅酸岩的同源或独立源区模式部很难充分解释两者同位素组成特征，逭反映碳酸岩的演化模式涉及更复杂的过程。可能是俯冲作用使碳酸岩源区经历不同时间和程度的富集、亏损过程导致地幔源区成分不均一。     

Pollution history and recovery of a boreal lake exposed to a heavy bleached pulping effluent load

We examined the effects of heavy pulp mill discharges on the Lake Lievestuoreenjärvi ecosystem and the later recovery of diatom and chironomid communities from age-dated short core samples. Beginning in 1927 the lake received a heavy effluent load from a sulphite pulp mill. Except for the recession during the Second World War and the temporary closure of the mill from 1967 to 1971, the industrial load, containing large quantities of nutrients, organic matter and toxic compounds, increased continuously. In the early 1980s, laboratory documents were falsified by the directors of the mill and the systematic illegal effluent overload led to a collapse of the whole lake ecosystem. In 1985, the outdated plant was finally closed down. Based on the assessment of chemical properties and biological remains of the sediment, we distinguished five developmental phases in the ecological state of the lake. In the pre-industrial phase, the pelagic and profundal benthic communities were dominated by species preferring ultraoligotrophic or oligotrophic lakes. Concomitant with the increasing discharge and deposition of chlorine compounds, resin acids, and mercury, as well as strong acidity and hypolimnetic and epilimnetic anoxia, the ecological status changed in a short period from excellent to bad. Finally, in the early 1960s, the majority of the lake was virtually dead and the aquatic life survived only in the uppermost littoral zone. Since 1985, a fast recovery in the water quality has led to a strong, but temporary eutrophy in pelagic communities. The main peak of eutrophication was caused by the invasion of a species new to the lake,Aulacoseira granulata var.angustissima. Later, the pelagic communities shifted towards oligotrophy, but the original, pre-industrial status has not been re-established. The profundal benthic communities have not achieved the pre-industrial structure, but at present indicate mesotrophy.