Confined groundwater system in Tokyo

The Musashino Terrace and the Shitamachi Lowland, the main urban areas in the Tokyo metropolis, are in the eastern part of Tokyo and are underlain by thick Quaternary sediments. The geologic structrue of these sediments has a general strike of WNW—ESE, with a gentle dip to the east in the western part of the Musashino Terrace, and strikes generally to the E—W with a gentle dip to the north in the eastern part of the terrace and strikes WNW—ESE to N—S with a very gentle dip to the east in the Shitamachi Lowland. The basal sediments in this area consist chiefly of massive thick silty layers, whereas the sediments overlying them consist of alternating layers of silt, sand, and gravel, which act as confined aquifers throughout the Musashino Terrace and the Shitamachi Lowland. Confined groundwater systems are being developed in the Tama District, the western part of the terrace, and are mainly recharged with river water from the Tama River. The unconfined groundwater system is being developed in the surface layers such as terrace sand and gravel formations and the Kanto Loam Formation. These confined aquifers that are being developed throughout the terrace and the lowland have been exploited for household water supplies and industrial and air-conditioning use for nearly seven decades. The heavy utilization of the confined groundwater, however, has caused a major lowering of groundwater levels. As a result of the lowering of groundwater levels, land subsidence has occurred all over the Lowland and the terrace. At this time the national government and the Tokyo Metropolitan Government restricted groundwater withdrawals for industrial, air-conditioning use and the others except for household supply. Owing to these restrictions, not only have the water levels recovered, but land subsidence has rapidly declined since around 1973.     

Formal definition and dating of the GSSP (Global Stratotype Section and Point) for the base of the Holocene using the Greenland NGRIP ice core,and selected auxiliary records

The Greenland ice core from NorthGRIP (NGRIP) contains a proxy climate record across the Pleistocene–Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision. This climatic event is most clearly reflected in an abrupt shift in deuterium excess values, accompanied by more gradual changes in δ¹⁸O, dust concentration, a range of chemical species, and annual layer thickness. A timescale based on multi‐parameter annual layer counting provides an age of 11 700 calendar yr b2 k (before AD 2000) for the base of the Holocene, with a maximum counting error of 99 yr. A proposal that an archived core from this unique sequence should constitute the Global Stratotype Section and Point (GSSP) for the base of the Holocene Series/Epoch (Quaternary System/Period) has been ratified by the International Union of Geological Sciences. Five auxiliary stratotypes for the Pleistocene–Holocene boundary have also been recognised. Copyright © 2008 John Wiley & Sons, Ltd.     

Interactions of uranium with bacteria and kaolinite clay

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.     

An Ecosystem Model Including Nitrogen Isotopes: Perspectives on a Study of the Marine Nitrogen Cycle

We have developed an ecosystem model including two nitrogen isotopes (¹⁴N and ¹⁵N), and validated this model using an actual data set. A study of nitrogen isotopic ratios (δ¹⁵N) using a marine ecosystem model is thought to be most helpful in quantitatively understanding the marine nitrogen cycle. Moreover, the model study may indicate a new potential of δ¹⁵N as a tracer. This model has six compartments: phytoplankton, zooplankton, particulate organic nitrogen, dissolved organic nitrogen, nitrate and ammonium in a two-box model, and has biological processes with/without isotopic fractionation. We have applied this model to the Sea of Okhotsk and successfully reproduced the δ¹⁵N of nitrate measured in seawater and the seasonal variations in δ¹⁵N of sinking particles obtained from sediment trap experiments. Simulated δ¹⁵N of phytoplankton are determined by δ ¹⁵N of nitrate and ammonium, and the nitrogen f-ratio, defined as the ratio of nitrate assimilation by phytoplankton to total nitrogenous nutrient assimilation. Detailed considerations of biological processes in the spring and autumn blooms have demonstrated that there is a significant difference between simulated δ¹⁵N values of phytoplankton, which assimilates only nitrate, and only ammonium, respectively. We suggest that observations of δ ¹⁵N values of phytoplankton, nitrate and ammonium in the spring and autumn blooms may indicate the ratios of nutrient selectivity by phytoplankton. In winter, most of the simulated biogeochemical fluxes decrease rapidly, but nitrification flux decreases much more slowly than the other biogeochemical fluxes. Therefore, simulated δ¹⁵N values and concentrations of ammonium reflect almost only nitrification. We suggest that the nitrification rate can be parameterized with observations of δ¹⁵N of ammonium in winter and a sensitive study varying the parameter of nitrification rate.     

Wavenumber spectra of planetary-scale disturbances in the Mars atmosphere

Wavenumber spectra of the martian atmosphere covering zonal wavenumbers s=1-6 were obtained as a function of latitude and season for the first time from the temperatures measured by the Thermal Emission Spectrometer onboard the Mars Global Surveyor. The stationary component tends to peak at s=2, where the martian topography has large amplitude, and drops rapidly at higher wavenumbers. The transient component in the middle and high latitudes tends to peak at s=1, which is lower than the most unstable wavenumber based on linear theories, and exhibits spectral slopes much flatter than the stationary component. In the equatorial region, the spectra of the transient component are almost flat, indicating that the organization of large-scale structures is less efficient in this region. The spectral shapes are similar between the 0.5 and 2.2 hPa surfaces, except that the slopes are slightly steeper at 0.5 than at 2.2 hPa, probably due to selective vertical transmission at low wavenumbers. The seasonal variation is relatively large in the middle and high latitudes, where the maximum power occurs in winter and the minimum occurs in summer, with an exception that the transient component is maximum in spring in the southern hemisphere. Intensification of s=1 transient waves is observed around the period of the initiation of global dust storms.     

Three-Dimensional Geopositioning Accuracy of Ikonos Imagery

An investigation of the accuracy potential of Ikonos 1m satellite imagery is reported. Three sensor orientation/triangulation models are applied to stereo- and three-image configurations of "Geo" imagery with the aim of achieving 3D geopositioning to sub-metre accuracy. The models considered comprise rational functions with bias compensation, affine projection and the direct linear transformation. Test results from the Melbourne Ikonos Testfield are reported and these show that with modest provision of good quality ground control, Ikonos "Geo" imagery can yield 3D object-point determination to an accuracy of 0.5m in planimetry and 0.7m in height. The accuracy achieved is not only consistent with expectations for rigorous sensor orientation models, but is also readily attainable in practice with only a small number of ground control points being required     

Geology and Mineralization at the Dajing Tin-polymetallic Ore Deposit, Inner Mongolia, China

Abstract: Dajing is a large-scale tin–polymetallic ore deposit in north China with Sn, Cu, Pb, Zn, Ag, and minor elements such as Co and In. The deposit is controlled by a passage-host structure system. Two groups of NE direction faults such as F₂ and F₁ are characterized by sinistral and multiphase activities, and the syn-ore NE faults with their derivative faults nearly in N-S direction constitute an important structure system as channelway for ore fluid. Around F₂ fault (mineralization center), metallic elements display horizontal zoning outwards from Sn, Cu to Cu, Sn, Pb, Zn, Ag and to Pb, Zn, Ag. Controlled by sinistral pull-apart vein system, the WNW direction host structure yielded the ore vein to "W" shape on horizontal plan while to staircase shape on vertical profile. Multiperiodic activities of the host structures system lead to multistage of ore mineralization. Four mineralization stages are recognized in the main mineralization, i.e. 1) cassiterite–arsenopyrite–quartz stage, 2) cassiterite-sulfide (or Cu–poly–metallic mineralization) stage, 3) massive pyrite stage, and 4) galena-sphalerite stage. Besides, fluid activities are identified here at the pre-mineral stage of the formation of quartz veins and sheared deformation, and at the post-mineral stage of quartz–calcite–fluorite deposition.
The earlier tin-rich ore solution raised from NE faults and its nearly N-S derivatives filled the NW-WNW direction fractures, and formed tin ore veins. Subsequent mineralization of Cu-polymetallic stage, pyrite stage and galena-sphalerite stage, overlapping on the same fracture system, sequentially expanded outwards from the fractures, and produced different kinds of ore types and mineralization zoning.     

Relationship between trace elements and depositional environments in shallow sediments: a case study from Southern Kanto Plain,Central Japan

Underground developments such as subways and shopping facilities have been increasing in number and magnitude in the relatively shallow subsurface of many urban areas where the earth materials commonly are composed of marine sediments. Marine sediments can contain significant amounts of toxic trace elements such as arsenic, boron, and lead. Changes in the subsurface environment caused by excavation and construction in underground developments could potentially cause these toxic elements to be dissolved into pore water of the sediments, which might lead to groundwater pollution. The purpose of this study is to investigate correlations among chemical properties of marine sediments, such as pH and electrical conductivity (EC), concentrations of toxic trace elements, and stratigraphic characteristics of the sediments. We selected three sites with different stratigraphic settings in the southern Kanto Plain around the Tokyo Metropolis. We collected core samples from shallow strata at a site in the Arakawa Lowland, southern Saitama, and at two sites in the Musashino Upland, Middle Tokyo. All sites have both marine and non-marine sediments up to 50–60 m in thickness. We determined trace element concentrations in the pore water, pH, EC, and loss on ignition. The results show that (1) the marine sediments tend to have low pH, high EC, and high sulfur concentration compared to the non-marine sediments (2) the concentration of most of the soluble heavy metals vary depending on the concentration of sulfate, the pH, and the formation processes of the strata, (3) the arsenic concentration is not related to sulfur concentration but apparently to Fe and Al concentrations, (4) the boron concentration is not related to any other properties implying that the boron level is independent of and cannot be predicted by common chemical properties, and (5) for all three sites, concentrations of most of the trace elements, EC, pH, and sulfate concentration were correlated with each other. This study shows that the concentration and potential mobilization of many toxic trace elements in marine sediments could be predicted by easily measurable pore water chemical properties such as pH and EC. This could be useful for predicting and avoiding the risk of groundwater pollution during underground development projects.     

Magnetic and electric field observations during the 2000 activity of Miyake-jima volcano, Central Japan

Magnetic and electric field variations associated with the 2000 eruption of Miyake-jima volcano are summarized. For about 1 week prior to the July 8 phreatic explosion, significant changes in the total intensity were observed at a few stations, which indicated uprising of a demagnetized area from a depth of 2 km towards the summit: this non-magnetic source can be regarded as a vacant space itself. Electric and magnetic field variations were observed simultaneously associated with the tilt-step event, which was the abrupt (∼50 s) inflation at a few km depth within the volcano followed by gradual recovery (∼several hours). The electric field is ascribed to the electrokinetic effect most probably due to forced injection of fluids from the source, while the magnetic field to the piezomagnetic effect due to increased pressure. Large magnetic variations amounting to a few tens of nT were observed at several stations since July 8, and they turned almost flat after the August 18 largest eruption. Magnetic changes are explained mostly by the vanishing of magnetic mass in the summit and additionally by the thermal demagnetization at a rather shallow depth. A large increase in the self-potential by 130 mV was also observed near the summit caldera associated with the August 18 eruption, which suggests that the hydrothermal circulation system sustained within the volcano for the past more than 10 years was destroyed by this eruption.