Reconstruction of Physicochemical Environment of Hydrothermal Mineralization at Malanjkhand Copper Deposit,Central India: Constraints from Sulfur Isotope Ratios in Pyrite,Molybdenite and Chalcopyrite

δ³⁴S values of pyrite, molybdenite and chalcopyrite were determined from the Malanjkhand copper deposit. These minerals constitute the primary sulfide phases that were deposited after the initial magnetite deposition in the main orebody and host granitoid. Pyrite exhibits a depleted range of values (?2.63 to ?0.56‰), chalcopyrite, a very narrow range of values around zero (?0.039 to 0.201‰) and molybdenite furnishes a range of enriched values (0.68 to 1.98‰). On back calculation of the δ³⁴S values of H₂S in the fluid from which the minerals were likely to have precipitated, using standard expressions for equilibrium fractionation at the temperature range obtained from fluid inclusion and mineral fluid equilibria, it is observed that H₂S in the fluid at pyrite deposition was depleted and gradually became enriched towards molybdenite and chalcopyrite deposition. This trend is best explained as being due to inorganic reduction of SO₄^2? in the fluid and is very much in agreement with the paragenetic sequence indicating increasing activity of H₂S in the fluid. The very restricted range in the δ³⁴S values of sulfide minerals in the fluid does indicate a single, possibly magmatic, source of sulfur that also agrees well with the earlier deduced model of genesis of the deposit as an ancient geothermal system associated with granitic magmatism.     

Olivine-rich exposures in the South Pole-Aitken Basin

The distribution and the geological context of the olivine-rich exposures in the South Pole-Aitken (SPA) Basin on the Moon were investigated based on the spectral data obtained from the Spectral Profiler (SP) and Multiband Imager (MI) onboard the Japanese lunar explorer Kaguya/SELENE. The olivine-rich exposures are found only in the peak rings or central peaks of the Schrödinger basin and Zeeman crater, which are located in the outer region of the SPA Basin and not in the center region. On a localized scale, the olivine-rich materials are exposed on landslide features on the crater walls or sloped wall of the central peaks or the peak rings. Another observational finding is the co-existence of olivine-rich and plagioclase-rich materials on a kilometer scale spanning most of the olivine-rich sites in the Schrödinger basin. Pyroxene-rich materials are found in fresh craters outside the peak rings or the central peaks with olivine-rich materials. Based on these results, the following scenario are proposed: (1) the impact to form the SPA Basin melted a large amount of the lunar upper mantle and crust, and distributed the melted materials to the outer region; (2) local differentiation of melted materials hid the olivine-rich materials in the center region of the SPA Basin; (3) later impacts that formed the Schrödinger and Zeeman craters excavated and exposed the olivine-rich materials to the surface again; and (4) space weathering and regolith gardening obscured the olivine-rich spectra at the exposure sites, but recent, small scale impacts or landslides on the sloped wall exposed fresh olivine-rich materials, allowing the identification of the olivine-rich exposures by spectral remote-sensing. This suggests that several, different scale events play an important role in forming the surface distributions of originally deep-seated materials on the Moon, as well as on other planetary bodies.     

Experimental impact shock chemistry on planetary icy satellites

We present new experimental results on impact shock chemistry into icy satellites of the outer planets. Icy mixtures of pure water ice with CO₂, Na₂CO₃, CH₃OH, and CH₃OH/(NH₄)₂SO₄ at 77 K were ablated with a powerful pulsed laser—a new technique used to simulate shock processes which can occur during impacts. New products were identified by GC-MS and FTIR analyses after laser ablation. Our results show that hydrogen peroxide is formed in irradiated H₂O/CO₂ ices with a final concentration of 0.23%. CO and CH₃OH were also detected as main products. The laser ablation of frozen H₂O/Na₂CO₃ generates only CO and CO₂ as destruction products from the salt. Pulsed irradiation of water ice containing methanol leads also to the formation of CO and CO₂, generates methane and more complex molecules containing carbonyl groups like acetaldehyde, acetone, methyl formate, and a diether, dimethyl formal. The last three compounds are also produced when adding ammonium sulfate to H₂O/CH₃OH ice, but acetone is more abundant. The formation of two hydrocarbons, CH₄ and C₂H₆ is observed as well as the production of three nitrogen compounds, nitrous oxide, hydrogen cyanide, and acetonitrile.     

Granitoid Types Related to Cretaceous Plutonic Au-Quartz Vein and Cu-Fe Skarn Deposits, Kitakami Mountains, Japan

Abstract. Early Cretaceous granitic intrusions are associated with Au‐quartz veins and Cu‐Fe skarns in the the Kitakami Mountains, which are underlain by the late Paleozoic of continental margin‐type sedimentary rocks and Mesozoic accretionary complexes. The plutonic rocks are divided into potassic, high‐Sr/Y calc‐alkaline and low‐Sr/Y calc‐alkaline series. All the metallic mineral deposits are spatially associated with small stocks and plugs; they show no consistent association with the larger plutonic bodies. The plutonic rocks generally belong to the magnetite series but less oxidized in the southwestern part of the Kitakami Mountains where Au‐quartz veins occur. The gold deposits are classified into high and low sulfide types. The high sulfide type contains a high volume of sulfide minerals mostly of chalcopyrite, arsenopyrite and pyrrhotite with low bulk Au/Ag ratios. This type occurs almost exclusively in and surrounding the Orikabe pluton, including two most important gold deposits (Oya and Kohoku) of the Kitakami Mountains. The pluton is composed of potassic gabbroids, potassic granitoids of the shoshonite ‐ high‐K calc‐alkaline series (Orikabe type), and less potassic Sasamori‐type granodiorite. All these rocks belong to a moderately oxidized magnetite series. The Orikabe pluton has one of the lowest initial Sr ratio (0.70392) in the Kitakami Mountains, and the Au‐Cu‐dominant ore components of the high sulfide type Au deposits are considered magmatic in origin carried by the juvenile magmas from the upper mantle. The low sulfide type is generally plain quartz vein with a low volume of sulfides and a high bulk Au/Ag ratio. The associated minerals are often scheelite and/or arsenopyrite and pyrrhotite. The ore deposits include historically famed Au‐quartz veins at Shishiori and Ogayu. They are widespread in the southwestern Kitakami Mountains and may be later than the high sulfide type in age, and are hosted most commonly in the sedimentary rocks, which surround small weakly oxidized magnetite‐series plutons of low to intermediate Sr/Y series. These less differentiated intrusions typically include quartz dior‐ite and granodiorite. Some ore components of this type may have derived from the host sedimentary rocks. Among other mineral deposit types in the region, the largest ore deposit is Kamaishi Cu‐Fe skarn (magnetite ores of 58 MT, Fe 50–64 %; Cu 143 KT). It is related to the high‐Sr/Y series Ganidake granodiorite stock, which is a strongly oxidized magnetite‐series body. In contrast, the second largest deposit in the mountains, Akagane deposit, is a similar‐type skarn but associated with an intrusion classified as less oxidized, ilmenite to intermediate series, and that is intermediate in Sr/Y of calc‐alkaline series granodiorite. Degree of magmatic differentiation appears to be not critical factor in the formation of Au‐quartz vein and Cu‐Fe skarn deposits in the region, but is definitely significant for controlling the distribution of the Mo‐mineralization to the east.     

Residual deformation characteristics of partially saturated sandy soils subjected to seismic excitation

Multiple series of triaxial tests were carried out on unsaturated sandy soils subjected to irregular seismic excitation. To observe the volume changes of unsaturated soil specimens during undrained loading and subsequent process of drainage, the inner cell was newly installed inside the large triaxial cell. The soil samples tested were recovered from the construction site of a liquefied natural gas storage facility located in Tokyo Bay area. In the tests, the initial conditions of soil specimens were specified with the degrees of saturation S_r of 50, 75 and 100%. The soil specimens were anisotropically consolidated, and subjected to undrained irregular seismic excitation. The time history of irregular seismic excitation was the one obtained from one of the recent earthquakes in Japan. The drainage line was then opened to let the excess pore water drain out of soil specimens. The volume changes and residual shear strains of unsaturated soil specimens thus obtained are presented in the present paper.     

Millennial‐scale stratigraphy of a tide‐dominated incised valley during the last 14 kyr: Spatial and quantitative reconstruction in the Tokyo Lowland,central Japan

Spatial and quantitative analysis of infilling processes of the tide‐dominated incised valleys beneath the Tokyo Lowland during the last 14 kyr was undertaken by using data from 18 sediment cores, 467 radiocarbon dates and 6100 borehole logs. The post‐Last Glacial Maximum valley fills consist of braided river, meandering river, estuary, spit and delta systems in ascending order. The boundary between the estuary and delta systems is regarded as the maximum flooding surface. The maximum flooding surface beneath the Tokyo Lowland is dated at 8 ka in the Arakawa Valley and 7 ka in the Nakagawa Valley. This age difference is due to the migration of the Tone River from the Arakawa Valley to the Nakagawa Valley at 5 ka, and suggests that the widely held view that the global initiation of deltas coincided with the abrupt rise of sea‐level at 9 to 8 ka is true only where there has been steady sediment supply from major rivers. The meandering river system is dominated by sheet‐like sands that were deposited during lateral migration of channels during the Younger Dryas and isolated vertical sands within muds that reflect vertical aggradation of channels before and after the Younger Dryas. The transition between these channel geometries is controlled by a threshold sea‐level rise of 4 to 7 mm yr^?1. Before migration of the Tone River at 5 ka, the tide‐dominated bay in the Nakagawa Valley was filled by upward‐fining laterally accreting muds. The muds accreted from the margin to the axis of the bay. Such lateral accretion of suspended particles derived from outside the bay has been documented in other tide‐dominated coastal environments and is probably common in other similar settings. After the migration of the Tone River, the bay was filled by upward‐coarsening deltaic sediments.     

Analysis of infrasonic and seismic events related to the 1998 Vulcanian eruption at Sakurajima

We present results from a detailed analysis of seismic and infrasonic data recorded over a four day period prior to the Vulcanian eruptive event at Sakurajima volcano on May 19, 1998. Nearly one hundred seismic and infrasonic events were recorded on at least one of the nine seismic–infrasonic stations located within 3 km of the crater. Four unique seismic event types are recognized based on the spectral features of seismograms, including weak seismic tremor characterized by a 5–6 Hz peak mode that later shifted to 4–5 Hz. Long-period events are characterized by a short-duration, wide spectral band signal with an emergent, high-frequency onset followed by a wave coda lasting 15–20 s and a fundamental mode of 4.2–4.4 Hz. Values of Q for long-period events range between 10 and 22 suggesting that a gas-rich fluid was involved. Explosive events are the third seismic type, characterized by a narrow spectral band signal with an impulsive high-frequency onset followed by a 20–30 second wave coda and a peak mode of 4.0–4.4 Hz. Volcano-tectonic earthquakes are the fourth seismic type. Prior to May 19, 1998, only the tremor and explosion seismic events are found to have an infrasonic component. Like seismic tremor, infrasonic tremor is typically observed as a weak background signal. Explosive infrasonic events were recorded 10–15 s after the explosive seismic events and with audible explosions prior to May 19. On May 19, high-frequency impulsive infrasonic events occurred sporadically and as swarms within hours of the eruption. These infrasonic events are observed to be coincident with swarms of long-period seismic events. Video coverage during the seismic–infrasonic experiment recorded intermittent releases of gases and ash during times when seismic and acoustic events were recorded. The sequence of seismic and infrasonic events is interpreted as representing a gas-rich fluid moving through a series of cracks and conduits beneath the active summit crater.     

Resource Evaluation of Indium in the Dajing Tin-Polymetallic Deposits, Inner Mongolia, China

Individual ores of 37 specimens and five mill concentrates were analyzed chemically, and anomalous indium contents were detected in the tin‐polymetallic veins of the Dajing mine. The indium contents are heterogenously distributed (0.5–296 ppm In), and are low generally in the ores of the East Block. Indium is mainly correlated with copper, partly with zinc in the Dajing deposits, implying that the element is substituted in copper and zinc sulfides and sulfosalts. The total indium content is expected as >768 tons, which is lower than a previous estimation of this mine. The whole tonnage of the southern part of the Da Hinggang Mountains is >1200 tons In, which is the second largest in China after the tin‐polymetallic deposits in the southern China.