Observation of Pore Spaces and Microcracks Using a Fluorescent Technique in Some Reservoir Rocks of Oil, Gas and Geothermal Fields in the Green Tuff Region, Japan

Abstract: Pore spaces and microcracks in representative oil, gas and geothermal reservoir rocks from the Green Tuff region, Japan, were examined using a fluorescent technique. This technique was developed to visualize microscopically pore spaces and microcracks filled with synthetic resin mixed with fluorescent paint under ultraviolet light. Various morphology of pore spaces and microcracks was clearly identified. Spaces in studied reservoir rocks are classified into following three types: pore spaces in matrix, pore spaces in particles, and microcracks. It is observed that valuable oil and gas reservoir rocks relatively include many pore spaces, while microcracks are important for geothermal rocks. Correlation between textural characteristics and porosity or permeability was found in the oil reservoir rocks. Effective permeability depends upon pore spaces in matrix more than upon other components such as pore spaces in particles and microcracks. Looseness in matrix caused by larger grain size of particles is strongly correlated with permeability. Pore spaces play an important role as a reservoir in oil and gas fields, but are less important in geothermal field. Instead, microcracks are important for geothermal reservoir system.     

A novel index to evaluate discretization methods:A case study of flood susceptibility assessment based on random forest

The selection of a suitable discretization method(DM)to discretize spatially continuous variables(SCVs)is critical in ML-based natural hazard susceptibility assessment.However,few studies start to consider the influence due to the selected DMs and how to efficiently select a suitable DM for each SCV.These issues were well addressed in this study.The information loss rate(ILR),an index based on the informa-tion entropy,seems can be used to select optimal DM for each SCV.However,the ILR fails to show the actual influence of discretization because such index only considers the total amount of information of the discretized variables departing from the original SCV.Facing this issue,we propose an index,infor-mation change rate(ICR),that focuses on the changed amount of information due to the discretization based on each cell,enabling the identification of the optimal DM.We develop a case study with Random Forest(training/testing ratio of 7:3)to assess flood susceptibility in Wanan County,China.The area under the curve-based and susceptibility maps-based approaches were presented to compare the ILR and ICR.The results show the ICR-based optimal DMs are more rational than the ILR-based ones in both cases.Moreover,we observed the ILR values are unnaturally small(＜1％),whereas the ICR values are obviously more in line with general recognition(usually 10％-30％).The above results all demonstrate the superiority of the ICR.We consider this study fills up the existing research gaps,improving the ML-based natural hazard susceptibility assessments.     

Iodine in the surface water of the ocean

Iodine in sea water of the Pacific was determined with special interest in the relation between iodide and iodate in the surface water of the ocean. The result was discussed with reference to the mechanism of iodide formation proposed byTsunogai andSase. The concentration of iodide varies widely from the lower value than the detection limit to 0.21g at./l, while the concentration of total iodine is nearly constant and the mean value is 0.41g at./l. The vertical profile of iodide often shows the maximum in the surface layer. In the surface layer, the concentration of iodide is higher in warm water (0,10g at./l on the average) than that in cold water of lower temperature than 20° C (0.03g at/l). The highest concentration of iodide among the warm waters is found in the surface water of the equatorial area (0.13g at./l) where the biological productivity is also high. Iodide is generally more enriched in the water having higher biological activity even in the cold water. These results are considered to be compatible with the mechanism of iodide formation proposed.     

Growth of ringwoodite reaction rims from MgSiO3 perovskite and periclase at 22.5 GPa and 1,800 °C

The growth rate of ringwoodite reaction rims between MgSiO₃ perovskite and periclase was investigated at 22.5 GPa and 1,800 °C for 1–24 h using the Kawai-type high-pressure apparatus. The reaction was likely to proceed by a diffusion-controlled mechanism in which the dominant diffusion mechanism was grain-boundary diffusion. The reaction constant (the width of the ringwoodite reaction rim squared divided by time) determined from these experiments was between 1.3 × 10^?15 and 5.6 × 10^?15 m²/s. A Pt inert marker experiment indicated that the MgO component migrated faster than the SiO₂ component in ringwoodite. Thus, either Mg or O having the slower diffusion rate controlled the reaction. Because previous diffusion studies have shown that diffusion rates of O are slower than those of Mg, O would be a rate-controlling element for ringwoodite formation from MgSiO₃ perovskite and periclase. The growth rate appeared to be too fast to explain the observed topographic rise (~10 km) inside mantle plumes at the 660-km discontinuity.     

In-situ survey of nanomolar manganese in seawater using an autonomous underwater vehicle around a volcanic crater at Teishi Knoll,Sagami Bay,Japan

We present the results of a chemical survey at a submarine volcano, Teishi Knoll, obtained using a submersible in-situ Mn analyzer (GAMOS) mounted on an autonomous underwater vehicle (AUV) platform. During this survey, high-resolution data of dissolved Mn were obtained in three dimensions in nearly real time. The AUV enabled continuous detailed observations along a preprogrammed pathway, which could not have been performed with conventional CTD hydrocasts. During this observation, anomalously high dissolved Mn concentrations were obtained within the crater, corresponding to high water temperatures. The anomalies might be a hydrothermal signature due to volcanic activity from the crater.     

Practical evaluation of carbon sources of forest soils in Slovenia from stable and radio-carbon isotope measurements

Carbon sources were estimated by measuring carbon isotope ratios (??¹³C and ??¹⁴C) with accelerator mass spectrometry (AMS) in forest soils of different lithology. Six locations were selected in temperate deciduous and coniferous stands in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorje, Gori?nica, and Rakitna), where carbonate rocks consisting of limestone and dolomite are abundant as underlying bedrock. Carbon isotope fractionation would not have occurred in two carbonaceous soils, since the values of both ??¹³C and ??¹⁴C changed consistently in these soils after thermal (550°C, 2?h) or chemical (1?M HCl, 24?h) treatments. Organic components were found to be predominant carbon sources (70?C100%) in the uppermost portions (0?C2?cm in depth). In deeper portions at a depth of about 30?C35?cm, soil carbon may be derived completely from underlying carbonate minerals in Idria, western part of Slovenia. The Combination of heat and chemical treatments with AMS provides practical information on soil carbon sources in carbonaceous soils.     

创意城市网络下日本神户设计之都的规划与实践

创意城市是城市复兴和再生的发展模式,创意城市网络是推动创意城市发展的全球性载体。这种跨地域、跨国家、跨大洲的城市网络与创意城市发展的地理过程、空间格局逐步成为新的地理现象。本文以神户为例,分析神户创意城市发展的背景条件,研究其指向设计之都的主导产业与规划内容,探讨其推进设计之都建设的实践与经验。     

Theory for the critical ionization velocity phenomenon

A theoretical consideration is given to the critical ionization velocity. A macroscopic theory is constructed, assuming that (1) the newly born ions have an unstable velocity distribution and (2) the resultant fluctuating electric field heats the electrons. For the critical ionization velocity to operate in the case of $\text{m}{}_{\mathrm{a}}\text{V}{}^2\text{2}\text{> eφ}{}_{\mathrm{<mtext>ion</mtext>}}$, the initial values of high speed ion (or newly ionized ion) density and suprathermal electron energy density should be above a certain threshold. This threshold depends upon the velocity diffusion co-efficient and the collisional loss rate of the newly ionized ion.     

Non-destructive monitoring of trace element levels in short-tailed albatrosses (Phoebastria albatrus) and black-footed albatrosses (Phoebastria nigripes) from Torishima Island, Japan using eggs and blood

Concentrations of 18 trace elements (V, Cr, Mn, Co, Cu, Zn, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Hg, Tl and Pb) were determined in abandoned eggs of short-tailed albatrosses and abandoned eggs and blood of black-footed albatrosses from Torishima Island, Japan in 2002. Mercury concentration was highest among the toxic elements in egg content of both the two species. In some egg contents of black-footed albatrosses, Hg concentrations were higher than the threshold level that may cause decreased hatchability and aberrant nesting behavior in some avian species. Concentrations of Cd in egg content and Ba in egg content and shell increased with an increase in egg breadth/length ratio, whereas Hg in egg content showed an opposite trend in black-footed albatrosses. Since egg breadth/length ratio is known to increase with the age of mother bird, this result may imply that concentrations of these elements in eggs vary with age of mother bird. In blood of black-footed albatross chicks, concentration of Hg was highest among the toxic elements and the Hg concentration showed an increase in the later growth stages. In contrast, concentration of Sr in blood decreased with growth stage. Since the behaviour of Sr is similar to that of Ca in animals, it is conceivable that Sr was used along with Ca for the formation of bone.